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- 1172 Lessons
- 32 Weeks
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- 3.1Atomic Structure: Particles In The Atom And Atomic Radius: Understand That Atoms Are Mostly Empty Space Surrounding A Very Small, Dense Nucleus That Contains Protons And Neutrons; Electrons Are Found In Shells In The Empty Space Around The Nucleus
- 3.2Atomic Structure: Particles In The Atom And Atomic Radius: Identify And Describe Protons, Neutrons And Electrons In Terms Of Their Relative Charges And Relative Masses
- 3.3Atomic Structure: Particles In The Atom And Atomic Radius: Understand The Terms Atomic And Proton Number; Mass And Nucleon Number
- 3.4Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Distribution Of Mass And Charge Within An Atom
- 3.5Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Behaviour Of Beams Of Protons, Neutrons And Electrons Moving At The Same Velocity In An Electric Field
- 3.6Atomic Structure: Particles In The Atom And Atomic Radius: Determine The Numbers Of Protons, Neutrons And Electrons Present In Both Atoms And Ions Given Atomic Or Proton Number, Mass Or Nucleon Number And Charge
- 3.7Atomic Structure: Particles In The Atom And Atomic Radius: State And Explain Qualitatively The Variations In Atomic Radius And Ionic Radius Across A Period And Down A Group
- 3.8Atomic Structure: Isotopes: Define The Term Isotope In Terms Of Numbers Of Protons And Neutrons
- 3.9Atomic Structure: Isotopes: Understand The Notation X Ya For Isotopes, Where X Is The Mass Or Nucleon Number And Y Is The Atomic Or Proton Number
- 3.10Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have The Same Chemical Properties
- 3.11Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have Different Physical Properties, Limited To Mass And Density
- 3.12Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand The Terms: • Shells, Sub-shells And Orbitals • Principal Quantum Number (N) • Ground State, Limited To Electronic Configuration
- 3.13Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Number Of Orbitals Making Up S, P And D Sub-shells, And The Number Of Electrons That Can Fill S, P And D Sub-shells
- 3.14Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Order Of Increasing Energy Of The Sub-shells Within The First Three Shells And The 4s And 4p Sub-shells
- 3.15Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Electronic Configurations To Include The Number Of Electrons In Each Shell, Sub-shell And Orbital
- 3.16Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Explain The Electronic Configurations In Terms Of Energy Of The Electrons And Inter-electron Repulsion
- 3.17Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Determine The Electronic Configuration Of Atoms And Ions Given The Atomic Or Proton Number And Charge, Using Either Of The Following Conventions: E.g. For Fe: 1s2 2s2 2p6 3s2 3p6 3d6 4s2 (Full Electronic Configuration) Or [ar] 3d6 4s2 (Shorthand Electronic Configuration)
- 3.18Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand And Use The Electrons In Boxes Notation E.g. For Fe: [ar]
- 3.19Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe And Sketch The Shapes Of S And P Orbitals
- 3.20Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe A Free Radical As A Species With One Or More Unpaired Electrons
- 3.21Atomic Structure: Ionisation Energy: Define And Use The Term First Ionisation Energy, Ie
- 3.22Atomic Structure: Ionisation Energy: Construct Equations To Represent First, Second And Subsequent Ionisation Energies
- 3.23Atomic Structure: Ionisation Energy: Identify And Explain The Trends In Ionisation Energies Across A Period And Down A Group Of The Periodic Table
- 3.24Atomic Structure: Ionisation Energy: Identify And Explain The Variation In Successive Ionisation Energies Of An Element
- 3.25Atomic Structure: Ionisation Energy: Understand That Ionisation Energies Are Due To The Attraction Between The Nucleus And The Outer Electron
- 3.26Atomic Structure: Ionisation Energy: Explain The Factors Influencing The Ionisation Energies Of Elements In Terms Of Nuclear Charge, Atomic/ionic Radius, Shielding By Inner Shells And Sub-shells And Spin-pair Repulsion
- 3.27Atomic Structure: Ionisation Energy: Deduce The Electronic Configurations Of Elements Using Successive Ionisation Energy Data
- 3.28Atomic Structure: Ionisation Energy: Deduce The Position Of An Element In The Periodic Table Using Successive Ionisation Energy Data
- 3.29Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define The Unified Atomic Mass Unit As One Twelfth Of The Mass Of A Carbon-12 Atom
- 3.30Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define Relative Atomic Mass, Ar , Relative Isotopic Mass, Relative Molecular Mass, Mr , And Relative Formula Mass In Terms Of The Unified Atomic Mass Unit
- 3.31Atoms, Molecules And Stoichiometry: The Mole And The Avogadro Constant: Define And Use The Term Mole In Terms Of The Avogadro Constant
- 3.32Atoms, Molecules And Stoichiometry: Formulas: Write Formulas Of Ionic Compounds From Ionic Charges And Oxidation Numbers (Shown By A Roman Numeral), Including: (A) The Prediction Of Ionic Charge From The Position Of An Element In The Periodic Table (B) Recall Of The Names And Formulas For The Following Ions: No3 – , Co3 2–, So4 2–, Oh– , Nh4 + , Zn2+, Ag+ , Hco3 – , Po4 3–
- 3.33Atoms, Molecules And Stoichiometry: Formulas: (A) Write And Construct Equations (Which Should Be Balanced), Including Ionic Equations (Which Should Not Include Spectator Ions) (B) Use Appropriate State Symbols In Equations
- 3.34Atoms, Molecules And Stoichiometry: Formulas: Define And Use The Terms Empirical And Molecular Formula
- 3.35Atoms, Molecules And Stoichiometry: Formulas: Understand And Use The Terms Anhydrous, Hydrated And Water Of Crystallisation
- 3.36Atoms, Molecules And Stoichiometry: Formulas: Calculate Empirical And Molecular Formulas, Using Given Data
- 3.37Atoms, Molecules And Stoichiometry: Reacting Masses And Volumes (Of Solutions And Gases): Perform Calculations Including Use Of The Mole Concept, Involving: (A) Reacting Masses (From Formulas And Equations) Including Percentage Yield Calculations (B) Volumes Of Gases (E.g. In The Burning Of Hydrocarbons) (C) Volumes And Concentrations Of Solutions (D) Limiting Reagent And Excess Reagent (When Performing Calculations, Candidates’ Answers Should Reflect The Number Of Significant Figures Given Or Asked For In The Question. When Rounding Up Or Down, Candidates Should Ensure That Significant Figures Are Neither Lost Unnecessarily Nor Used Beyond What Is Justified (See Also Mathematical Requirements Section).) (E) Deduce Stoichiometric Relationships From Calculations Such As Those In 2.4.1(A)–(D)
- 3.38Chemical Bonding: Electronegativity And Bonding: Define Electronegativity As The Power Of An Atom To Attract Electrons To Itself
- 3.39Chemical Bonding: Electronegativity And Bonding: Explain The Factors Influencing The Electronegativities Of The Elements In Terms Of Nuclear Charge, Atomic Radius And Shielding By Inner Shells And Sub-shells
- 3.40Chemical Bonding: Electronegativity And Bonding: State And Explain The Trends In Electronegativity Across A Period And Down A Group Of The Periodic Table
- 3.41Chemical Bonding: Electronegativity And Bonding: Use The Differences In Pauling Electronegativity Values To Predict The Formation Of Ionic And Covalent Bonds (The Presence Of Covalent Character In Some Ionic Compounds Will Not Be Assessed) (Pauling Electronegativity Values Will Be Given Where Necessary)
- 3.42Chemical Bonding: Ionic Bonding: Define Ionic Bonding As The Electrostatic Attraction Between Oppositely Charged Ions (Positively Charged Cations And Negatively Charged Anions)
- 3.43Chemical Bonding: Ionic Bonding: Describe Ionic Bonding Including The Examples Of Sodium Chloride, Magnesium Oxide And Calcium Fluoride
- 3.44Chemical Bonding: Metallic Bonding: Define Metallic Bonding As The Electrostatic Attraction Between Positive Metal Ions And Delocalised Electrons
- 3.45Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: Define Covalent Bonding As Electrostatic Attraction Between The Nuclei Of Two Atoms And A Shared Pair Of Electrons (A) Describe Covalent Bonding In Molecules Including: • Hydrogen, H2 • Oxygen, O2 • Nitrogen, N2 • Chlorine, Cl 2 • Hydrogen Chloride, Hcl • Carbon Dioxide, Co2 • Ammonia, Nh3 • Methane, Ch4 • Ethane, C2h6 • Ethene, C2h4 (B) Understand That Elements In Period 3 Can Expand Their Octet Including In The Compounds Sulfur Dioxide, So2, Phosphorus Pentachloride, Pcl 5 , And Sulfur Hexafluoride, Sf6 (C) Describe Coordinate (Dative Covalent) Bonding, Including In The Reaction Between Ammonia And Hydrogen Chloride Gases To Form The Ammonium Ion, Nh4 + , And In The Al 2cl 6 Molecule
- 3.46Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: (A) Describe Covalent Bonds In Terms Of Orbital Overlap Giving Σ And Π Bonds: • Σ Bonds Are Formed By Direct Overlap Of Orbitals Between The Bonding Atoms • Π Bonds Are Formed By The Sideways Overlap Of Adjacent P Orbitals Above And Below The Σ Bond (B) Describe How The Σ And Π Bonds Form In Molecules Including H₂, C₂h₆, C₂h₄, Hcn And N₂ (C) Use The Concept Of Hybridisation To Describe Sp, Sp² And Sp³ Orbitals
- 3.47Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: A) Define The Terms: • Bond Energy As The Energy Required To Break One Mole Of A Particular Covalent Bond In The Gaseous State • Bond Length As The Internuclear Distance Of Two Covalently Bonded Atoms (B) Use Bond Energy Values And The Concept Of Bond Length To Compare The Reactivity Of Covalent Molecules
- 3.48Chemical Bonding: Shapes Of Molecules: State And Explain The Shapes Of, And Bond Angles In, Molecules By Using Vsepr Theory, Including As Simple Examples: • Bf3 (Trigonal Planar, 120°) • Co2 (Linear, 180°) • Ch4 (Tetrahedral, 109.5°) • Nh3 (Pyramidal, 107°) • H2o (Non-linear, 104.5°) • Sf6 (Octahedral, 90°) • Pf5 (Trigonal Bipyramidal, 120° And 90°)
- 3.49Chemical Bonding: Shapes Of Molecules: Predict The Shapes Of, And Bond Angles In, Molecules And Ions Analogous To Those Specified In 3.5.1
- 3.50Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Hydrogen Bonding, Limited To Molecules Containing N–h And O–h Groups, Including Ammonia And Water As Simple Examples (B) Use The Concept Of Hydrogen Bonding To Explain The Anomalous Properties Of H₂o (Ice And Water): • Its Relatively High Melting And Boiling Points • Its Relatively High Surface Tension • The Density Of The Solid Ice Compared With The Liquid Water
- 3.51Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: Use The Concept Of Electronegativity To Explain Bond Polarity And Dipole Moments Of Molecules
- 3.52Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Van Der Waals’ Forces As The Intermolecular Forces Between Molecular Entities Other Than Those Due To Bond Formation, And Use The Term Van Der Waals’ Forces As A Generic Term To Describe All Intermolecular Forces (B) Describe The Types Of Van Der Waals’ Forces: • Instantaneous Dipole–induced Dipole (Id-id) Forces, Also Called London Dispersion Forces • Permanent Dipole–permanent Dipole (Pd-pd) Forces, Including Hydrogen Bonding (C) Describe Hydrogen Bonding And Understand That Hydrogen Bonding Is A Special Case Of Permanent Dipole–permanent Dipole Forces Between Molecules Where Hydrogen Is Bonded To A Highly Electronegative Atom
- 3.53Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: State That, In General, Ionic, Covalent And Metallic Bonding Are Stronger Than Intermolecular Forces
- 3.54Chemical Bonding: Dot-and-cross Diagrams: Use Dot-and-cross Diagrams To Illustrate Ionic, Covalent And Coordinate Bonding Including The Representation Of Any Compounds Stated In 3.4 And 3.5 (Dot-and-cross Diagrams May Include Species With Atoms Which Have An Expanded Octet Or Species With An Odd Number Of Electrons)
- 3.55States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Explain The Origin Of Pressure In A Gas In Terms Of Collisions Between Gas Molecules And The Wall Of The Container
- 3.56States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Understand That Ideal Gases Have Zero Particle Volume And No Intermolecular Forces Of Attraction
- 3.57States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: State And Use The Ideal Gas Equation Pv = Nrt In Calculations, Including In The Determination Of Mr
- 3.58States Of Matter: Bonding And Structure: Describe, In Simple Terms, The Lattice Structure Of A Crystalline Solid Which Is: (A) Giant Ionic, Including Sodium Chloride And Magnesium Oxide (B) Simple Molecular, Including Iodine, Buckminsterfullerene C60 And Ice (C) Giant Molecular, Including Silicon(Iv) Oxide, Graphite And Diamond (D) Giant Metallic, Including Copper
- 3.59States Of Matter: Bonding And Structure: Describe, Interpret And Predict The Effect Of Different Types Of Structure And Bonding On The Physical Properties Of Substances, Including Melting Point, Boiling Point, Electrical Conductivity And Solubility
- 3.60States Of Matter: Bonding And Structure: Deduce The Type Of Structure And Bonding Present In A Substance From Given Information
- 3.61Chemical Energetics: Enthalpy Change, Δh: Understand That Chemical Reactions Are Accompanied By Enthalpy Changes And These Changes Can Be Exothermic (δh Is Negative) Or Endothermic (δh Is Positive)
- 3.62Chemical Energetics: Enthalpy Change, Δh: Construct And Interpret A Reaction Pathway Diagram, In Terms Of The Enthalpy Change Of The Reaction And Of The Activation Energy
- 3.63Chemical Energetics: Enthalpy Change, Δh: Define And Use The Terms: (A) Standard Conditions (This Syllabus Assumes That These Are 298k And 101kpa) Shown By ⦵ . (B) Enthalpy Change With Particular Reference To: Reaction, Δhr , Formation, Δhf , Combustion, Δhc , Neutralisation, Δhneut
- 3.64Chemical Energetics: Enthalpy Change, Δh: Understand That Energy Transfers Occur During Chemical Reactions Because Of The Breaking And Making Of Chemical Bonds
- 3.65Chemical Energetics: Enthalpy Change, Δh: Use Bond Energies (δh Positive, I.e. Bond Breaking) To Calculate Enthalpy Change Of Reaction, Δhr
- 3.66Chemical Energetics: Enthalpy Change, Δh: Understand That Some Bond Energies Are Exact And Some Bond Energies Are Averages
- 3.67Chemical Energetics: Enthalpy Change, Δh: Calculate Enthalpy Changes From Appropriate Experimental Results, Including The Use Of The Relationships Q = Mcδt And Δh = –mcδt/ N
- 3.68Chemical Energetics: Hess’s Law: Apply Hess’s Law To Construct Simple Energy Cycles
- 3.69Chemical Energetics: Hess’s Law: Carry Out Calculations Using Cycles And Relevant Energy Terms, Including: (A) Determining Enthalpy Changes That Cannot Be Found By Direct Experiment (B) Use Of Bond Energy Data
- 3.70Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Calculate Oxidation Numbers Of Elements In Compounds And Ions
- 3.71Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use Changes In Oxidation Numbers To Help Balance Chemical Equations
- 3.72Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Redox, Oxidation, Reduction And Disproportionation In Terms Of Electron Transfer And Changes In Oxidation Number
- 3.73Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Oxidising Agent And Reducing Agent
- 3.74Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use A Roman Numeral To Indicate The Magnitude Of The Oxidation Number Of An Element
- 3.75Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: (A) Understand What Is Meant By A Reversible Reaction (B) Understand What Is Meant By Dynamic Equilibrium In Terms Of The Rate Of Forward And Reverse Reactions Being Equal And The Concentration Of Reactants And Products Remaining Constant (C) Understand The Need For A Closed System In Order To Establish Dynamic Equilibrium
- 3.76Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Define Le Chatelier’s Principle As: If A Change Is Made To A System At Dynamic Equilibrium, The Position Of Equilibrium Moves To Minimise This Change
- 3.77Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use Le Chatelier’s Principle To Deduce Qualitatively (From Appropriate Information) The Effects Of Changes In Temperature, Concentration, Pressure Or Presence Of A Catalyst On A System At Equilibrium
- 3.78Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Concentrations, Kc
- 3.79Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Terms Mole Fraction And Partial Pressure
- 3.80Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Partial Pressures, Kp (Use Of The Relationship Between Kp And Kc Is Not Required)
- 3.81Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Kc And Kp Expressions To Carry Out Calculations (Such Calculations Will Not Require The Solving Of Quadratic Equations)
- 3.82Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Calculate The Quantities Present At Equilibrium, Given Appropriate Data
- 3.83Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: State Whether Changes In Temperature, Concentration Or Pressure Or The Presence Of A Catalyst Affect The Value Of The Equilibrium Constant For A Reaction
- 3.84Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Describe And Explain The Conditions Used In The Haber Process And The Contact Process, As Examples Of The Importance Of An Understanding Of Dynamic Equilibrium In The Chemical Industry And The Application Of Le Chatelier’s Principle
- 3.85Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Acids, Limited To Hydrochloric Acid, Hcl, Sulfuric Acid, H2so4, Nitric Acid, Hno3, Ethanoic Acid, Ch3cooh
- 3.86Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Alkalis, Limited To Sodium Hydroxide, Naoh, Potassium Hydroxide, Koh, Ammonia, Nh3
- 3.87Brønsted–lowry Theory Of Acids And Bases: Describe The Brønsted–lowry Theory Of Acids And Bases
- 3.88Brønsted–lowry Theory Of Acids And Bases: Describe Strong Acids And Strong Bases As Fully Dissociated In Aqueous Solution And Weak Acids And Weak Bases As Partially Dissociated In Aqueous Solution
- 3.89Brønsted–lowry Theory Of Acids And Bases: Appreciate That Water Has Ph Of 7, Acid Solutions Ph Of Below 7 And Alkaline Solutions Ph Of Above 7
- 3.90Brønsted–lowry Theory Of Acids And Bases: Explain Qualitatively The Differences In Behaviour Between Strong And Weak Acids Including The Reaction With A Reactive Metal And Difference In Ph Values By Use Of A Ph Meter, Universal Indicator Or Conductivity
- 3.91Brønsted–lowry Theory Of Acids And Bases: Understand That Neutralisation Reactions Occur When H+ (Aq) And Oh– (Aq) Form H2o(L)
- 3.92Brønsted–lowry Theory Of Acids And Bases: Understand That Salts Are Formed In Neutralisation Reactions
- 3.93Brønsted–lowry Theory Of Acids And Bases: Sketch The Ph Titration Curves Of Titrations Using Combinations Of Strong And Weak Acids With Strong And Weak Alkalis
- 3.94Brønsted–lowry Theory Of Acids And Bases: Select Suitable Indicators For Acid-alkali Titrations, Given Appropriate Data (Pka Values Will Not Be Used)
- 3.95Reaction Kinetics: Rate Of Reaction: Explain And Use The Term Rate Of Reaction, Frequency Of Collisions, Effective Collisions And Non-effective Collisions
- 3.96Reaction Kinetics: Rate Of Reaction: Explain Qualitatively, In Terms Of Frequency Of Effective Collisions, The Effect Of Concentration And Pressure Changes On The Rate Of A Reaction
- 3.97Reaction Kinetics: Rate Of Reaction: Use Experimental Data To Calculate The Rate Of A Reaction
- 3.98Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Define Activation Energy, Ea, As The Minimum Energy Required For A Collision To Be Effective
- 3.99Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Sketch And Use The Boltzmann Distribution To Explain The Significance Of Activation Energy
- 3.100Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Explain Qualitatively, In Terms Both Of The Boltzmann Distribution And Of Frequency Of Effective Collisions, The Effect Of Temperature Change On The Rate Of A Reaction
- 3.101Reaction Kinetics: Homogeneous And Heterogeneous Catalysts: Explain And Use The Terms Catalyst And Catalysis: (A) Explain That, In The Presence Of A Catalyst, A Reaction Has A Different Mechanism, I.e. One Of Lower Activation Energy (B) Explain This Catalytic Effect In Terms Of The Boltzmann Distribution (C) Construct And Interpret A Reaction Pathway Diagram, For A Reaction In The Presence And Absence Of An Effective Catalyst
- 3.102The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Describe Qualitatively (And Indicate The Periodicity In) The Variations In Atomic Radius, Ionic Radius, Melting Point And Electrical Conductivity Of The Elements
- 3.103The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Explain The Variation In Melting Point And Electrical Conductivity In Terms Of The Structure And Bonding Of The Elements
- 3.104The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen (To Give Na2o, Mgo, Al 2o3, P4o10, So2), Chlorine (To Give Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5) And Water (Na And Mg Only)
- 3.105The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: State And Explain The Variation In The Oxidation Number Of The Oxides (Na2o, Mgo, Al 2o3, P4o10, So2 And So3 Only) And Chlorides (Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5 Only) In Terms Of Their Outer Shell (Valence Shell) Electrons
- 3.106The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions, If Any, Of The Oxides Na2o, Mgo, Al 2o3, Sio2, P4o10, So2 And So3 With Water Including The Likely Phs Of The Solutions Obtained
- 3.107The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Acid/base Behaviour Of The Oxides Na2o, Mgo, Al 2o3, P4o10, So2 And So3 And The Hydroxides Naoh, Mg(Oh)2 And Al(Oh)3 Including, Where Relevant, Amphoteric Behaviour In Reactions With Acids And Bases (Sodium Hydroxide Only)
- 3.108The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Reactions Of The Chlorides Nacl, Mgcl 2, Al Cl 3, Sicl 4, Pcl 5 With Water Including The Likely Phs Of The Solutions Obtained
- 3.109The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Explain The Variations And Trends In 9.2.2, 9.2.3, 9.2.4 And 9.2.5 In Terms Of Bonding And Electronegativity
- 3.110The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Suggest The Types Of Chemical Bonding Present In The Chlorides And Oxides From Observations Of Their Chemical And Physical Properties
- 3.111Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen, Water And Dilute Hydrochloric And Sulfuric Acids
- 3.112Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Thermal Decomposition Of The Nitrates And Carbonates, To Include The Trend In Thermal Stabilities
- 3.113Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Make Predictions From, The Trends In Physical And Chemical Properties Of The Elements Involved In The Reactions In 10.1.1 And The Compounds Involved In 10.1.2, 10.1.3 And 10.1.5
- 3.114Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: State The Variation In The Solubilities Of The Hydroxides And Sulfates
- 3.115Group 17: Physical Properties Of The Group 17 Elements: Describe The Colours And The Trend In Volatility Of Chlorine, Bromine And Iodine
- 3.116Group 17: Physical Properties Of The Group 17 Elements: Describe And Explain The Trend In The Bond Strength Of The Halogen Molecules
- 3.117Group 17: Physical Properties Of The Group 17 Elements: Interpret The Volatility Of The Elements In Terms Of Instantaneous Dipole–induced Dipole Forces
- 3.118Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Reactivity Of The Elements As Oxidising Agents
- 3.119Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Reactions Of The Elements With Hydrogen And Explain Their Relative Reactivity In These Reactions
- 3.120Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Thermal Stabilities Of The Hydrogen Halides And Explain These In Terms Of Bond Strengths
- 3.121Group 17: Some Reactions Of The Halide Ions: Describe The Relative Reactivity Of Halide Ions As Reducing Agents
- 3.122Group 17: Some Reactions Of The Halide Ions: Describe And Explain The Reactions Of Halide Ions With: (A) Aqueous Silver Ions Followed By Aqueous Ammonia (The Formation And Formula Of The [ag(Nh3) 2] + Complex Is Not Required) (B) Concentrated Sulfuric Acid, To Include Balanced Chemical Equations
- 3.123Group 17: The Reactions Of Chlorine: Describe And Interpret, In Terms Of Changes In Oxidation Number, The Reaction Of Chlorine With Cold And With Hot Aqueous Sodium Hydroxide And Recognise These As Disproportionation Reactions
- 3.124Group 17: The Reactions Of Chlorine: Explain, Including By Use Of An Equation, The Use Of Chlorine In Water Purification To Include The Production Of The Active Species Hocl And Clo– Which Kill Bacteria
- 3.125Nitrogen And Sulfur: Nitrogen And Sulfur: Explain The Lack Of Reactivity Of Nitrogen, With Reference To Triple Bond Strength And Lack Of Polarity
- 3.126Nitrogen And Sulfur: Nitrogen And Sulfur: Describe And Explain: (A) The Basicity Of Ammonia, Using The Brønsted–lowry Theory (B) The Structure Of The Ammonium Ion And Its Formation By An Acid–base Reaction (C) The Displacement Of Ammonia From Ammonium Salts By An Acid–base Reaction
- 3.127Nitrogen And Sulfur: Nitrogen And Sulfur: State And Explain The Natural And Man-made Occurrences Of Oxides Of Nitrogen And Their Catalytic Removal From The Exhaust Gases Of Internal Combustion Engines
- 3.128Nitrogen And Sulfur: Nitrogen And Sulfur: Understand That Atmospheric Oxides Of Nitrogen (No And No2) Can React With Unburned Hydrocarbons To Form Peroxyacetyl Nitrate, Pan, Which Is A Component Of Photochemical Smog
- 3.129Nitrogen And Sulfur: Nitrogen And Sulfur: Describe The Role Of No And No2 In The Formation Of Acid Rain Both Directly And In Their Catalytic Role In The Oxidation Of Atmospheric Sulfur Dioxide
- 3.130An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Define The Term Hydrocarbon As A Compound Made Up Of C And H Atoms Only
- 3.131An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That Alkanes Are Simple Hydrocarbons With No Functional Group
- 3.132An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That The Compounds In The Table On Pages 29 And 30 Contain A Functional Group Which Dictates Their Physical And Chemical Properties
- 3.133An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Interpret And Use The General, Structural, Displayed And Skeletal Formulas Of The Classes Of Compound Stated In The Table On Pages 29 And 30
- 3.134An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand And Use Systematic Nomenclature Of Simple Aliphatic Organic Molecules With Functional Groups Detailed In The Table On Pages 29 And 30, Up To Six Carbon Atoms (Six Plus Six For Esters, Straight Chains Only For Esters And Nitriles)
- 3.135An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Deduce The Molecular And/or Empirical Formula Of A Compound, Given Its Structural, Displayed Or Skeletal Formula
- 3.136An Introduction To As Level Organic Chemistry: Characteristic Organic Reactions: Interpret And Use The Following Terminology Associated With Types Of Organic Compounds And Reactions: (A) Homologous Series (B) Saturated And Unsaturated (C) Homolytic And Heterolytic Fission (D) Free Radical, Initiation, Propagation, Termination (E) Nucleophile, Electrophile, Nucleophilic, Electrophilic (F) Addition, Substitution, Elimination, Hydrolysis, Condensation (G) Oxidation And Reduction (In Equations For Organic Redox Reactions, The Symbol [o] Can Be Used To Represent One Atom Of Oxygen From An Oxidising Agent And The Symbol [h] To Represent One Atom Of Hydrogen From A Reducing Agent)
- 3.137An Introduction To As Level Organic Chemistry: Characteristic Organic Reactions: Understand And Use The Following Terminology Associated With Types Of Organic Mechanisms: (A) Free-radical Substitution (B) Electrophilic Addition (C) Nucleophilic Substitution (D) Nucleophilic Addition (In Organic Reaction Mechanisms, The Use Of Curly Arrows To Represent Movement Of Electron Pairs Is Expected; The Arrow Should Begin At A Bond Or A Lone Pair Of Electrons)
- 3.138An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe Organic Molecules As Either Straight-chained, Branched Or Cyclic
- 3.139An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe And Explain The Shape Of, And Bond Angles In, Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 3.140An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe The Arrangement Of Σ And Π Bonds In Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 3.141An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Understand And Use The Term Planar When Describing The Arrangement Of Atoms In Organic Molecules, For Example Ethene
- 3.142An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Structural Isomerism And Its Division Into Chain, Positional And Functional Group Isomerism
- 3.143An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Stereoisomerism And Its Division Into Geometrical (Cis/trans) And Optical Isomerism (Use Of E/z Nomenclature Is Acceptable But Is Not Required)
- 3.144An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Geometrical (Cis/trans) Isomerism In Alkenes, And Explain Its Origin In Terms Of Restricted Rotation Due To The Presence Of Π Bonds
- 3.145An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Explain What Is Meant By A Chiral Centre And That Such A Centre Gives Rise To Two Optical Isomers (Enantiomers) (Candidates Should Appreciate That Compounds Can Contain More Than One Chiral Centre, But Knowledge Of Meso Compounds, Or Nomenclature Such As Diastereoisomers Is Not Required.)
- 3.146An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Identify Chiral Centres And Geometrical (Cis/trans) Isomerism In A Molecule Of Given Structural Formula Including Cyclic Compounds
- 3.147An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Deduce The Possible Isomers For An Organic Molecule Of Known Molecular Formula
- 3.148Hydrocarbons: Alkanes: Recall The Reactions (Reagents And Conditions) By Which Alkanes Can Be Produced: (A) Addition Of Hydrogen To An Alkene In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (B) Cracking Of A Longer Chain Alkane, Heat With Al 2o3
- 3.149Hydrocarbons: Alkanes: Describe: (A) The Complete And Incomplete Combustion Of Alkanes (B) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane
- 3.150Hydrocarbons: Alkanes: Describe The Mechanism Of Free-radical Substitution With Reference To The Initiation, Propagation And Termination Steps
- 3.151Hydrocarbons: Alkanes: Suggest How Cracking Can Be Used To Obtain More Useful Alkanes And Alkenes Of Lower Mr From Heavier Crude Oil Fractions
- 3.152Hydrocarbons: Alkanes: Understand The General Unreactivity Of Alkanes, Including Towards Polar Reagents In Terms Of The Strength Of The C–h Bonds And Their Relative Lack Of Polarity
- 3.153Hydrocarbons: Alkanes: Recognise The Environmental Consequences Of Carbon Monoxide, Oxides Of Nitrogen And Unburnt Hydrocarbons Arising From The Combustion Of Alkanes In The Internal Combustion Engine And Of Their Catalytic Removal
- 3.154Hydrocarbons: Alkenes: Recall The Reactions (Including Reagents And Conditions) By Which Alkenes Can Be Produced: (A) Elimination Of Hx From A Halogenoalkane By Ethanolic Naoh And Heat (B) Dehydration Of An Alcohol, By Using A Heated Catalyst (E.g. Al 2o3) Or A Concentrated Acid (E.g. Concentrated H2so4) (C) Cracking Of A Longer Chain Alkane
- 3.155Hydrocarbons: Alkenes: Describe The Following Reactions Of Alkenes: (A) The Electrophilic Addition Of (I) Hydrogen In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (Ii) Steam, H2o(G) And H3po4 Catalyst (Iii) A Hydrogen Halide, Hx(G), At Room Temperature (Iv) A Halogen, X2 (B) The Oxidation By Cold Dilute Acidified Kmno4 To Form The Diol (C) The Oxidation By Hot Concentrated Acidified Kmno4 Leading To The Rupture Of The Carbon–carbon Double Bond And The Identities Of The Subsequent Products To Determine The Position Of Alkene Linkages In Larger Molecules (D) Addition Polymerisation Exemplified By The Reactions Of Ethene And Propene
- 3.156Hydrocarbons: Alkenes: Describe The Use Of Aqueous Bromine To Show The Presence Of A C=c Bond
- 3.157Hydrocarbons: Alkenes: Describe The Mechanism Of Electrophilic Addition In Alkenes, Using Bromine/ethene And Hydrogen Bromide/propene As Examples
- 3.158Hydrocarbons: Alkenes: Describe And Explain The Inductive Effects Of Alkyl Groups On The Stability Of Primary, Secondary And Tertiary Cations Formed During Electrophilic Addition (This Should Be Used To Explain Markovnikov Addition)
- 3.159Halogen Compounds: Halogenoalkanes: Recall The Reactions (Reagents And Conditions) By Which Halogenoalkanes Can Be Produced: (A) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane (B) Electrophilic Addition Of An Alkene With A Halogen, X2, Or Hydrogen Halide, Hx(G), At Room Temperature (C) Substitution Of An Alcohol, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2
- 3.160Halogen Compounds: Halogenoalkanes: Classify Halogenoalkanes Into Primary, Secondary And Tertiary
- 3.161Halogen Compounds: Halogenoalkanes: Describe The Following Nucleophilic Substitution Reactions: (A) The Reaction With Naoh(Aq) And Heat To Produce An Alcohol (B) The Reaction With Kcn In Ethanol And Heat To Produce A Nitrile (C) The Reaction With Nh3 In Ethanol Heated Under Pressure To Produce An Amine (D) The Reaction With Aqueous Silver Nitrate In Ethanol As A Method Of Identifying The Halogen Present As Exemplified By Bromoethane
- 3.162Halogen Compounds: Halogenoalkanes: Describe The Elimination Reaction With Naoh In Ethanol And Heat To Produce An Alkene As Exemplified By Bromoethane
- 3.163Halogen Compounds: Halogenoalkanes: Describe The Sn1 And Sn2 Mechanisms Of Nucleophilic Substitution In Halogenoalkanes Including The Inductive Effects Of Alkyl Groups
- 3.164Halogen Compounds: Halogenoalkanes: Recall That Primary Halogenoalkanes Tend To React Via The Sn2 Mechanism; Tertiary Halogenoalkanes Via The Sn1 Mechanism; And Secondary Halogenoalkanes By A Mixture Of The Two, Depending On Structure
- 3.165Halogen Compounds: Halogenoalkanes: Describe And Explain The Different Reactivities Of Halogenoalkanes (With Particular Reference To The Relative Strengths Of The C–x Bonds As Exemplified By The Reactions Of Halogenoalkanes With Aqueous Silver Nitrates)
- 3.166Hydroxy Compounds: Alcohols: Recall The Reactions (Reagents And Conditions) By Which Alcohols Can Be Produced: (A) Electrophilic Addition Of Steam To An Alkene, H2o(G) And H3po4 Catalyst (B) Reaction Of Alkenes With Cold Dilute Acidified Potassium Manganate(Vii) To Form A Diol (C) Substitution Of A Halogenoalkane Using Naoh(Aq) And Heat (D) Reduction Of An Aldehyde Or Ketone Using Nabh4 Or Lialh4 (E) Reduction Of A Carboxylic Acid Using Lialh4 (F) Hydrolysis Of An Ester Using Dilute Acid Or Dilute Alkali And Heat
- 3.167Hydroxy Compounds: Alcohols: Describe: (A) The Reaction With Oxygen (Combustion) (B) Substitution To Form Halogenoalkanes, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2 (C) The Reaction With Na(S) (D) Oxidation With Acidified K2cr2o7 Or Acidified Kmno4 To: (I) Carbonyl Compounds By Distillation (Ii) Carboxylic Acids By Refluxing (Primary Alcohols Give Aldehydes Which Can Be Further Oxidised To Carboxylic Acids, Secondary Alcohols Give Ketones, Tertiary Alcohols Cannot Be Oxidised) (E) Dehydration To An Alkene, By Using A Heated Catalyst, E.g. Al 2o3 Or A Concentrated Acid (F) Formation Of Esters By Reaction With Carboxylic Acids And Concentrated H2so4 As Catalyst As Exemplified By Ethanol
- 3.168Hydroxy Compounds: Alcohols: (A) Classify Alcohols As Primary, Secondary And Tertiary Alcohols, To Include Examples With More Than One Alcohol Group (B) State Characteristic Distinguishing Reactions, E.g. Mild Oxidation With Acidified K2cr2o7 , Colour Change From Orange To Green
- 3.169Hydroxy Compounds: Alcohols: Deduce The Presence Of A Ch3ch(Oh)– Group In An Alcohol, Ch3ch(Oh)–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 3.170Hydroxy Compounds: Alcohols: Explain The Acidity Of Alcohols Compared With Water
- 3.171Carbonyl Compounds: Aldehydes And Ketones: Recall The Reactions (Reagents And Conditions) By Which Aldehydes And Ketones Can Be Produced: (A) The Oxidation Of Primary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Aldehydes (B) The Oxidation Of Secondary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Ketones
- 3.172Carbonyl Compounds: Aldehydes And Ketones: Describe: (A) The Reduction Of Aldehydes And Ketones Using Nabh4 Or Lialh4 To Produce Alcohols (B) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat To Produce Hydroxynitriles As Exemplified By Ethanal And Propanone
- 3.173Carbonyl Compounds: Aldehydes And Ketones: Describe The Mechanism Of The Nucleophilic Addition Reactions Of Hydrogen Cyanide With Aldehydes And Ketones In 17.1.2(B)
- 3.174Carbonyl Compounds: Aldehydes And Ketones: Describe The Use Of 2,4-dinitrophenylhydrazine (2,4-dnph Reagent) To Detect The Presence Of Carbonyl Compounds
- 3.175Carbonyl Compounds: Aldehydes And Ketones: Deduce The Nature (Aldehyde Or Ketone) Of An Unknown Carbonyl Compound From The Results Of Simple Tests (Fehling’s And Tollens’ Reagents; Ease Of Oxidation)
- 3.176Carbonyl Compounds: Aldehydes And Ketones: Deduce The Presence Of A Ch3co– Group In An Aldehyde Or Ketone, Ch3co–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 3.177Carboxylic Acids And Derivatives: Carboxylic Acids: Recall The Reactions By Which Carboxylic Acids Can Be Produced: (A) Oxidation Of Primary Alcohols And Aldehydes With Acidified K2cr2o7 Or Acidified Kmno4 And Refluxing (B) Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification (C) Hydrolysis Of Esters With Dilute Acid Or Dilute Alkali And Heat Followed By Acidification
- 3.178Carboxylic Acids And Derivatives: Carboxylic Acids: Describe: (A) The Redox Reaction With Reactive Metals To Produce A Salt And H2(G) (B) The Neutralisation Reaction With Alkalis To Produce A Salt And H2o(L ) (C) The Acid–base Reaction With Carbonates To Produce A Salt And H2o(L) And Co2(G) (D) Esterification With Alcohols With Concentrated H2so4 As Catalyst (E) Reduction By Lialh4 To Form A Primary Alcohol
- 3.179Carboxylic Acids And Derivatives: Esters: Recall The Reaction (Reagents And Conditions) By Which Esters Can Be Produced: (A) The Condensation Reaction Between An Alcohol And A Carboxylic Acid With Concentrated H₂so₄ As Catalyst
- 3.180Carboxylic Acids And Derivatives: Esters: Describe The Hydrolysis Of Esters By Dilute Acid And By Dilute Alkali And Heat
- 3.181Nitrogen Compounds: Primary Amines: Recall The Reactions By Which Amines Can Be Produced: (A) Reaction Of A Halogenoalkane With Nh₃ In Ethanol Heated Under Pressure Classification Of Amines Will Not Be Tested At As Level.
- 3.182Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Nitriles Can Be Produced: (A) Reaction Of A Halogenoalkane With Kcn In Ethanol And Heat
- 3.183Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Hydroxynitriles Can Be Produced: (A) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat
- 3.184Nitrogen Compounds: Nitriles And Hydroxynitriles: Describe The Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification To Produce A Carboxylic Acid
- 3.185Polymerisation: Addition Polymerisation: Describe Addition Polymerisation As Exemplified By Poly(Ethene) And Poly(Chloroethene), Pvc
- 3.186Polymerisation: Addition Polymerisation: Deduce The Repeat Unit Of An Addition Polymer Obtained From A Given Monomer
- 3.187Polymerisation: Addition Polymerisation: Identify The Monomer(S) Present In A Given Section Of An Addition Polymer Molecule
- 3.188Polymerisation: Addition Polymerisation: Recognise The Difficulty Of The Disposal Of Poly(Alkene)s, I.e. Non-biodegradability And Harmful Combustion Products
- 3.189Organic Synthesis: Organic Synthesis: For An Organic Molecule Containing Several Functional Groups: (A) Identify Organic Functional Groups Using The Reactions In The Syllabus (B) Predict Properties And Reactions
- 3.190Organic Synthesis: Organic Synthesis: Devise Multi-step Synthetic Routes For Preparing Organic Molecules Using The Reactions In The Syllabus
- 3.191Organic Synthesis: Organic Synthesis: Analyse A Given Synthetic Route In Terms Of Type Of Reaction And Reagents Used For Each Step Of It, And Possible By-products Analysis
- 3.192Analytical Techniques: Infrared Spectroscopy: Analyse An Infrared Spectrum Of A Simple Molecule To Identify Functional Groups (See The Data Section For The Functional Groups Required)
- 3.193Analytical Techniques: Mass Spectrometry: Analyse Mass Spectra In Terms Of M/e Values And Isotopic Abundances (Knowledge Of The Working Of The Mass Spectrometer Is Not Required)
- 3.194Analytical Techniques: Mass Spectrometry: Calculate The Relative Atomic Mass Of An Element Given The Relative Abundances Of Its Isotopes, Or Its Mass Spectrum
- 3.195Analytical Techniques: Mass Spectrometry: Deduce The Molecular Mass Of An Organic Molecule From The Molecular Ion Peak In A Mass Spectrum
- 3.196Analytical Techniques: Mass Spectrometry: Suggest The Identity Of Molecules Formed By Simple Fragmentation In A Given Mass Spectrum
- 3.197Analytical Techniques: Mass Spectrometry: Deduce The Number Of Carbon Atoms, N, In A Compound Using The [m + 1]+ Peak And The Formula N = 100 × Abundance Of [m + 1]+ Ion 1.1 × Abundance Of M+ Ion
- 3.198Analytical Techniques: Mass Spectrometry: Deduce The Presence Of Bromine And Chlorine Atoms In A Compound Using The [m + 2]+ Peak
- Video Lectures For The ContentVideo Lectures Covering Course Content In Detail22
- 4.0Atomic Structure
- 4.1Atoms, Molecules And Stoichiometry
- 4.2Chemical Bonding
- 4.3States of Matter
- 4.4Chemical Energetics
- 4.5Electrochemistry
- 4.6Equilibria
- 4.7Reaction Kinetics
- 4.8The Periodic Table: Chemical Periodicity
- 4.9Group 2
- 4.10Group 17
- 4.11Nitrogen And Sulfur
- 4.12An Introduction To AS Level Organic Chemistry
- 4.13Hydrocarbons
- 4.14Halogen Compounds
- 4.15Hydroxy Compounds
- 4.16Carbonyl Compounds
- 4.17Carboxylic Acids And Derivatives
- 4.18Nitrogen Compounds
- 4.19Polymerisation
- 4.20Organic Synthesis
- 4.21Analytical Techniques
- QuizzesShort Quizzes To Auto-Test Your Knowledge of The Syllabus22
- 5.0Atomic Structure10 Minutes0 Questions
- 5.1Atoms, Molecules And Stoichiometry10 Minutes0 Questions
- 5.2Chemical Bonding10 Minutes0 Questions
- 5.3States of Matter10 Minutes0 Questions
- 5.4Chemical Energetics10 Minutes0 Questions
- 5.5Electrochemistry10 Minutes0 Questions
- 5.6Equilibria10 Minutes0 Questions
- 5.7Reaction Kinetics10 Minutes0 Questions
- 5.8The Periodic Table: Chemical Periodicity10 Minutes0 Questions
- 5.9Group 210 Minutes0 Questions
- 5.10Group 1710 Minutes0 Questions
- 5.11Nitrogen And Sulfur10 Minutes0 Questions
- 5.12Hydrocarbons10 Minutes0 Questions
- 5.13Halogen Compounds10 Minutes0 Questions
- 5.14Hydroxy Compounds10 Minutes0 Questions
- 5.15Carbonyl Compounds10 Minutes0 Questions
- 5.16Carboxylic Acids And Derivatives10 Minutes0 Questions
- 5.17Nitrogen Compounds10 Minutes0 Questions
- 5.18Polymerisation10 Minutes0 Questions
- 5.19Organic Synthesis10 Minutes0 Questions
- 5.20Analytical Techniques10 Minutes0 Questions
- 5.21Quiz Atomic Structure
- Quizzes For PreparationQuizzes With Detailed Explained Answers And Common Mistakes Discussed In Detail198
- 6.1Atomic Structure: Particles In The Atom And Atomic Radius: Understand That Atoms Are Mostly Empty Space Surrounding A Very Small, Dense Nucleus That Contains Protons And Neutrons; Electrons Are Found In Shells In The Empty Space Around The Nucleus
- 6.2Atomic Structure: Particles In The Atom And Atomic Radius: Identify And Describe Protons, Neutrons And Electrons In Terms Of Their Relative Charges And Relative Masses
- 6.3Atomic Structure: Particles In The Atom And Atomic Radius: Understand The Terms Atomic And Proton Number; Mass And Nucleon Number
- 6.4Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Distribution Of Mass And Charge Within An Atom
- 6.5Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Behaviour Of Beams Of Protons, Neutrons And Electrons Moving At The Same Velocity In An Electric Field
- 6.6Atomic Structure: Particles In The Atom And Atomic Radius: Determine The Numbers Of Protons, Neutrons And Electrons Present In Both Atoms And Ions Given Atomic Or Proton Number, Mass Or Nucleon Number And Charge
- 6.7Atomic Structure: Particles In The Atom And Atomic Radius: State And Explain Qualitatively The Variations In Atomic Radius And Ionic Radius Across A Period And Down A Group
- 6.8Atomic Structure: Isotopes: Define The Term Isotope In Terms Of Numbers Of Protons And Neutrons
- 6.9Atomic Structure: Isotopes: Understand The Notation X Ya For Isotopes, Where X Is The Mass Or Nucleon Number And Y Is The Atomic Or Proton Number
- 6.10Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have The Same Chemical Properties
- 6.11Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have Different Physical Properties, Limited To Mass And Density
- 6.12Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand The Terms: • Shells, Sub-shells And Orbitals • Principal Quantum Number (N) • Ground State, Limited To Electronic Configuration
- 6.13Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Order Of Increasing Energy Of The Sub-shells Within The First Three Shells And The 4s And 4p Sub-shells
- 6.14Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Electronic Configurations To Include The Number Of Electrons In Each Shell, Sub-shell And Orbital
- 6.15Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Explain The Electronic Configurations In Terms Of Energy Of The Electrons And Inter-electron Repulsion
- 6.16Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Determine The Electronic Configuration Of Atoms And Ions Given The Atomic Or Proton Number And Charge, Using Either Of The Following Conventions: E.g. For Fe: 1s2 2s2 2p6 3s2 3p6 3d6 4s2 (Full Electronic Configuration) Or [ar] 3d6 4s2 (Shorthand Electronic Configuration)
- 6.17Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand And Use The Electrons In Boxes Notation E.g. For Fe: [ar]
- 6.18Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe And Sketch The Shapes Of S And P Orbitals
- 6.19Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe A Free Radical As A Species With One Or More Unpaired Electrons
- 6.20Atomic Structure: Ionisation Energy: Define And Use The Term First Ionisation Energy, Ie
- 6.21Atomic Structure: Ionisation Energy: Construct Equations To Represent First, Second And Subsequent Ionisation Energies
- 6.22Atomic Structure: Ionisation Energy: Identify And Explain The Trends In Ionisation Energies Across A Period And Down A Group Of The Periodic Table
- 6.23Atomic Structure: Ionisation Energy: Identify And Explain The Variation In Successive Ionisation Energies Of An Element
- 6.24Atomic Structure: Ionisation Energy: Understand That Ionisation Energies Are Due To The Attraction Between The Nucleus And The Outer Electron
- 6.25Atomic Structure: Ionisation Energy: Explain The Factors Influencing The Ionisation Energies Of Elements In Terms Of Nuclear Charge, Atomic/ionic Radius, Shielding By Inner Shells And Sub-shells And Spin-pair Repulsion
- 6.26Atomic Structure: Ionisation Energy: Deduce The Electronic Configurations Of Elements Using Successive Ionisation Energy Data
- 6.27Atomic Structure: Ionisation Energy: Deduce The Position Of An Element In The Periodic Table Using Successive Ionisation Energy Data
- 6.28Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define The Unified Atomic Mass Unit As One Twelfth Of The Mass Of A Carbon-12 Atom
- 6.29Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define Relative Atomic Mass, Ar , Relative Isotopic Mass, Relative Molecular Mass, Mr , And Relative Formula Mass In Terms Of The Unified Atomic Mass Unit
- 6.30Atoms, Molecules And Stoichiometry: The Mole And The Avogadro Constant: Define And Use The Term Mole In Terms Of The Avogadro Constant
- 6.31Atoms, Molecules And Stoichiometry: Formulas: Write Formulas Of Ionic Compounds From Ionic Charges And Oxidation Numbers (Shown By A Roman Numeral), Including: (A) The Prediction Of Ionic Charge From The Position Of An Element In The Periodic Table (B) Recall Of The Names And Formulas For The Following Ions: No3 – , Co3 2–, So4 2–, Oh– , Nh4 + , Zn2+, Ag+ , Hco3 – , Po4 3–
- 6.32Atoms, Molecules And Stoichiometry: Formulas: (A) Write And Construct Equations (Which Should Be Balanced), Including Ionic Equations (Which Should Not Include Spectator Ions) (B) Use Appropriate State Symbols In Equations
- 6.33Atoms, Molecules And Stoichiometry: Formulas: Define And Use The Terms Empirical And Molecular Formula
- 6.34Atoms, Molecules And Stoichiometry: Formulas: Understand And Use The Terms Anhydrous, Hydrated And Water Of Crystallisation
- 6.35Atoms, Molecules And Stoichiometry: Formulas: Calculate Empirical And Molecular Formulas, Using Given Data
- 6.36Atoms, Molecules And Stoichiometry: Reacting Masses And Volumes (Of Solutions And Gases): Perform Calculations Including Use Of The Mole Concept, Involving: (A) Reacting Masses (From Formulas And Equations) Including Percentage Yield Calculations (B) Volumes Of Gases (E.g. In The Burning Of Hydrocarbons) (C) Volumes And Concentrations Of Solutions (D) Limiting Reagent And Excess Reagent (When Performing Calculations, Candidates’ Answers Should Reflect The Number Of Significant Figures Given Or Asked For In The Question. When Rounding Up Or Down, Candidates Should Ensure That Significant Figures Are Neither Lost Unnecessarily Nor Used Beyond What Is Justified (See Also Mathematical Requirements Section).) (E) Deduce Stoichiometric Relationships From Calculations Such As Those In 2.4.1(A)–(D)
- 6.37Chemical Bonding: Electronegativity And Bonding: Define Electronegativity As The Power Of An Atom To Attract Electrons To Itself
- 6.38Chemical Bonding: Electronegativity And Bonding: Define Electronegativity As The Power Of An Atom To Attract Electrons To Itself
- 6.39Chemical Bonding: Electronegativity And Bonding: Explain The Factors Influencing The Electronegativities Of The Elements In Terms Of Nuclear Charge, Atomic Radius And Shielding By Inner Shells And Sub-shells
- 6.40Chemical Bonding: Electronegativity And Bonding: State And Explain The Trends In Electronegativity Across A Period And Down A Group Of The Periodic Table
- 6.41Chemical Bonding: Electronegativity And Bonding: Use The Differences In Pauling Electronegativity Values To Predict The Formation Of Ionic And Covalent Bonds (The Presence Of Covalent Character In Some Ionic Compounds Will Not Be Assessed) (Pauling Electronegativity Values Will Be Given Where Necessary)
- 6.42Chemical Bonding: Ionic Bonding: Define Ionic Bonding As The Electrostatic Attraction Between Oppositely Charged Ions (Positively Charged Cations And Negatively Charged Anions)
- 6.43Chemical Bonding: Ionic Bonding: Describe Ionic Bonding Including The Examples Of Sodium Chloride, Magnesium Oxide And Calcium Fluoride
- 6.44Chemical Bonding: Metallic Bonding: Define Metallic Bonding As The Electrostatic Attraction Between Positive Metal Ions And Delocalised Electrons
- 6.45Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: Define Covalent Bonding As Electrostatic Attraction Between The Nuclei Of Two Atoms And A Shared Pair Of Electrons (A) Describe Covalent Bonding In Molecules Including: • Hydrogen, H2 • Oxygen, O2 • Nitrogen, N2 • Chlorine, Cl 2 • Hydrogen Chloride, Hcl • Carbon Dioxide, Co2 • Ammonia, Nh3 • Methane, Ch4 • Ethane, C2h6 • Ethene, C2h4 (B) Understand That Elements In Period 3 Can Expand Their Octet Including In The Compounds Sulfur Dioxide, So2, Phosphorus Pentachloride, Pcl 5 , And Sulfur Hexafluoride, Sf6 (C) Describe Coordinate (Dative Covalent) Bonding, Including In The Reaction Between Ammonia And Hydrogen Chloride Gases To Form The Ammonium Ion, Nh4 + , And In The Al 2cl 6 Molecule
- 6.46Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: (A) Describe Covalent Bonds In Terms Of Orbital Overlap Giving Σ And Π Bonds: • Σ Bonds Are Formed By Direct Overlap Of Orbitals Between The Bonding Atoms • Π Bonds Are Formed By The Sideways Overlap Of Adjacent P Orbitals Above And Below The Σ Bond (B) Describe How The Σ And Π Bonds Form In Molecules Including H₂, C₂h₆, C₂h₄, Hcn And N₂ (C) Use The Concept Of Hybridisation To Describe Sp, Sp² And Sp³ Orbitals
- 6.47Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: A) Define The Terms: • Bond Energy As The Energy Required To Break One Mole Of A Particular Covalent Bond In The Gaseous State • Bond Length As The Internuclear Distance Of Two Covalently Bonded Atoms (B) Use Bond Energy Values And The Concept Of Bond Length To Compare The Reactivity Of Covalent Molecules
- 6.48Chemical Bonding: Shapes Of Molecules: State And Explain The Shapes Of, And Bond Angles In, Molecules By Using Vsepr Theory, Including As Simple Examples: • Bf3 (Trigonal Planar, 120°) • Co2 (Linear, 180°) • Ch4 (Tetrahedral, 109.5°) • Nh3 (Pyramidal, 107°) • H2o (Non-linear, 104.5°) • Sf6 (Octahedral, 90°) • Pf5 (Trigonal Bipyramidal, 120° And 90°)
- 6.49Chemical Bonding: Shapes Of Molecules: Predict The Shapes Of, And Bond Angles In, Molecules And Ions Analogous To Those Specified In 3.5.1
- 6.50Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Hydrogen Bonding, Limited To Molecules Containing N–h And O–h Groups, Including Ammonia And Water As Simple Examples (B) Use The Concept Of Hydrogen Bonding To Explain The Anomalous Properties Of H₂o (Ice And Water): • Its Relatively High Melting And Boiling Points • Its Relatively High Surface Tension • The Density Of The Solid Ice Compared With The Liquid Water
- 6.51Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: Use The Concept Of Electronegativity To Explain Bond Polarity And Dipole Moments Of Molecules
- 6.52Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Van Der Waals’ Forces As The Intermolecular Forces Between Molecular Entities Other Than Those Due To Bond Formation, And Use The Term Van Der Waals’ Forces As A Generic Term To Describe All Intermolecular Forces (B) Describe The Types Of Van Der Waals’ Forces: • Instantaneous Dipole–induced Dipole (Id-id) Forces, Also Called London Dispersion Forces • Permanent Dipole–permanent Dipole (Pd-pd) Forces, Including Hydrogen Bonding (C) Describe Hydrogen Bonding And Understand That Hydrogen Bonding Is A Special Case Of Permanent Dipole–permanent Dipole Forces Between Molecules Where Hydrogen Is Bonded To A Highly Electronegative Atom
- 6.53Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: State That, In General, Ionic, Covalent And Metallic Bonding Are Stronger Than Intermolecular Forces
- 6.54Chemical Bonding: Dot-and-cross Diagrams: Use Dot-and-cross Diagrams To Illustrate Ionic, Covalent And Coordinate Bonding Including The Representation Of Any Compounds Stated In 3.4 And 3.5 (Dot-and-cross Diagrams May Include Species With Atoms Which Have An Expanded Octet Or Species With An Odd Number Of Electrons)
- 6.55States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Explain The Origin Of Pressure In A Gas In Terms Of Collisions Between Gas Molecules And The Wall Of The Container
- 6.56States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Understand That Ideal Gases Have Zero Particle Volume And No Intermolecular Forces Of Attraction
- 6.57States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: State And Use The Ideal Gas Equation Pv = Nrt In Calculations, Including In The Determination Of Mr
- 6.58States Of Matter: Bonding And Structure: Describe, In Simple Terms, The Lattice Structure Of A Crystalline Solid Which Is: (A) Giant Ionic, Including Sodium Chloride And Magnesium Oxide (B) Simple Molecular, Including Iodine, Buckminsterfullerene C60 And Ice (C) Giant Molecular, Including Silicon(Iv) Oxide, Graphite And Diamond (D) Giant Metallic, Including Copper
- 6.59States Of Matter: Bonding And Structure: Describe, Interpret And Predict The Effect Of Different Types Of Structure And Bonding On The Physical Properties Of Substances, Including Melting Point, Boiling Point, Electrical Conductivity And Solubility
- 6.60States Of Matter: Bonding And Structure: Deduce The Type Of Structure And Bonding Present In A Substance From Given Information
- 6.61Chemical Energetics: Enthalpy Change, Δh: Understand That Chemical Reactions Are Accompanied By Enthalpy Changes And These Changes Can Be Exothermic (δh Is Negative) Or Endothermic (δh Is Positive)
- 6.62Chemical Energetics: Enthalpy Change, Δh: Construct And Interpret A Reaction Pathway Diagram, In Terms Of The Enthalpy Change Of The Reaction And Of The Activation Energy
- 6.63Chemical Energetics: Enthalpy Change, Δh: Define And Use The Terms: (A) Standard Conditions (This Syllabus Assumes That These Are 298k And 101kpa) Shown By ⦵ . (B) Enthalpy Change With Particular Reference To: Reaction, Δhr , Formation, Δhf , Combustion, Δhc , Neutralisation, Δhneut
- 6.64Chemical Energetics: Enthalpy Change, Δh: Understand That Energy Transfers Occur During Chemical Reactions Because Of The Breaking And Making Of Chemical Bonds
- 6.65Chemical Energetics: Enthalpy Change, Δh: Use Bond Energies (δh Positive, I.e. Bond Breaking) To Calculate Enthalpy Change Of Reaction, Δhr
- 6.66Chemical Energetics: Enthalpy Change, Δh: Understand That Some Bond Energies Are Exact And Some Bond Energies Are Averages
- 6.67Chemical Energetics: Enthalpy Change, Δh: Calculate Enthalpy Changes From Appropriate Experimental Results, Including The Use Of The Relationships Q = Mcδt And Δh = –mcδt/ N
- 6.68Chemical Energetics: Hess’s Law: Apply Hess’s Law To Construct Simple Energy Cycles
- 6.69Chemical Energetics: Hess’s Law: Carry Out Calculations Using Cycles And Relevant Energy Terms, Including: (A) Determining Enthalpy Changes That Cannot Be Found By Direct Experiment (B) Use Of Bond Energy Data
- 6.70Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Calculate Oxidation Numbers Of Elements In Compounds And Ions
- 6.71Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use Changes In Oxidation Numbers To Help Balance Chemical Equations
- 6.72Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Redox, Oxidation, Reduction And Disproportionation In Terms Of Electron Transfer And Changes In Oxidation Number
- 6.73Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Oxidising Agent And Reducing Agent
- 6.74Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use A Roman Numeral To Indicate The Magnitude Of The Oxidation Number Of An Element
- 6.75Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: (A) Understand What Is Meant By A Reversible Reaction (B) Understand What Is Meant By Dynamic Equilibrium In Terms Of The Rate Of Forward And Reverse Reactions Being Equal And The Concentration Of Reactants And Products Remaining Constant (C) Understand The Need For A Closed System In Order To Establish Dynamic Equilibrium
- 6.76Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Define Le Chatelier’s Principle As: If A Change Is Made To A System At Dynamic Equilibrium, The Position Of Equilibrium Moves To Minimise This Change
- 6.77Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use Le Chatelier’s Principle To Deduce Qualitatively (From Appropriate Information) The Effects Of Changes In Temperature, Concentration, Pressure Or Presence Of A Catalyst On A System At Equilibrium
- 6.78Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Concentrations, Kc
- 6.79Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Terms Mole Fraction And Partial Pressure
- 6.80Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Partial Pressures, Kp (Use Of The Relationship Between Kp And Kc Is Not Required)
- 6.81Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Kc And Kp Expressions To Carry Out Calculations (Such Calculations Will Not Require The Solving Of Quadratic Equations)
- 6.82Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Calculate The Quantities Present At Equilibrium, Given Appropriate Data
- 6.83Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: State Whether Changes In Temperature, Concentration Or Pressure Or The Presence Of A Catalyst Affect The Value Of The Equilibrium Constant For A Reaction
- 6.84Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Describe And Explain The Conditions Used In The Haber Process And The Contact Process, As Examples Of The Importance Of An Understanding Of Dynamic Equilibrium In The Chemical Industry And The Application Of Le Chatelier’s Principle
- 6.85Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Acids, Limited To Hydrochloric Acid, Hcl, Sulfuric Acid, H2so4, Nitric Acid, Hno3, Ethanoic Acid, Ch3cooh
- 6.86Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Alkalis, Limited To Sodium Hydroxide, Naoh, Potassium Hydroxide, Koh, Ammonia, Nh3
- 6.87Brønsted–lowry Theory Of Acids And Bases: Describe The Brønsted–lowry Theory Of Acids And Bases
- 6.88Brønsted–lowry Theory Of Acids And Bases: Describe Strong Acids And Strong Bases As Fully Dissociated In Aqueous Solution And Weak Acids And Weak Bases As Partially Dissociated In Aqueous Solution
- 6.89Brønsted–lowry Theory Of Acids And Bases: Appreciate That Water Has Ph Of 7, Acid Solutions Ph Of Below 7 And Alkaline Solutions Ph Of Above 7
- 6.90Brønsted–lowry Theory Of Acids And Bases: Explain Qualitatively The Differences In Behaviour Between Strong And Weak Acids Including The Reaction With A Reactive Metal And Difference In Ph Values By Use Of A Ph Meter, Universal Indicator Or Conductivity
- 6.91Brønsted–lowry Theory Of Acids And Bases: Understand That Neutralisation Reactions Occur When H+ (Aq) And Oh– (Aq) Form H2o(L)
- 6.92Brønsted–lowry Theory Of Acids And Bases: Understand That Salts Are Formed In Neutralisation Reactions
- 6.93Brønsted–lowry Theory Of Acids And Bases: Sketch The Ph Titration Curves Of Titrations Using Combinations Of Strong And Weak Acids With Strong And Weak Alkalis
- 6.94Brønsted–lowry Theory Of Acids And Bases: Select Suitable Indicators For Acid-alkali Titrations, Given Appropriate Data (Pka Values Will Not Be Used)
- 6.95Reaction Kinetics: Rate Of Reaction: Explain And Use The Term Rate Of Reaction, Frequency Of Collisions, Effective Collisions And Non-effective Collisions
- 6.96Reaction Kinetics: Rate Of Reaction: Explain Qualitatively, In Terms Of Frequency Of Effective Collisions, The Effect Of Concentration And Pressure Changes On The Rate Of A Reaction
- 6.97Reaction Kinetics: Rate Of Reaction: Use Experimental Data To Calculate The Rate Of A Reaction
- 6.98Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Define Activation Energy, Ea, As The Minimum Energy Required For A Collision To Be Effective
- 6.99Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Sketch And Use The Boltzmann Distribution To Explain The Significance Of Activation Energy
- 6.100Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Explain Qualitatively, In Terms Both Of The Boltzmann Distribution And Of Frequency Of Effective Collisions, The Effect Of Temperature Change On The Rate Of A Reaction
- 6.101Reaction Kinetics: Homogeneous And Heterogeneous Catalysts: Explain And Use The Terms Catalyst And Catalysis: (A) Explain That, In The Presence Of A Catalyst, A Reaction Has A Different Mechanism, I.e. One Of Lower Activation Energy (B) Explain This Catalytic Effect In Terms Of The Boltzmann Distribution (C) Construct And Interpret A Reaction Pathway Diagram, For A Reaction In The Presence And Absence Of An Effective Catalyst
- 6.102The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Describe Qualitatively (And Indicate The Periodicity In) The Variations In Atomic Radius, Ionic Radius, Melting Point And Electrical Conductivity Of The Elements
- 6.103The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Explain The Variation In Melting Point And Electrical Conductivity In Terms Of The Structure And Bonding Of The Elements
- 6.104The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen (To Give Na2o, Mgo, Al 2o3, P4o10, So2), Chlorine (To Give Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5) And Water (Na And Mg Only)
- 6.105The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: State And Explain The Variation In The Oxidation Number Of The Oxides (Na2o, Mgo, Al 2o3, P4o10, So2 And So3 Only) And Chlorides (Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5 Only) In Terms Of Their Outer Shell (Valence Shell) Electrons
- 6.106The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions, If Any, Of The Oxides Na2o, Mgo, Al 2o3, Sio2, P4o10, So2 And So3 With Water Including The Likely Phs Of The Solutions Obtained
- 6.107The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Acid/base Behaviour Of The Oxides Na2o, Mgo, Al 2o3, P4o10, So2 And So3 And The Hydroxides Naoh, Mg(Oh)2 And Al(Oh)3 Including, Where Relevant, Amphoteric Behaviour In Reactions With Acids And Bases (Sodium Hydroxide Only)
- 6.108The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Reactions Of The Chlorides Nacl, Mgcl 2, Al Cl 3, Sicl 4, Pcl 5 With Water Including The Likely Phs Of The Solutions Obtained
- 6.109The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Explain The Variations And Trends In 9.2.2, 9.2.3, 9.2.4 And 9.2.5 In Terms Of Bonding And Electronegativity
- 6.110The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Suggest The Types Of Chemical Bonding Present In The Chlorides And Oxides From Observations Of Their Chemical And Physical Properties
- 6.111Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen, Water And Dilute Hydrochloric And Sulfuric Acids
- 6.112Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Thermal Decomposition Of The Nitrates And Carbonates, To Include The Trend In Thermal Stabilities
- 6.113Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Make Predictions From, The Trends In Physical And Chemical Properties Of The Elements Involved In The Reactions In 10.1.1 And The Compounds Involved In 10.1.2, 10.1.3 And 10.1.5
- 6.114Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: State The Variation In The Solubilities Of The Hydroxides And Sulfates
- 6.115Group 17: Physical Properties Of The Group 17 Elements: Describe The Colours And The Trend In Volatility Of Chlorine, Bromine And Iodine
- 6.116Group 17: Physical Properties Of The Group 17 Elements: Describe And Explain The Trend In The Bond Strength Of The Halogen Molecules
- 6.117Group 17: Physical Properties Of The Group 17 Elements: Interpret The Volatility Of The Elements In Terms Of Instantaneous Dipole–induced Dipole Forces
- 6.118Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Reactivity Of The Elements As Oxidising Agents
- 6.119Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Reactions Of The Elements With Hydrogen And Explain Their Relative Reactivity In These Reactions
- 6.120Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Thermal Stabilities Of The Hydrogen Halides And Explain These In Terms Of Bond Strengths
- 6.121Group 17: Some Reactions Of The Halide Ions: Describe The Relative Reactivity Of Halide Ions As Reducing Agents
- 6.122Group 17: Some Reactions Of The Halide Ions: Describe And Explain The Reactions Of Halide Ions With: (A) Aqueous Silver Ions Followed By Aqueous Ammonia (The Formation And Formula Of The [ag(Nh3) 2] + Complex Is Not Required) (B) Concentrated Sulfuric Acid, To Include Balanced Chemical Equations
- 6.123Group 17: The Reactions Of Chlorine: Describe And Interpret, In Terms Of Changes In Oxidation Number, The Reaction Of Chlorine With Cold And With Hot Aqueous Sodium Hydroxide And Recognise These As Disproportionation Reactions
- 6.124Group 17: The Reactions Of Chlorine: Explain, Including By Use Of An Equation, The Use Of Chlorine In Water Purification To Include The Production Of The Active Species Hocl And Clo– Which Kill Bacteria
- 6.125Nitrogen And Sulfur: Nitrogen And Sulfur: Explain The Lack Of Reactivity Of Nitrogen, With Reference To Triple Bond Strength And Lack Of Polarity
- 6.126Nitrogen And Sulfur: Nitrogen And Sulfur: Describe And Explain: (A) The Basicity Of Ammonia, Using The Brønsted–lowry Theory (B) The Structure Of The Ammonium Ion And Its Formation By An Acid–base Reaction (C) The Displacement Of Ammonia From Ammonium Salts By An Acid–base Reaction
- 6.127Nitrogen And Sulfur: Nitrogen And Sulfur: State And Explain The Natural And Man-made Occurrences Of Oxides Of Nitrogen And Their Catalytic Removal From The Exhaust Gases Of Internal Combustion Engines
- 6.128Nitrogen And Sulfur: Nitrogen And Sulfur: Understand That Atmospheric Oxides Of Nitrogen (No And No2) Can React With Unburned Hydrocarbons To Form Peroxyacetyl Nitrate, Pan, Which Is A Component Of Photochemical Smog
- 6.129Nitrogen And Sulfur: Nitrogen And Sulfur: Describe The Role Of No And No2 In The Formation Of Acid Rain Both Directly And In Their Catalytic Role In The Oxidation Of Atmospheric Sulfur Dioxide
- 6.130An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Define The Term Hydrocarbon As A Compound Made Up Of C And H Atoms Only
- 6.131An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That Alkanes Are Simple Hydrocarbons With No Functional Group
- 6.132An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That The Compounds In The Table On Pages 29 And 30 Contain A Functional Group Which Dictates Their Physical And Chemical Properties
- 6.133An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Interpret And Use The General, Structural, Displayed And Skeletal Formulas Of The Classes Of Compound Stated In The Table On Pages 29 And 30
- 6.134An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand And Use Systematic Nomenclature Of Simple Aliphatic Organic Molecules With Functional Groups Detailed In The Table On Pages 29 And 30, Up To Six Carbon Atoms (Six Plus Six For Esters, Straight Chains Only For Esters And Nitriles)
- 6.135An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Deduce The Molecular And/or Empirical Formula Of A Compound, Given Its Structural, Displayed Or Skeletal Formula
- 6.136An Introduction To As Level Organic Chemistry: Characteristic Organic Reactions: Interpret And Use The Following Terminology Associated With Types Of Organic Compounds And Reactions: (A) Homologous Series (B) Saturated And Unsaturated (C) Homolytic And Heterolytic Fission (D) Free Radical, Initiation, Propagation, Termination (E) Nucleophile, Electrophile, Nucleophilic, Electrophilic (F) Addition, Substitution, Elimination, Hydrolysis, Condensation (G) Oxidation And Reduction (In Equations For Organic Redox Reactions, The Symbol [o] Can Be Used To Represent One Atom Of Oxygen From An Oxidising Agent And The Symbol [h] To Represent One Atom Of Hydrogen From A Reducing Agent)
- 6.137An Introduction To As Level Organic Chemistry: Characteristic Organic Reactions: Understand And Use The Following Terminology Associated With Types Of Organic Mechanisms: (A) Free-radical Substitution (B) Electrophilic Addition (C) Nucleophilic Substitution (D) Nucleophilic Addition (In Organic Reaction Mechanisms, The Use Of Curly Arrows To Represent Movement Of Electron Pairs Is Expected; The Arrow Should Begin At A Bond Or A Lone Pair Of Electrons)
- 6.138An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe Organic Molecules As Either Straight-chained, Branched Or Cyclic
- 6.139An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe And Explain The Shape Of, And Bond Angles In, Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 6.140An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe The Arrangement Of Σ And Π Bonds In Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 6.141An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Understand And Use The Term Planar When Describing The Arrangement Of Atoms In Organic Molecules, For Example Ethene
- 6.142An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Structural Isomerism And Its Division Into Chain, Positional And Functional Group Isomerism
- 6.143An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Stereoisomerism And Its Division Into Geometrical (Cis/trans) And Optical Isomerism (Use Of E/z Nomenclature Is Acceptable But Is Not Required)
- 6.144An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Geometrical (Cis/trans) Isomerism In Alkenes, And Explain Its Origin In Terms Of Restricted Rotation Due To The Presence Of Π Bonds
- 6.145An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Explain What Is Meant By A Chiral Centre And That Such A Centre Gives Rise To Two Optical Isomers (Enantiomers) (Candidates Should Appreciate That Compounds Can Contain More Than One Chiral Centre, But Knowledge Of Meso Compounds, Or Nomenclature Such As Diastereoisomers Is Not Required.)
- 6.146An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Identify Chiral Centres And Geometrical (Cis/trans) Isomerism In A Molecule Of Given Structural Formula Including Cyclic Compounds
- 6.147An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Deduce The Possible Isomers For An Organic Molecule Of Known Molecular Formula
- 6.148Hydrocarbons: Alkanes: Recall The Reactions (Reagents And Conditions) By Which Alkanes Can Be Produced: (A) Addition Of Hydrogen To An Alkene In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (B) Cracking Of A Longer Chain Alkane, Heat With Al 2o3
- 6.149Hydrocarbons: Alkanes: Describe: (A) The Complete And Incomplete Combustion Of Alkanes (B) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane
- 6.150Hydrocarbons: Alkanes: Describe The Mechanism Of Free-radical Substitution With Reference To The Initiation, Propagation And Termination Steps
- 6.151Hydrocarbons: Alkanes: Suggest How Cracking Can Be Used To Obtain More Useful Alkanes And Alkenes Of Lower Mr From Heavier Crude Oil Fractions
- 6.152Hydrocarbons: Alkanes: Understand The General Unreactivity Of Alkanes, Including Towards Polar Reagents In Terms Of The Strength Of The C–h Bonds And Their Relative Lack Of Polarity
- 6.153Hydrocarbons: Alkanes: Recognise The Environmental Consequences Of Carbon Monoxide, Oxides Of Nitrogen And Unburnt Hydrocarbons Arising From The Combustion Of Alkanes In The Internal Combustion Engine And Of Their Catalytic Removal
- 6.154Hydrocarbons: Alkenes: Recall The Reactions (Including Reagents And Conditions) By Which Alkenes Can Be Produced: (A) Elimination Of Hx From A Halogenoalkane By Ethanolic Naoh And Heat (B) Dehydration Of An Alcohol, By Using A Heated Catalyst (E.g. Al 2o3) Or A Concentrated Acid (E.g. Concentrated H2so4) (C) Cracking Of A Longer Chain Alkane
- 6.155Hydrocarbons: Alkenes: Describe The Following Reactions Of Alkenes: (A) The Electrophilic Addition Of (I) Hydrogen In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (Ii) Steam, H2o(G) And H3po4 Catalyst (Iii) A Hydrogen Halide, Hx(G), At Room Temperature (Iv) A Halogen, X2 (B) The Oxidation By Cold Dilute Acidified Kmno4 To Form The Diol (C) The Oxidation By Hot Concentrated Acidified Kmno4 Leading To The Rupture Of The Carbon–carbon Double Bond And The Identities Of The Subsequent Products To Determine The Position Of Alkene Linkages In Larger Molecules (D) Addition Polymerisation Exemplified By The Reactions Of Ethene And Propene
- 6.156Hydrocarbons: Alkenes: Describe The Use Of Aqueous Bromine To Show The Presence Of A C=c Bond
- 6.157Hydrocarbons: Alkenes: Describe The Mechanism Of Electrophilic Addition In Alkenes, Using Bromine/ethene And Hydrogen Bromide/propene As Examples
- 6.158Hydrocarbons: Alkenes: Describe And Explain The Inductive Effects Of Alkyl Groups On The Stability Of Primary, Secondary And Tertiary Cations Formed During Electrophilic Addition (This Should Be Used To Explain Markovnikov Addition)
- 6.159Halogen Compounds: Halogenoalkanes: Recall The Reactions (Reagents And Conditions) By Which Halogenoalkanes Can Be Produced: (A) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane (B) Electrophilic Addition Of An Alkene With A Halogen, X2, Or Hydrogen Halide, Hx(G), At Room Temperature (C) Substitution Of An Alcohol, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2
- 6.160Halogen Compounds: Halogenoalkanes: Classify Halogenoalkanes Into Primary, Secondary And Tertiary
- 6.161Halogen Compounds: Halogenoalkanes: Describe The Following Nucleophilic Substitution Reactions: (A) The Reaction With Naoh(Aq) And Heat To Produce An Alcohol (B) The Reaction With Kcn In Ethanol And Heat To Produce A Nitrile (C) The Reaction With Nh3 In Ethanol Heated Under Pressure To Produce An Amine (D) The Reaction With Aqueous Silver Nitrate In Ethanol As A Method Of Identifying The Halogen Present As Exemplified By Bromoethane
- 6.162Halogen Compounds: Halogenoalkanes: Describe The Elimination Reaction With Naoh In Ethanol And Heat To Produce An Alkene As Exemplified By Bromoethane
- 6.163Halogen Compounds: Halogenoalkanes: Describe The Sn1 And Sn2 Mechanisms Of Nucleophilic Substitution In Halogenoalkanes Including The Inductive Effects Of Alkyl Groups
- 6.164Halogen Compounds: Halogenoalkanes: Recall That Primary Halogenoalkanes Tend To React Via The Sn2 Mechanism; Tertiary Halogenoalkanes Via The Sn1 Mechanism; And Secondary Halogenoalkanes By A Mixture Of The Two, Depending On Structure
- 6.165Halogen Compounds: Halogenoalkanes: Describe And Explain The Different Reactivities Of Halogenoalkanes (With Particular Reference To The Relative Strengths Of The C–x Bonds As Exemplified By The Reactions Of Halogenoalkanes With Aqueous Silver Nitrates)
- 6.166Hydroxy Compounds: Alcohols: Recall The Reactions (Reagents And Conditions) By Which Alcohols Can Be Produced: (A) Electrophilic Addition Of Steam To An Alkene, H2o(G) And H3po4 Catalyst (B) Reaction Of Alkenes With Cold Dilute Acidified Potassium Manganate(Vii) To Form A Diol (C) Substitution Of A Halogenoalkane Using Naoh(Aq) And Heat (D) Reduction Of An Aldehyde Or Ketone Using Nabh4 Or Lialh4 (E) Reduction Of A Carboxylic Acid Using Lialh4 (F) Hydrolysis Of An Ester Using Dilute Acid Or Dilute Alkali And Heat
- 6.167Hydroxy Compounds: Alcohols: Describe: (A) The Reaction With Oxygen (Combustion) (B) Substitution To Form Halogenoalkanes, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2 (C) The Reaction With Na(S) (D) Oxidation With Acidified K2cr2o7 Or Acidified Kmno4 To: (I) Carbonyl Compounds By Distillation (Ii) Carboxylic Acids By Refluxing (Primary Alcohols Give Aldehydes Which Can Be Further Oxidised To Carboxylic Acids, Secondary Alcohols Give Ketones, Tertiary Alcohols Cannot Be Oxidised) (E) Dehydration To An Alkene, By Using A Heated Catalyst, E.g. Al 2o3 Or A Concentrated Acid (F) Formation Of Esters By Reaction With Carboxylic Acids And Concentrated H2so4 As Catalyst As Exemplified By Ethanol
- 6.168Hydroxy Compounds: Alcohols: (A) Classify Alcohols As Primary, Secondary And Tertiary Alcohols, To Include Examples With More Than One Alcohol Group (B) State Characteristic Distinguishing Reactions, E.g. Mild Oxidation With Acidified K2cr2o7 , Colour Change From Orange To Green
- 6.169Hydroxy Compounds: Alcohols: Deduce The Presence Of A Ch3ch(Oh)– Group In An Alcohol, Ch3ch(Oh)–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 6.170Hydroxy Compounds: Alcohols: Explain The Acidity Of Alcohols Compared With Water
- 6.171Carbonyl Compounds: Aldehydes And Ketones: Recall The Reactions (Reagents And Conditions) By Which Aldehydes And Ketones Can Be Produced: (A) The Oxidation Of Primary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Aldehydes (B) The Oxidation Of Secondary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Ketones
- 6.172Carbonyl Compounds: Aldehydes And Ketones: Describe: (A) The Reduction Of Aldehydes And Ketones Using Nabh4 Or Lialh4 To Produce Alcohols (B) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat To Produce Hydroxynitriles As Exemplified By Ethanal And Propanone
- 6.173Carbonyl Compounds: Aldehydes And Ketones: Describe The Mechanism Of The Nucleophilic Addition Reactions Of Hydrogen Cyanide With Aldehydes And Ketones In 17.1.2(B)
- 6.174Carbonyl Compounds: Aldehydes And Ketones: Describe The Use Of 2,4-dinitrophenylhydrazine (2,4-dnph Reagent) To Detect The Presence Of Carbonyl Compounds
- 6.175Carbonyl Compounds: Aldehydes And Ketones: Deduce The Nature (Aldehyde Or Ketone) Of An Unknown Carbonyl Compound From The Results Of Simple Tests (Fehling’s And Tollens’ Reagents; Ease Of Oxidation)
- 6.176Carbonyl Compounds: Aldehydes And Ketones: Deduce The Presence Of A Ch3co– Group In An Aldehyde Or Ketone, Ch3co–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 6.177Carboxylic Acids And Derivatives: Carboxylic Acids: Recall The Reactions By Which Carboxylic Acids Can Be Produced: (A) Oxidation Of Primary Alcohols And Aldehydes With Acidified K2cr2o7 Or Acidified Kmno4 And Refluxing (B) Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification (C) Hydrolysis Of Esters With Dilute Acid Or Dilute Alkali And Heat Followed By Acidification
- 6.178Carboxylic Acids And Derivatives: Carboxylic Acids: Describe: (A) The Redox Reaction With Reactive Metals To Produce A Salt And H2(G) (B) The Neutralisation Reaction With Alkalis To Produce A Salt And H2o(L ) (C) The Acid–base Reaction With Carbonates To Produce A Salt And H2o(L) And Co2(G) (D) Esterification With Alcohols With Concentrated H2so4 As Catalyst (E) Reduction By Lialh4 To Form A Primary Alcohol
- 6.179Carboxylic Acids And Derivatives: Esters: Recall The Reaction (Reagents And Conditions) By Which Esters Can Be Produced: (A) The Condensation Reaction Between An Alcohol And A Carboxylic Acid With Concentrated H₂so₄ As Catalyst
- 6.180Carboxylic Acids And Derivatives: Esters: Describe The Hydrolysis Of Esters By Dilute Acid And By Dilute Alkali And Heat
- 6.181Nitrogen Compounds: Primary Amines: Recall The Reactions By Which Amines Can Be Produced: (A) Reaction Of A Halogenoalkane With Nh₃ In Ethanol Heated Under Pressure Classification Of Amines Will Not Be Tested At As Level.
- 6.182Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Nitriles Can Be Produced: (A) Reaction Of A Halogenoalkane With Kcn In Ethanol And Heat
- 6.183Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Hydroxynitriles Can Be Produced: (A) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat
- 6.184Nitrogen Compounds: Nitriles And Hydroxynitriles: Describe The Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification To Produce A Carboxylic Acid
- 6.185Polymerisation: Addition Polymerisation: Describe Addition Polymerisation As Exemplified By Poly(Ethene) And Poly(Chloroethene), Pvc
- 6.186Polymerisation: Addition Polymerisation: Deduce The Repeat Unit Of An Addition Polymer Obtained From A Given Monomer
- 6.187Polymerisation: Addition Polymerisation: Identify The Monomer(S) Present In A Given Section Of An Addition Polymer Molecule
- 6.188Polymerisation: Addition Polymerisation: Recognise The Difficulty Of The Disposal Of Poly(Alkene)s, I.e. Non-biodegradability And Harmful Combustion Products
- 6.189Organic Synthesis: Organic Synthesis: For An Organic Molecule Containing Several Functional Groups: (A) Identify Organic Functional Groups Using The Reactions In The Syllabus (B) Predict Properties And Reactions
- 6.190Organic Synthesis: Organic Synthesis: Devise Multi-step Synthetic Routes For Preparing Organic Molecules Using The Reactions In The Syllabus
- 6.191Organic Synthesis: Organic Synthesis: Analyse A Given Synthetic Route In Terms Of Type Of Reaction And Reagents Used For Each Step Of It, And Possible By-products Analysis
- 6.192Analytical Techniques: Infrared Spectroscopy: Analyse An Infrared Spectrum Of A Simple Molecule To Identify Functional Groups (See The Data Section For The Functional Groups Required)
- 6.193Analytical Techniques: Mass Spectrometry: Analyse Mass Spectra In Terms Of M/e Values And Isotopic Abundances (Knowledge Of The Working Of The Mass Spectrometer Is Not Required)
- 6.194Analytical Techniques: Mass Spectrometry: Calculate The Relative Atomic Mass Of An Element Given The Relative Abundances Of Its Isotopes, Or Its Mass Spectrum
- 6.195Analytical Techniques: Mass Spectrometry: Deduce The Molecular Mass Of An Organic Molecule From The Molecular Ion Peak In A Mass Spectrum
- 6.196Analytical Techniques: Mass Spectrometry: Suggest The Identity Of Molecules Formed By Simple Fragmentation In A Given Mass Spectrum
- 6.197Analytical Techniques: Mass Spectrometry: Deduce The Number Of Carbon Atoms, N, In A Compound Using The [m + 1]+ Peak And The Formula N = 100 × Abundance Of [m + 1]+ Ion 1.1 × Abundance Of M+ Ion
- 6.198Analytical Techniques: Mass Spectrometry: Deduce The Presence Of Bromine And Chlorine Atoms In A Compound Using The [m + 2]+ Peak
- AssignmentsDetailed Assignments For Syllabus Preparation (Including Past Paper Questions)22
- 7.0Atomic Structure3 Days
- 7.1Atoms, Molecules And Stoichiometry3 Days
- 7.2Chemical Bonding3 Days
- 7.3States of Matter3 Days
- 7.4Chemical Energetics3 Days
- 7.5Electrochemistry3 Days
- 7.6Equilibria3 Days
- 7.7Reaction Kinetics3 Days
- 7.8The Periodic Table: Chemistry Periodicity3 Days
- 7.9Group 23 Days
- 7.10Group 173 Days
- 7.11Nitrogen And Sulfur3 Days
- 7.12An Introduction To AS Level Organic Chemistry3 Days
- 7.13Hydrocarbons3 Days
- 7.14Halogen Compounds3 Days
- 7.15Hydroxy Compounds3 Days
- 7.16Carbonyl Compounds3 Days
- 7.17Carboxylic Acids And Derivatives3 Days
- 7.18Nitrogen Compounds3 Days
- 7.19Polymerisation3 Days
- 7.20Organic Synthesis3 Days
- 7.21Analytical Techniques3 Days
- Paper Pattern/ Paper Preparation/ Techniques To Attempt The Paper/ Common Mistakes To AvoidDetailed Information Including Written + Video Material Regarding Paper Attempt / Preparation/ Techniques/ Common Mistakes To Avoid50
- 8.1Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): Complete Breakdown Of AS Level Chemistry Papers (Paper 1, Paper 2, Paper 3)
- 8.2Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): Marks Distribution And Weightage Across Papers (AO1, AO2, AO3 Focus)
- 8.3Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): Time Allocation Strategy For Each Paper
- 8.4Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): How Cambridge Designs Questions From Learning Outcomes
- 8.5Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): Understanding Command Words And What Examiners Actually Want
- 8.6Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): Difference Between Knowledge Marks And Application Marks
- 8.7Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): Examiner Language Vs Student Language (Why Answers Get Capped)
- 8.8Understanding The AS Level Chemistry Paper Structure (Paper Intelligence): How Mark Schemes Are Applied Positively (Not Deductively)
- 8.9Paper 1 (MCQs) — Pattern, Strategy & Traps: Paper 1 Question Styles And Recurring MCQ Patterns
- 8.10Paper 1 (MCQs) — Pattern, Strategy & Traps: Elimination Technique For Difficult MCQs
- 8.11Paper 1 (MCQs) — Pattern, Strategy & Traps: Common Calculation Traps In MCQs (Units, Ratios, Logs, pH)
- 8.12Paper 1 (MCQs) — Pattern, Strategy & Traps: Misleading Options: How Cambridge Designs Wrong Answers
- 8.13Paper 1 (MCQs) — Pattern, Strategy & Traps: Data Booklet Usage Strategy In MCQs
- 8.14Paper 1 (MCQs) — Pattern, Strategy & Traps: Handling Organic Reaction MCQs Without Full Working
- 8.15Paper 1 (MCQs) — Pattern, Strategy & Traps: Speed Vs Accuracy: The Ideal MCQ Attempt Order
- 8.16Paper 1 (MCQs) — Pattern, Strategy & Traps: Most Common MCQ Mistakes Reported By Examiners
- 8.17Paper 2 (Structured Questions) — High-Scoring Techniques: How Structured Questions Are Layered (Easy → Trap → Discriminator)
- 8.18Paper 2 (Structured Questions) — High-Scoring Techniques: Writing Chemical Equations The Examiner Accepts
- 8.19Paper 2 (Structured Questions) — High-Scoring Techniques: Calculation Layout That Secures Full Working Marks
- 8.20Paper 2 (Structured Questions) — High-Scoring Techniques: Significant Figures, Units And Penalty Errors
- 8.21Paper 2 (Structured Questions) — High-Scoring Techniques: Explaining Trends Using Correct Chemical Language
- 8.22Paper 2 (Structured Questions) — High-Scoring Techniques: Organic Mechanism Diagrams: What Loses Marks Instantly
- 8.23Paper 2 (Structured Questions) — High-Scoring Techniques: Data Interpretation Questions: Graphs, Tables, Unknowns
- 8.24Paper 2 (Structured Questions) — High-Scoring Techniques: How To Answer “Explain” Vs “Describe” Vs “Deduce”
- 8.25Paper 2 (Structured Questions) — High-Scoring Techniques: Common Paper 2 Mistakes That Drop Students One Grade
- 8.26Paper 3 (Practical Skills) — Reality Vs Myth: Actual Structure Of Paper 3 (Not What Students Assume)
- 8.27Paper 3 (Practical Skills) — Reality Vs Myth: Planning Questions: What Must Be Written Vs What Is Wasted
- 8.28Paper 3 (Practical Skills) — Reality Vs Myth: Recording Observations The Cambridge Way
- 8.29Paper 3 (Practical Skills) — Reality Vs Myth: Processing Data And Graph Drawing Rules
- 8.30Paper 3 (Practical Skills) — Reality Vs Myth: Error, Uncertainty And Improvement Questions Demystified
- 8.31Paper 3 (Practical Skills) — Reality Vs Myth: Why “Human Error” Is Penalised
- 8.32Paper 3 (Practical Skills) — Reality Vs Myth: Evaluation Questions That Look Easy But Destroy Marks
- 8.33Paper 3 (Practical Skills) — Reality Vs Myth: Most Repeated Practical Mistakes From Examiner Reports
- 8.34Calculation Mastery & Mathematical Technique: Mole Calculations That Cause Maximum Failure
- 8.35Calculation Mastery & Mathematical Technique: pH, Ka, Kc, Kp And Log Errors Students Repeat Every Year
- 8.36Calculation Mastery & Mathematical Technique: Thermochemistry Calculations: Where Marks Are Actually Lost
- 8.37Calculation Mastery & Mathematical Technique: Electrochemistry Calculations And Sign Convention Errors
- 8.38Calculation Mastery & Mathematical Technique: Rate Equations And Half-Life Traps
- 8.39Calculation Mastery & Mathematical Technique: When Rounding Costs You Marks (And When It Doesn’t)
- 8.40Organic Chemistry Answering Strategy: Writing Organic Reactions Without Over-Writing
- 8.41Organic Chemistry Answering Strategy: Mechanisms: How Much Detail Is Enough
- 8.42Organic Chemistry Answering Strategy: Multi-Step Organic Synthesis: Planning Before Writing
- 8.43Organic Chemistry Answering Strategy: Functional Group Tests: Precision Vs Guessing
- 8.44Organic Chemistry Answering Strategy: Common Organic Misconceptions Examiners Flag
- 8.45Exam-Day Intelligence & Final Preparation: Order Of Attempting Questions For Maximum Score
- 8.46Exam-Day Intelligence & Final Preparation: When To Skip, When To Return, When To Commit
- 8.47Exam-Day Intelligence & Final Preparation: How To Use The Last 10 Minutes Effectively
- 8.48Exam-Day Intelligence & Final Preparation: Presentation, Cross-Outs, Extra Booklets — What’s Allowed
- 8.49Exam-Day Intelligence & Final Preparation: Examiner Red Flags That Instantly Cap Marks
- 8.50Exam-Day Intelligence & Final Preparation: Final 7-Day Revision Strategy Based On Past Paper Trends
- Solved Past PapersDetailed Written Explanations And Solutions of Past Papers, Including Model Answers and Explanations For Past Paper Questions0
- Past Paper SessionsVideo Content Regarding Past Paper Solutions0
- Notes (Rearranged Version)Notes Arranged In A Different Style For Preparation Ease22
- 11.0Atomic Structure
- 11.1Atoms, Molecules And Stoichiometry
- 11.2Chemical Bonding
- 11.3States of Matter
- 11.4Chemical Energetics
- 11.5Electrochemistry
- 11.6Equilibria
- 11.7Reaction Kinetics
- 11.8The Periodic Table: Chemical Periodicity
- 11.9Group 2
- 11.10Group 17
- 11.11Nitrogen And Sulfur
- 11.12An Introduction To AS Level Organic Chemistry
- 11.13Hydrocarbons
- 11.14Halogen Compounds
- 11.15Hydroxy Compounds
- 11.16Carbonyl Compounds
- 11.17Carboxylic Acids And Derivatives
- 11.18Nitrogen Compounds
- 11.19Polymerisation
- 11.20Organic Synthesis
- 11.21Analytical Techniques
- Videos Lectures (Pre-Recorded)Videos Recorded In A Different Style For Preparation Ease0
- Extra Section (Practical Section, Formulae Sheet)125
- 13.1Formulae Sheet: Fundamental Quantities & Constants: SI Units, Prefixes And Powers Of Ten Used In Chemistry
- 13.2Formulae Sheet: Fundamental Quantities & Constants: Avogadro Constant And Its Applications
- 13.3Formulae Sheet: Fundamental Quantities & Constants: Relative Atomic Mass (Aᵣ) And Relative Molecular Mass (Mᵣ)
- 13.4Formulae Sheet: Fundamental Quantities & Constants: Molar Mass, Moles And Amount Of Substance
- 13.5Formulae Sheet: Fundamental Quantities & Constants: Density Formula And Rearrangements
- 13.6Formulae Sheet: Fundamental Quantities & Constants: Percentage Composition By Mass
- 13.7Formulae Sheet: Empirical Formula And Molecular Formula Relationships
- 13.8Formulae Sheet: Stoichiometry & Chemical Calculations: Mole Ratio Calculations From Balanced Equations
- 13.9Formulae Sheet: Stoichiometry & Chemical Calculations: Limiting Reagent Calculations
- 13.10Formulae Sheet: Stoichiometry & Chemical Calculations: Percentage Yield Formula
- 13.11Formulae Sheet: Stoichiometry & Chemical Calculations: Percentage Purity Formula
- 13.12Formulae Sheet: Stoichiometry & Chemical Calculations: Concentration In mol dm⁻³
- 13.13Formulae Sheet: Stoichiometry & Chemical Calculations: Conversion Between Mass, Moles And Concentration
- 13.14Formulae Sheet: Stoichiometry & Chemical Calculations: Dilution Formula (C₁V₁ = C₂V₂)
- 13.15Formulae Sheet: Stoichiometry & Chemical Calculations: Gas Volume Calculations At r.t.p. (24.0 dm³ mol⁻¹)
- 13.16Formulae Sheet: Atomic Structure & Periodicity Formulae: Proton, Neutron And Electron Relationships
- 13.17Formulae Sheet: Atomic Structure & Periodicity Formulae: Isotopic Abundance And Weighted Mean Formula
- 13.18Formulae Sheet: Atomic Structure & Periodicity Formulae: Mass Spectrometry Calculations
- 13.19Formulae Sheet: Atomic Structure & Periodicity Formulae: Ionisation Energy Calculations (Conceptual + Numerical Links)
- 13.20Formulae Sheet: Chemical Bonding & Structure (Quantitative Parts): Enthalpy And Bond Energy Relationships
- 13.21Formulae Sheet: Chemical Bonding & Structure (Quantitative Parts): Bond Enthalpy Calculations
- 13.22Formulae Sheet: Chemical Bonding & Structure (Quantitative Parts): Enthalpy Change Of Reaction From Bond Energies
- 13.23Formulae Sheet: Chemical Bonding & Structure (Quantitative Parts): Lattice Energy (Conceptual Formula Links Only – AS Level)
- 13.24Formulae Sheet: States Of Matter & Gas Laws: Ideal Gas Equation: pV = nRT
- 13.25Formulae Sheet: States Of Matter & Gas Laws: Rearrangements Of The Ideal Gas Equation
- 13.26Formulae Sheet: States Of Matter & Gas Laws: Unit Conversions For Pressure, Volume And Temperature
- 13.27Formulae Sheet: States Of Matter & Gas Laws: Gas Density Formula Derived From pV = nRT
- 13.28Formulae Sheet: Chemical Energetics: Enthalpy Change Definition Formula (ΔH)
- 13.29Formulae Sheet: Chemical Energetics: Enthalpy Change From Temperature Change (q = mcΔT)
- 13.30Formulae Sheet: Chemical Energetics: Hess’s Law Cycle Calculations
- 13.31Formulae Sheet: Chemical Energetics: Enthalpy Of Formation Calculations
- 13.32Formulae Sheet: Chemical Energetics: Enthalpy Of Combustion Calculations
- 13.33Formulae Sheet: Chemical Energetics: Enthalpy Of Neutralisation Calculations
- 13.34Formulae Sheet: Kinetics (Rates Of Reaction): Rate Of Reaction Formula
- 13.35Formulae Sheet: Kinetics (Rates Of Reaction): Rate From Concentration–Time Graphs
- 13.36Formulae Sheet: Kinetics (Rates Of Reaction): Rate From Tangents And Gradients
- 13.37Formulae Sheet: Kinetics (Rates Of Reaction): Activation Energy Concepts Linked To Maxwell–Boltzmann
- 13.38Formulae Sheet: Kinetics (Rates Of Reaction): Effect Of Concentration And Temperature (Quantitative Reasoning)
- 13.39Formulae Sheet: Chemical Equilibria: Dynamic Equilibrium Expression
- 13.40Formulae Sheet: Chemical Equilibria: Equilibrium Constant Kc Formula
- 13.41Formulae Sheet: Chemical Equilibria: Writing Kc Expressions Correctly
- 13.42Formulae Sheet: Chemical Equilibria: Calculating Kc From Equilibrium Concentrations
- 13.43Formulae Sheet: Chemical Equilibria: Predicting Equilibrium Shifts (Le Chatelier — formula-linked logic)
- 13.44Formulae Sheet: Acids, Bases & pH Calculations: pH Formula (pH = −log[H⁺])
- 13.45Formulae Sheet: Acids, Bases & pH Calculations: Rearranging pH Formula To Find [H⁺]
- 13.46Formulae Sheet: Acids, Bases & pH Calculations: Strong Acid pH Calculations
- 13.47Formulae Sheet: Acids, Bases & pH Calculations: Strong Base pH Calculations
- 13.48Formulae Sheet: Acids, Bases & pH Calculations: Relationship Between pH And Concentration
- 13.49Formulae Sheet: Acids, Bases & pH Calculations: Ka Expression For Weak Acids
- 13.50Formulae Sheet: Acids, Bases & pH Calculations: Calculating Ka From pH And Concentration
- 13.51Formulae Sheet: Acids, Bases & pH Calculations: pKa And Its Relationship To Ka
- 13.52Formulae Sheet: Acids, Bases & pH Calculations: Using Ka To Compare Acid Strength
- 13.53Formulae Sheet: Redox & Electrochemistry: Oxidation Number Rules
- 13.54Formulae Sheet: Redox & Electrochemistry: Redox Half-Equation Method
- 13.55Formulae Sheet: Redox & Electrochemistry: Electron Transfer Calculations
- 13.56Formulae Sheet: Redox & Electrochemistry: Electrolysis Charge Formula (Q = It)
- 13.57Formulae Sheet: Redox & Electrochemistry: Faraday Constant Applications
- 13.58Formulae Sheet: Redox & Electrochemistry: Mass And Mole Calculations In Electrolysis
- 13.59Formulae Sheet: Organic Chemistry Quantitative Formulae: General Formulae Of Homologous Series
- 13.60Formulae Sheet: Organic Chemistry Quantitative Formulae: Molecular Formula Determination From Percentage Composition
- 13.61Formulae Sheet: Organic Chemistry Quantitative Formulae: Combustion Analysis Calculations
- 13.62Formulae Sheet: Organic Chemistry Quantitative Formulae: Yield Calculations In Organic Reactions
- 13.63Formulae Sheet: Organic Chemistry Quantitative Formulae: Atom Economy Formula
- 13.64Formulae Sheet: Practical & Data Handling Formulae: Uncertainty And Percentage Uncertainty Formula
- 13.65Formulae Sheet: Practical & Data Handling Formulae: Combining Uncertainties
- 13.66Formulae Sheet: Practical & Data Handling Formulae: Gradient Formula For Graphs
- 13.67Formulae Sheet: Practical & Data Handling Formulae: Mean, Range And Trend Interpretation (Data Skills)
- 13.68Practical Skills: Understanding Paper 3 Structure & Assessment: Structure Of AS Level Chemistry Paper 3
- 13.69Practical Skills: Understanding Paper 3 Structure & Assessment: Skill Weighting: Planning, Observation, Processing, Evaluation
- 13.70Practical Skills: Understanding Paper 3 Structure & Assessment: How Marks Are Awarded In Practical Questions
- 13.71Practical Skills: Understanding Paper 3 Structure & Assessment: Difference Between Method Marks And Accuracy Marks
- 13.72Practical Skills: Understanding Paper 3 Structure & Assessment: Common Examiner Expectations In Paper 3
- 13.73Practical Skills: Experimental Planning Skills: Writing A Complete Experimental Plan (Variables, Controls, Steps)
- 13.74Practical Skills: Experimental Planning Skills: Independent, Dependent And Controlled Variables
- 13.75Practical Skills: Experimental Planning Skills: Choosing Appropriate Apparatus (Size, Accuracy, Precision)
- 13.76Practical Skills: Experimental Planning Skills: Designing Fair Tests
- 13.77Practical Skills: Experimental Planning Skills: Repeats, Averages And Reliability
- 13.78Practical Skills: Experimental Planning Skills: Safety Considerations And Hazards
- 13.79Practical Skills: Experimental Planning Skills: Planning Questions That Involve Titration
- 13.80Practical Skills: Experimental Planning Skills: Planning Questions Involving Rates Of Reaction
- 13.81Practical Skills: Experimental Planning Skills: Planning Questions Using Calorimetry
- 13.82Practical Skills: Experimental Planning Skills: Planning Questions Using Gas Collection
- 13.83Practical Skills: Measurement & Apparatus Handling: Correct Use Of Burettes, Pipettes And Measuring Cylinders
- 13.84Practical Skills: Measurement & Apparatus Handling: Reading Scales Correctly (Meniscus Rules)
- 13.85Practical Skills: Measurement & Apparatus Handling: Choice Between Measuring Cylinder Vs Pipette (Exam Logic)
- 13.86Practical Skills: Measurement & Apparatus Handling: Use Of Thermometers And Temperature Control
- 13.87Practical Skills: Measurement & Apparatus Handling: Use Of Stopwatches And Timing Reactions
- 13.88Practical Skills: Measurement & Apparatus Handling: Balances: Mass Measurement And Significant Figures
- 13.89Practical Skills: Recording Results & Observations: Recording Qualitative Observations (Colour, Precipitate, Gas)
- 13.90Practical Skills: Recording Results & Observations: Writing Observations Vs Explanations
- 13.91Practical Skills: Recording Results & Observations: Correct Use Of Tables (Headings, Units, Consistency)
- 13.92Practical Skills: Recording Results & Observations: Decimal Places And Significant Figures In Tables
- 13.93Practical Skills: Recording Results & Observations: Avoiding Subjective Language In Observations
- 13.94Practical Skills: Recording Results & Observations: Common Observation Errors Examiners Penalise
- 13.95Practical Skills: Data Processing & Calculations: Calculations From Raw Practical Data
- 13.96Practical Skills: Data Processing & Calculations: Titration Calculations From Experimental Readings
- 13.97Practical Skills: Data Processing & Calculations: Rate Calculations From Time Measurements
- 13.98Practical Skills: Data Processing & Calculations: Energy Change Calculations From Calorimetry Data
- 13.99Practical Skills: Data Processing & Calculations: Percentage Yield And Purity In Practical Contexts
- 13.100Practical Skills: Data Processing & Calculations: Error Carried Forward In Practical Calculations
- 13.101Practical Skills: Graph Skills (High-Frequency Area): Choosing Correct Axes And Scales
- 13.102Practical Skills: Graph Skills (High-Frequency Area): Plotting Points Accurately
- 13.103Practical Skills: Graph Skills (High-Frequency Area): Drawing Best-Fit Lines Or Curves
- 13.104Practical Skills: Graph Skills (High-Frequency Area): Determining Gradients And Tangents
- 13.105Practical Skills: Graph Skills (High-Frequency Area): Extracting Quantitative Information From Graphs
- 13.106Practical Skills: Graph Skills (High-Frequency Area): Common Graph Drawing Mistakes
- 13.107Practical Skills: Uncertainty, Errors & Evaluation: Types Of Error: Random Vs Systematic
- 13.108Practical Skills: Uncertainty, Errors & Evaluation: Sources Of Error In Practical Experiments
- 13.109Practical Skills: Uncertainty, Errors & Evaluation: Absolute And Percentage Uncertainty
- 13.110Practical Skills: Uncertainty, Errors & Evaluation: Combining Uncertainties
- 13.111Practical Skills: Uncertainty, Errors & Evaluation: Meaningful Evaluation Statements (Not Vague Ones)
- 13.112Practical Skills: Uncertainty, Errors & Evaluation: Improvements That Actually Score Marks
- 13.113Practical Skills: Uncertainty, Errors & Evaluation: Why “Human Error” Is Penalised
- 13.114Practical Skills: Uncertainty, Errors & Evaluation: Limitations Vs Improvements (Exam Distinction)
- 13.115Practical Skills: Qualitative Analysis Skills: Identifying Gases From Tests And Observations
- 13.116Practical Skills: Qualitative Analysis Skills: Flame Tests And Their Limitations
- 13.117Practical Skills: Qualitative Analysis Skills: Test For Cations And Anions (Observation-Focused)
- 13.118Practical Skills: Qualitative Analysis Skills: Organic Functional Group Tests In Practical Contexts
- 13.119Practical Skills: Qualitative Analysis Skills: Writing Balanced Chemical Equations For Tests
- 13.120Practical Skills: Examiner Traps & Final Practical Intelligence: Most Repeated Paper 3 Mistakes From Examiner Reports
- 13.121Practical Skills: Examiner Traps & Final Practical Intelligence: Words That Instantly Lose Marks In Evaluation
- 13.122Practical Skills: Examiner Traps & Final Practical Intelligence: How Over-Detail Loses Planning Marks
- 13.123Practical Skills: Examiner Traps & Final Practical Intelligence: When Diagrams Help And When They Waste Time
- 13.124Practical Skills: Examiner Traps & Final Practical Intelligence: Using Data Booklet In Practical Questions
- 13.125Practical Skills: Examiner Traps & Final Practical Intelligence: Final Checklist Before Submitting Paper 3
- Cheat SheetsShort, Quick Revision Cheat Sheets196
- 14.1Atomic Structure: Particles In The Atom And Atomic Radius: Understand That Atoms Are Mostly Empty Space Surrounding A Very Small, Dense Nucleus That Contains Protons And Neutrons; Electrons Are Found In Shells In The Empty Space Around The Nucleus
- 14.2Atomic Structure: Particles In The Atom And Atomic Radius: Identify And Describe Protons, Neutrons And Electrons In Terms Of Their Relative Charges And Relative Masses
- 14.3Atomic Structure: Particles In The Atom And Atomic Radius: Understand The Terms Atomic And Proton Number; Mass And Nucleon Number
- 14.4Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Distribution Of Mass And Charge Within An Atom
- 14.5Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Behaviour Of Beams Of Protons, Neutrons And Electrons Moving At The Same Velocity In An Electric Field
- 14.6Atomic Structure: Particles In The Atom And Atomic Radius: Determine The Numbers Of Protons, Neutrons And Electrons Present In Both Atoms And Ions Given Atomic Or Proton Number, Mass Or Nucleon Number And Charge
- 14.7Atomic Structure: Particles In The Atom And Atomic Radius: State And Explain Qualitatively The Variations In Atomic Radius And Ionic Radius Across A Period And Down A Group
- 14.8Atomic Structure: Isotopes: Define The Term Isotope In Terms Of Numbers Of Protons And Neutrons
- 14.9Atomic Structure: Isotopes: Understand The Notation X Ya For Isotopes, Where X Is The Mass Or Nucleon Number And Y Is The Atomic Or Proton Number
- 14.10Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have The Same Chemical Properties
- 14.11Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have Different Physical Properties, Limited To Mass And Density
- 14.12Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand The Terms: • Shells, Sub-shells And Orbitals • Principal Quantum Number (N) • Ground State, Limited To Electronic Configuration
- 14.13Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Number Of Orbitals Making Up S, P And D Sub-shells, And The Number Of Electrons That Can Fill S, P And D Sub-shells
- 14.14Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Order Of Increasing Energy Of The Sub-shells Within The First Three Shells And The 4s And 4p Sub-shells
- 14.15Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Electronic Configurations To Include The Number Of Electrons In Each Shell, Sub-shell And Orbital
- 14.16Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Explain The Electronic Configurations In Terms Of Energy Of The Electrons And Inter-electron Repulsion
- 14.17Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Determine The Electronic Configuration Of Atoms And Ions Given The Atomic Or Proton Number And Charge, Using Either Of The Following Conventions: E.g. For Fe: 1s2 2s2 2p6 3s2 3p6 3d6 4s2 (Full Electronic Configuration) Or [ar] 3d6 4s2 (Shorthand Electronic Configuration)
- 14.18Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand And Use The Electrons In Boxes Notation E.g. For Fe: [ar]
- 14.19Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe And Sketch The Shapes Of S And P Orbitals
- 14.20Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe A Free Radical As A Species With One Or More Unpaired Electrons
- 14.21Atomic Structure: Ionisation Energy: Define And Use The Term First Ionisation Energy, Ie
- 14.22Atomic Structure: Ionisation Energy: Construct Equations To Represent First, Second And Subsequent Ionisation Energies
- 14.23Atomic Structure: Ionisation Energy: Identify And Explain The Trends In Ionisation Energies Across A Period And Down A Group Of The Periodic Table
- 14.24Atomic Structure: Ionisation Energy: Identify And Explain The Variation In Successive Ionisation Energies Of An Element
- 14.25Atomic Structure: Ionisation Energy: Understand That Ionisation Energies Are Due To The Attraction Between The Nucleus And The Outer Electron
- 14.26Atomic Structure: Ionisation Energy: Explain The Factors Influencing The Ionisation Energies Of Elements In Terms Of Nuclear Charge, Atomic/ionic Radius, Shielding By Inner Shells And Sub-shells And Spin-pair Repulsion
- 14.27Atomic Structure: Ionisation Energy: Deduce The Electronic Configurations Of Elements Using Successive Ionisation Energy Data
- 14.28Atomic Structure: Ionisation Energy: Deduce The Position Of An Element In The Periodic Table Using Successive Ionisation Energy Data
- 14.29Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define The Unified Atomic Mass Unit As One Twelfth Of The Mass Of A Carbon-12 Atom
- 14.30Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define Relative Atomic Mass, Ar , Relative Isotopic Mass, Relative Molecular Mass, Mr , And Relative Formula Mass In Terms Of The Unified Atomic Mass Unit
- 14.31Atoms, Molecules And Stoichiometry: The Mole And The Avogadro Constant: Define And Use The Term Mole In Terms Of The Avogadro Constant
- 14.32Atoms, Molecules And Stoichiometry: Formulas: Write Formulas Of Ionic Compounds From Ionic Charges And Oxidation Numbers (Shown By A Roman Numeral), Including: (A) The Prediction Of Ionic Charge From The Position Of An Element In The Periodic Table (B) Recall Of The Names And Formulas For The Following Ions: No3 – , Co3 2–, So4 2–, Oh– , Nh4 + , Zn2+, Ag+ , Hco3 – , Po4 3–
- 14.33Atoms, Molecules And Stoichiometry: Formulas: (A) Write And Construct Equations (Which Should Be Balanced), Including Ionic Equations (Which Should Not Include Spectator Ions) (B) Use Appropriate State Symbols In Equations
- 14.34Atoms, Molecules And Stoichiometry: Formulas: Define And Use The Terms Empirical And Molecular Formula
- 14.35Atoms, Molecules And Stoichiometry: Formulas: Understand And Use The Terms Anhydrous, Hydrated And Water Of Crystallisation
- 14.36Atoms, Molecules And Stoichiometry: Formulas: Calculate Empirical And Molecular Formulas, Using Given Data
- 14.37Atoms, Molecules And Stoichiometry: Reacting Masses And Volumes (Of Solutions And Gases): Perform Calculations Including Use Of The Mole Concept, Involving: (A) Reacting Masses (From Formulas And Equations) Including Percentage Yield Calculations (B) Volumes Of Gases (E.g. In The Burning Of Hydrocarbons) (C) Volumes And Concentrations Of Solutions (D) Limiting Reagent And Excess Reagent (When Performing Calculations, Candidates’ Answers Should Reflect The Number Of Significant Figures Given Or Asked For In The Question. When Rounding Up Or Down, Candidates Should Ensure That Significant Figures Are Neither Lost Unnecessarily Nor Used Beyond What Is Justified (See Also Mathematical Requirements Section).) (E) Deduce Stoichiometric Relationships From Calculations Such As Those In 2.4.1(A)–(D)
- 14.38Chemical Bonding: Electronegativity And Bonding: Define Electronegativity As The Power Of An Atom To Attract Electrons To Itself
- 14.39Chemical Bonding: Electronegativity And Bonding: Explain The Factors Influencing The Electronegativities Of The Elements In Terms Of Nuclear Charge, Atomic Radius And Shielding By Inner Shells And Sub-shells
- 14.40Chemical Bonding: Electronegativity And Bonding: State And Explain The Trends In Electronegativity Across A Period And Down A Group Of The Periodic Table
- 14.41Chemical Bonding: Electronegativity And Bonding: Use The Differences In Pauling Electronegativity Values To Predict The Formation Of Ionic And Covalent Bonds (The Presence Of Covalent Character In Some Ionic Compounds Will Not Be Assessed) (Pauling Electronegativity Values Will Be Given Where Necessary)
- 14.42Chemical Bonding: Ionic Bonding: Define Ionic Bonding As The Electrostatic Attraction Between Oppositely Charged Ions (Positively Charged Cations And Negatively Charged Anions)
- 14.43Chemical Bonding: Ionic Bonding: Describe Ionic Bonding Including The Examples Of Sodium Chloride, Magnesium Oxide And Calcium Fluoride
- 14.44Chemical Bonding: Metallic Bonding: Define Metallic Bonding As The Electrostatic Attraction Between Positive Metal Ions And Delocalised Electrons
- 14.45Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: Define Covalent Bonding As Electrostatic Attraction Between The Nuclei Of Two Atoms And A Shared Pair Of Electrons (A) Describe Covalent Bonding In Molecules Including: • Hydrogen, H2 • Oxygen, O2 • Nitrogen, N2 • Chlorine, Cl 2 • Hydrogen Chloride, Hcl • Carbon Dioxide, Co2 • Ammonia, Nh3 • Methane, Ch4 • Ethane, C2h6 • Ethene, C2h4 (B) Understand That Elements In Period 3 Can Expand Their Octet Including In The Compounds Sulfur Dioxide, So2, Phosphorus Pentachloride, Pcl 5 , And Sulfur Hexafluoride, Sf6 (C) Describe Coordinate (Dative Covalent) Bonding, Including In The Reaction Between Ammonia And Hydrogen Chloride Gases To Form The Ammonium Ion, Nh4 + , And In The Al 2cl 6 Molecule
- 14.46Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: (A) Describe Covalent Bonds In Terms Of Orbital Overlap Giving Σ And Π Bonds: • Σ Bonds Are Formed By Direct Overlap Of Orbitals Between The Bonding Atoms • Π Bonds Are Formed By The Sideways Overlap Of Adjacent P Orbitals Above And Below The Σ Bond (B) Describe How The Σ And Π Bonds Form In Molecules Including H₂, C₂h₆, C₂h₄, Hcn And N₂ (C) Use The Concept Of Hybridisation To Describe Sp, Sp² And Sp³ Orbitals
- 14.47Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: A) Define The Terms: • Bond Energy As The Energy Required To Break One Mole Of A Particular Covalent Bond In The Gaseous State • Bond Length As The Internuclear Distance Of Two Covalently Bonded Atoms (B) Use Bond Energy Values And The Concept Of Bond Length To Compare The Reactivity Of Covalent Molecules
- 14.48Chemical Bonding: Shapes Of Molecules: State And Explain The Shapes Of, And Bond Angles In, Molecules By Using Vsepr Theory, Including As Simple Examples: • Bf3 (Trigonal Planar, 120°) • Co2 (Linear, 180°) • Ch4 (Tetrahedral, 109.5°) • Nh3 (Pyramidal, 107°) • H2o (Non-linear, 104.5°) • Sf6 (Octahedral, 90°) • Pf5 (Trigonal Bipyramidal, 120° And 90°)
- 14.49Chemical Bonding: Shapes Of Molecules: Predict The Shapes Of, And Bond Angles In, Molecules And Ions Analogous To Those Specified In 3.5.1
- 14.50Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Hydrogen Bonding, Limited To Molecules Containing N–h And O–h Groups, Including Ammonia And Water As Simple Examples (B) Use The Concept Of Hydrogen Bonding To Explain The Anomalous Properties Of H₂o (Ice And Water): • Its Relatively High Melting And Boiling Points • Its Relatively High Surface Tension • The Density Of The Solid Ice Compared With The Liquid Water
- 14.51Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: Use The Concept Of Electronegativity To Explain Bond Polarity And Dipole Moments Of Molecules
- 14.52Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Van Der Waals’ Forces As The Intermolecular Forces Between Molecular Entities Other Than Those Due To Bond Formation, And Use The Term Van Der Waals’ Forces As A Generic Term To Describe All Intermolecular Forces (B) Describe The Types Of Van Der Waals’ Forces: • Instantaneous Dipole–induced Dipole (Id-id) Forces, Also Called London Dispersion Forces • Permanent Dipole–permanent Dipole (Pd-pd) Forces, Including Hydrogen Bonding (C) Describe Hydrogen Bonding And Understand That Hydrogen Bonding Is A Special Case Of Permanent Dipole–permanent Dipole Forces Between Molecules Where Hydrogen Is Bonded To A Highly Electronegative Atom
- 14.53Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: State That, In General, Ionic, Covalent And Metallic Bonding Are Stronger Than Intermolecular Forces
- 14.54Chemical Bonding: Dot-and-cross Diagrams: Use Dot-and-cross Diagrams To Illustrate Ionic, Covalent And Coordinate Bonding Including The Representation Of Any Compounds Stated In 3.4 And 3.5 (Dot-and-cross Diagrams May Include Species With Atoms Which Have An Expanded Octet Or Species With An Odd Number Of Electrons)
- 14.55States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Explain The Origin Of Pressure In A Gas In Terms Of Collisions Between Gas Molecules And The Wall Of The Container
- 14.56States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Understand That Ideal Gases Have Zero Particle Volume And No Intermolecular Forces Of Attraction
- 14.57States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: State And Use The Ideal Gas Equation Pv = Nrt In Calculations, Including In The Determination Of Mr
- 14.58States Of Matter: Bonding And Structure: Describe, In Simple Terms, The Lattice Structure Of A Crystalline Solid Which Is: (A) Giant Ionic, Including Sodium Chloride And Magnesium Oxide (B) Simple Molecular, Including Iodine, Buckminsterfullerene C60 And Ice (C) Giant Molecular, Including Silicon(Iv) Oxide, Graphite And Diamond (D) Giant Metallic, Including Copper
- 14.59States Of Matter: Bonding And Structure: Describe, Interpret And Predict The Effect Of Different Types Of Structure And Bonding On The Physical Properties Of Substances, Including Melting Point, Boiling Point, Electrical Conductivity And Solubility
- 14.60States Of Matter: Bonding And Structure: Deduce The Type Of Structure And Bonding Present In A Substance From Given Information
- 14.61Chemical Energetics: Enthalpy Change, Δh: Understand That Chemical Reactions Are Accompanied By Enthalpy Changes And These Changes Can Be Exothermic (δh Is Negative) Or Endothermic (δh Is Positive)
- 14.62Chemical Energetics: Enthalpy Change, Δh: Construct And Interpret A Reaction Pathway Diagram, In Terms Of The Enthalpy Change Of The Reaction And Of The Activation Energy
- 14.63Chemical Energetics: Enthalpy Change, Δh: Define And Use The Terms: (A) Standard Conditions (This Syllabus Assumes That These Are 298k And 101kpa) Shown By ⦵ . (B) Enthalpy Change With Particular Reference To: Reaction, Δhr , Formation, Δhf , Combustion, Δhc , Neutralisation, Δhneut
- 14.64Chemical Energetics: Enthalpy Change, Δh: Understand That Energy Transfers Occur During Chemical Reactions Because Of The Breaking And Making Of Chemical Bonds
- 14.65Chemical Energetics: Enthalpy Change, Δh: Use Bond Energies (δh Positive, I.e. Bond Breaking) To Calculate Enthalpy Change Of Reaction, Δhr
- 14.66Chemical Energetics: Enthalpy Change, Δh: Understand That Some Bond Energies Are Exact And Some Bond Energies Are Averages
- 14.67Chemical Energetics: Enthalpy Change, Δh: Calculate Enthalpy Changes From Appropriate Experimental Results, Including The Use Of The Relationships Q = Mcδt And Δh = –mcδt/ N
- 14.68Chemical Energetics: Hess’s Law: Apply Hess’s Law To Construct Simple Energy Cycles
- 14.69Chemical Energetics: Hess’s Law: Carry Out Calculations Using Cycles And Relevant Energy Terms, Including: (A) Determining Enthalpy Changes That Cannot Be Found By Direct Experiment (B) Use Of Bond Energy Data
- 14.70Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Calculate Oxidation Numbers Of Elements In Compounds And Ions
- 14.71Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use Changes In Oxidation Numbers To Help Balance Chemical Equations
- 14.72Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Redox, Oxidation, Reduction And Disproportionation In Terms Of Electron Transfer And Changes In Oxidation Number
- 14.73Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Oxidising Agent And Reducing Agent
- 14.74Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use A Roman Numeral To Indicate The Magnitude Of The Oxidation Number Of An Element
- 14.75Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: (A) Understand What Is Meant By A Reversible Reaction (B) Understand What Is Meant By Dynamic Equilibrium In Terms Of The Rate Of Forward And Reverse Reactions Being Equal And The Concentration Of Reactants And Products Remaining Constant (C) Understand The Need For A Closed System In Order To Establish Dynamic Equilibrium
- 14.76Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Define Le Chatelier’s Principle As: If A Change Is Made To A System At Dynamic Equilibrium, The Position Of Equilibrium Moves To Minimise This Change
- 14.77Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use Le Chatelier’s Principle To Deduce Qualitatively (From Appropriate Information) The Effects Of Changes In Temperature, Concentration, Pressure Or Presence Of A Catalyst On A System At Equilibrium
- 14.78Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Concentrations, Kc
- 14.79Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Terms Mole Fraction And Partial Pressure
- 14.80Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Partial Pressures, Kp (Use Of The Relationship Between Kp And Kc Is Not Required)
- 14.81Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Kc And Kp Expressions To Carry Out Calculations (Such Calculations Will Not Require The Solving Of Quadratic Equations)
- 14.82Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Calculate The Quantities Present At Equilibrium, Given Appropriate Data
- 14.83Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: State Whether Changes In Temperature, Concentration Or Pressure Or The Presence Of A Catalyst Affect The Value Of The Equilibrium Constant For A Reaction
- 14.84Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Describe And Explain The Conditions Used In The Haber Process And The Contact Process, As Examples Of The Importance Of An Understanding Of Dynamic Equilibrium In The Chemical Industry And The Application Of Le Chatelier’s Principle
- 14.85Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Acids, Limited To Hydrochloric Acid, Hcl, Sulfuric Acid, H2so4, Nitric Acid, Hno3, Ethanoic Acid, Ch3cooh
- 14.86Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Alkalis, Limited To Sodium Hydroxide, Naoh, Potassium Hydroxide, Koh, Ammonia, Nh3
- 14.87Brønsted–lowry Theory Of Acids And Bases: Describe The Brønsted–lowry Theory Of Acids And Bases
- 14.88Brønsted–lowry Theory Of Acids And Bases: Describe Strong Acids And Strong Bases As Fully Dissociated In Aqueous Solution And Weak Acids And Weak Bases As Partially Dissociated In Aqueous Solution
- 14.89Brønsted–lowry Theory Of Acids And Bases: Appreciate That Water Has Ph Of 7, Acid Solutions Ph Of Below 7 And Alkaline Solutions Ph Of Above 7
- 14.90Brønsted–lowry Theory Of Acids And Bases: Explain Qualitatively The Differences In Behaviour Between Strong And Weak Acids Including The Reaction With A Reactive Metal And Difference In Ph Values By Use Of A Ph Meter, Universal Indicator Or Conductivity
- 14.91Brønsted–lowry Theory Of Acids And Bases: Understand That Neutralisation Reactions Occur When H+ (Aq) And Oh– (Aq) Form H2o(L)
- 14.92Brønsted–lowry Theory Of Acids And Bases: Understand That Salts Are Formed In Neutralisation Reactions
- 14.93Brønsted–lowry Theory Of Acids And Bases: Sketch The Ph Titration Curves Of Titrations Using Combinations Of Strong And Weak Acids With Strong And Weak Alkalis
- 14.94Brønsted–lowry Theory Of Acids And Bases: Select Suitable Indicators For Acid-alkali Titrations, Given Appropriate Data (Pka Values Will Not Be Used)
- 14.95Reaction Kinetics: Rate Of Reaction: Explain And Use The Term Rate Of Reaction, Frequency Of Collisions, Effective Collisions And Non-effective Collisions
- 14.96Reaction Kinetics: Rate Of Reaction: Explain Qualitatively, In Terms Of Frequency Of Effective Collisions, The Effect Of Concentration And Pressure Changes On The Rate Of A Reaction
- 14.97Reaction Kinetics: Rate Of Reaction: Use Experimental Data To Calculate The Rate Of A Reaction
- 14.98Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Define Activation Energy, Ea, As The Minimum Energy Required For A Collision To Be Effective
- 14.99Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Sketch And Use The Boltzmann Distribution To Explain The Significance Of Activation Energy
- 14.100Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Explain Qualitatively, In Terms Both Of The Boltzmann Distribution And Of Frequency Of Effective Collisions, The Effect Of Temperature Change On The Rate Of A Reaction
- 14.101Reaction Kinetics: Homogeneous And Heterogeneous Catalysts: Explain And Use The Terms Catalyst And Catalysis: (A) Explain That, In The Presence Of A Catalyst, A Reaction Has A Different Mechanism, I.e. One Of Lower Activation Energy (B) Explain This Catalytic Effect In Terms Of The Boltzmann Distribution (C) Construct And Interpret A Reaction Pathway Diagram, For A Reaction In The Presence And Absence Of An Effective Catalyst
- 14.102The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Describe Qualitatively (And Indicate The Periodicity In) The Variations In Atomic Radius, Ionic Radius, Melting Point And Electrical Conductivity Of The Elements
- 14.103The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Explain The Variation In Melting Point And Electrical Conductivity In Terms Of The Structure And Bonding Of The Elements
- 14.104The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen (To Give Na2o, Mgo, Al 2o3, P4o10, So2), Chlorine (To Give Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5) And Water (Na And Mg Only)
- 14.105The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: State And Explain The Variation In The Oxidation Number Of The Oxides (Na2o, Mgo, Al 2o3, P4o10, So2 And So3 Only) And Chlorides (Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5 Only) In Terms Of Their Outer Shell (Valence Shell) Electrons
- 14.106The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions, If Any, Of The Oxides Na2o, Mgo, Al 2o3, Sio2, P4o10, So2 And So3 With Water Including The Likely Phs Of The Solutions Obtained
- 14.107The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Acid/base Behaviour Of The Oxides Na2o, Mgo, Al 2o3, P4o10, So2 And So3 And The Hydroxides Naoh, Mg(Oh)2 And Al(Oh)3 Including, Where Relevant, Amphoteric Behaviour In Reactions With Acids And Bases (Sodium Hydroxide Only)
- 14.108The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Reactions Of The Chlorides Nacl, Mgcl 2, Al Cl 3, Sicl 4, Pcl 5 With Water Including The Likely Phs Of The Solutions Obtained
- 14.109The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Explain The Variations And Trends In 9.2.2, 9.2.3, 9.2.4 And 9.2.5 In Terms Of Bonding And Electronegativity
- 14.110The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Suggest The Types Of Chemical Bonding Present In The Chlorides And Oxides From Observations Of Their Chemical And Physical Properties
- 14.111Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen, Water And Dilute Hydrochloric And Sulfuric Acids
- 14.112Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Thermal Decomposition Of The Nitrates And Carbonates, To Include The Trend In Thermal Stabilities
- 14.113Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Make Predictions From, The Trends In Physical And Chemical Properties Of The Elements Involved In The Reactions In 10.1.1 And The Compounds Involved In 10.1.2, 10.1.3 And 10.1.5
- 14.114Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: State The Variation In The Solubilities Of The Hydroxides And Sulfates
- 14.115Group 17: Physical Properties Of The Group 17 Elements: Describe The Colours And The Trend In Volatility Of Chlorine, Bromine And Iodine
- 14.116Group 17: Physical Properties Of The Group 17 Elements: Describe And Explain The Trend In The Bond Strength Of The Halogen Molecules
- 14.117Group 17: Physical Properties Of The Group 17 Elements: Interpret The Volatility Of The Elements In Terms Of Instantaneous Dipole–induced Dipole Forces
- 14.118Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Reactivity Of The Elements As Oxidising Agents
- 14.119Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Reactions Of The Elements With Hydrogen And Explain Their Relative Reactivity In These Reactions
- 14.120Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Thermal Stabilities Of The Hydrogen Halides And Explain These In Terms Of Bond Strengths
- 14.121Group 17: Some Reactions Of The Halide Ions: Describe The Relative Reactivity Of Halide Ions As Reducing Agents
- 14.122Group 17: Some Reactions Of The Halide Ions: Describe And Explain The Reactions Of Halide Ions With: (A) Aqueous Silver Ions Followed By Aqueous Ammonia (The Formation And Formula Of The [ag(Nh3) 2] + Complex Is Not Required) (B) Concentrated Sulfuric Acid, To Include Balanced Chemical Equations
- 14.123Group 17: The Reactions Of Chlorine: Explain, Including By Use Of An Equation, The Use Of Chlorine In Water Purification To Include The Production Of The Active Species Hocl And Clo– Which Kill Bacteria
- 14.124Nitrogen And Sulfur: Nitrogen And Sulfur: Explain The Lack Of Reactivity Of Nitrogen, With Reference To Triple Bond Strength And Lack Of Polarity
- 14.125Nitrogen And Sulfur: Nitrogen And Sulfur: Describe And Explain: (A) The Basicity Of Ammonia, Using The Brønsted–lowry Theory (B) The Structure Of The Ammonium Ion And Its Formation By An Acid–base Reaction (C) The Displacement Of Ammonia From Ammonium Salts By An Acid–base Reaction
- 14.126Nitrogen And Sulfur: Nitrogen And Sulfur: State And Explain The Natural And Man-made Occurrences Of Oxides Of Nitrogen And Their Catalytic Removal From The Exhaust Gases Of Internal Combustion Engines
- 14.127Nitrogen And Sulfur: Nitrogen And Sulfur: Understand That Atmospheric Oxides Of Nitrogen (No And No2) Can React With Unburned Hydrocarbons To Form Peroxyacetyl Nitrate, Pan, Which Is A Component Of Photochemical Smog
- 14.128Nitrogen And Sulfur: Nitrogen And Sulfur: Describe The Role Of No And No2 In The Formation Of Acid Rain Both Directly And In Their Catalytic Role In The Oxidation Of Atmospheric Sulfur Dioxide
- 14.129An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Define The Term Hydrocarbon As A Compound Made Up Of C And H Atoms Only
- 14.130An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That Alkanes Are Simple Hydrocarbons With No Functional Group
- 14.131An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That The Compounds In The Table On Pages 29 And 30 Contain A Functional Group Which Dictates Their Physical And Chemical Properties
- 14.132An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Interpret And Use The General, Structural, Displayed And Skeletal Formulas Of The Classes Of Compound Stated In The Table On Pages 29 And 30
- 14.133An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand And Use Systematic Nomenclature Of Simple Aliphatic Organic Molecules With Functional Groups Detailed In The Table On Pages 29 And 30, Up To Six Carbon Atoms (Six Plus Six For Esters, Straight Chains Only For Esters And Nitriles)
- 14.134An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Deduce The Molecular And/or Empirical Formula Of A Compound, Given Its Structural, Displayed Or Skeletal Formula
- 14.135An Introduction To As Level Organic Chemistry: Characteristic Organic Reactions: Interpret And Use The Following Terminology Associated With Types Of Organic Compounds And Reactions: (A) Homologous Series (B) Saturated And Unsaturated (C) Homolytic And Heterolytic Fission (D) Free Radical, Initiation, Propagation, Termination (E) Nucleophile, Electrophile, Nucleophilic, Electrophilic (F) Addition, Substitution, Elimination, Hydrolysis, Condensation (G) Oxidation And Reduction (In Equations For Organic Redox Reactions, The Symbol [o] Can Be Used To Represent One Atom Of Oxygen From An Oxidising Agent And The Symbol [h] To Represent One Atom Of Hydrogen From A Reducing Agent)
- 14.136An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe Organic Molecules As Either Straight-chained, Branched Or Cyclic
- 14.137An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe And Explain The Shape Of, And Bond Angles In, Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 14.138An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe The Arrangement Of Σ And Π Bonds In Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 14.139An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Understand And Use The Term Planar When Describing The Arrangement Of Atoms In Organic Molecules, For Example Ethene
- 14.140An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Structural Isomerism And Its Division Into Chain, Positional And Functional Group Isomerism
- 14.141An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Stereoisomerism And Its Division Into Geometrical (Cis/trans) And Optical Isomerism (Use Of E/z Nomenclature Is Acceptable But Is Not Required)
- 14.142An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Geometrical (Cis/trans) Isomerism In Alkenes, And Explain Its Origin In Terms Of Restricted Rotation Due To The Presence Of Π Bonds
- 14.143An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Explain What Is Meant By A Chiral Centre And That Such A Centre Gives Rise To Two Optical Isomers (Enantiomers) (Candidates Should Appreciate That Compounds Can Contain More Than One Chiral Centre, But Knowledge Of Meso Compounds, Or Nomenclature Such As Diastereoisomers Is Not Required.)
- 14.144An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Identify Chiral Centres And Geometrical (Cis/trans) Isomerism In A Molecule Of Given Structural Formula Including Cyclic Compounds
- 14.145An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Deduce The Possible Isomers For An Organic Molecule Of Known Molecular Formula
- 14.146Hydrocarbons: Alkanes: Recall The Reactions (Reagents And Conditions) By Which Alkanes Can Be Produced: (A) Addition Of Hydrogen To An Alkene In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (B) Cracking Of A Longer Chain Alkane, Heat With Al 2o3
- 14.147Hydrocarbons: Alkanes: Describe: (A) The Complete And Incomplete Combustion Of Alkanes (B) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane
- 14.148Hydrocarbons: Alkanes: Describe The Mechanism Of Free-radical Substitution With Reference To The Initiation, Propagation And Termination Steps
- 14.149Hydrocarbons: Alkanes: Suggest How Cracking Can Be Used To Obtain More Useful Alkanes And Alkenes Of Lower Mr From Heavier Crude Oil Fractions
- 14.150Hydrocarbons: Alkanes: Understand The General Unreactivity Of Alkanes, Including Towards Polar Reagents In Terms Of The Strength Of The C–h Bonds And Their Relative Lack Of Polarity
- 14.151Hydrocarbons: Alkanes: Recognise The Environmental Consequences Of Carbon Monoxide, Oxides Of Nitrogen And Unburnt Hydrocarbons Arising From The Combustion Of Alkanes In The Internal Combustion Engine And Of Their Catalytic Removal
- 14.152Hydrocarbons: Alkenes: Recall The Reactions (Including Reagents And Conditions) By Which Alkenes Can Be Produced: (A) Elimination Of Hx From A Halogenoalkane By Ethanolic Naoh And Heat (B) Dehydration Of An Alcohol, By Using A Heated Catalyst (E.g. Al 2o3) Or A Concentrated Acid (E.g. Concentrated H2so4) (C) Cracking Of A Longer Chain Alkane
- 14.153Hydrocarbons: Alkenes: Describe The Following Reactions Of Alkenes: (A) The Electrophilic Addition Of (I) Hydrogen In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (Ii) Steam, H2o(G) And H3po4 Catalyst (Iii) A Hydrogen Halide, Hx(G), At Room Temperature (Iv) A Halogen, X2 (B) The Oxidation By Cold Dilute Acidified Kmno4 To Form The Diol (C) The Oxidation By Hot Concentrated Acidified Kmno4 Leading To The Rupture Of The Carbon–carbon Double Bond And The Identities Of The Subsequent Products To Determine The Position Of Alkene Linkages In Larger Molecules (D) Addition Polymerisation Exemplified By The Reactions Of Ethene And Propene
- 14.154Hydrocarbons: Alkenes: Describe The Use Of Aqueous Bromine To Show The Presence Of A C=c Bond
- 14.155Hydrocarbons: Alkenes: Describe The Mechanism Of Electrophilic Addition In Alkenes, Using Bromine/ethene And Hydrogen Bromide/propene As Examples
- 14.156Hydrocarbons: Alkenes: Describe And Explain The Inductive Effects Of Alkyl Groups On The Stability Of Primary, Secondary And Tertiary Cations Formed During Electrophilic Addition (This Should Be Used To Explain Markovnikov Addition)
- 14.157Halogen Compounds: Halogenoalkanes: Recall The Reactions (Reagents And Conditions) By Which Halogenoalkanes Can Be Produced: (A) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane (B) Electrophilic Addition Of An Alkene With A Halogen, X2, Or Hydrogen Halide, Hx(G), At Room Temperature (C) Substitution Of An Alcohol, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2
- 14.158Halogen Compounds: Halogenoalkanes: Classify Halogenoalkanes Into Primary, Secondary And Tertiary
- 14.159Halogen Compounds: Halogenoalkanes: Describe The Following Nucleophilic Substitution Reactions: (A) The Reaction With Naoh(Aq) And Heat To Produce An Alcohol (B) The Reaction With Kcn In Ethanol And Heat To Produce A Nitrile (C) The Reaction With Nh3 In Ethanol Heated Under Pressure To Produce An Amine (D) The Reaction With Aqueous Silver Nitrate In Ethanol As A Method Of Identifying The Halogen Present As Exemplified By Bromoethane
- 14.160Halogen Compounds: Halogenoalkanes: Describe The Elimination Reaction With Naoh In Ethanol And Heat To Produce An Alkene As Exemplified By Bromoethane
- 14.161Halogen Compounds: Halogenoalkanes: Describe The Sn1 And Sn2 Mechanisms Of Nucleophilic Substitution In Halogenoalkanes Including The Inductive Effects Of Alkyl Groups
- 14.162Halogen Compounds: Halogenoalkanes: Recall That Primary Halogenoalkanes Tend To React Via The Sn2 Mechanism; Tertiary Halogenoalkanes Via The Sn1 Mechanism; And Secondary Halogenoalkanes By A Mixture Of The Two, Depending On Structure
- 14.163Halogen Compounds: Halogenoalkanes: Describe And Explain The Different Reactivities Of Halogenoalkanes (With Particular Reference To The Relative Strengths Of The C–x Bonds As Exemplified By The Reactions Of Halogenoalkanes With Aqueous Silver Nitrates)
- 14.164Hydroxy Compounds: Alcohols: Recall The Reactions (Reagents And Conditions) By Which Alcohols Can Be Produced: (A) Electrophilic Addition Of Steam To An Alkene, H2o(G) And H3po4 Catalyst (B) Reaction Of Alkenes With Cold Dilute Acidified Potassium Manganate(Vii) To Form A Diol (C) Substitution Of A Halogenoalkane Using Naoh(Aq) And Heat (D) Reduction Of An Aldehyde Or Ketone Using Nabh4 Or Lialh4 (E) Reduction Of A Carboxylic Acid Using Lialh4 (F) Hydrolysis Of An Ester Using Dilute Acid Or Dilute Alkali And Heat
- 14.165Hydroxy Compounds: Alcohols: Describe: (A) The Reaction With Oxygen (Combustion) (B) Substitution To Form Halogenoalkanes, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2 (C) The Reaction With Na(S) (D) Oxidation With Acidified K2cr2o7 Or Acidified Kmno4 To: (I) Carbonyl Compounds By Distillation (Ii) Carboxylic Acids By Refluxing (Primary Alcohols Give Aldehydes Which Can Be Further Oxidised To Carboxylic Acids, Secondary Alcohols Give Ketones, Tertiary Alcohols Cannot Be Oxidised) (E) Dehydration To An Alkene, By Using A Heated Catalyst, E.g. Al 2o3 Or A Concentrated Acid (F) Formation Of Esters By Reaction With Carboxylic Acids And Concentrated H2so4 As Catalyst As Exemplified By Ethanol
- 14.166Hydroxy Compounds: Alcohols: (A) Classify Alcohols As Primary, Secondary And Tertiary Alcohols, To Include Examples With More Than One Alcohol Group (B) State Characteristic Distinguishing Reactions, E.g. Mild Oxidation With Acidified K2cr2o7 , Colour Change From Orange To Green
- 14.167Hydroxy Compounds: Alcohols: Deduce The Presence Of A Ch3ch(Oh)– Group In An Alcohol, Ch3ch(Oh)–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 14.168Hydroxy Compounds: Alcohols: Explain The Acidity Of Alcohols Compared With Water
- 14.169Carbonyl Compounds: Aldehydes And Ketones: Recall The Reactions (Reagents And Conditions) By Which Aldehydes And Ketones Can Be Produced: (A) The Oxidation Of Primary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Aldehydes (B) The Oxidation Of Secondary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Ketones
- 14.170Carbonyl Compounds: Aldehydes And Ketones: Describe: (A) The Reduction Of Aldehydes And Ketones Using Nabh4 Or Lialh4 To Produce Alcohols (B) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat To Produce Hydroxynitriles As Exemplified By Ethanal And Propanone
- 14.171Carbonyl Compounds: Aldehydes And Ketones: Describe The Mechanism Of The Nucleophilic Addition Reactions Of Hydrogen Cyanide With Aldehydes And Ketones In 17.1.2(B)
- 14.172Carbonyl Compounds: Aldehydes And Ketones: Describe The Use Of 2,4-dinitrophenylhydrazine (2,4-dnph Reagent) To Detect The Presence Of Carbonyl Compounds
- 14.173Carbonyl Compounds: Aldehydes And Ketones: Deduce The Nature (Aldehyde Or Ketone) Of An Unknown Carbonyl Compound From The Results Of Simple Tests (Fehling’s And Tollens’ Reagents; Ease Of Oxidation)
- 14.174Carbonyl Compounds: Aldehydes And Ketones: Deduce The Presence Of A Ch3co– Group In An Aldehyde Or Ketone, Ch3co–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 14.175Carboxylic Acids And Derivatives: Carboxylic Acids: Recall The Reactions By Which Carboxylic Acids Can Be Produced: (A) Oxidation Of Primary Alcohols And Aldehydes With Acidified K2cr2o7 Or Acidified Kmno4 And Refluxing (B) Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification (C) Hydrolysis Of Esters With Dilute Acid Or Dilute Alkali And Heat Followed By Acidification
- 14.176Carboxylic Acids And Derivatives: Carboxylic Acids: Describe: (A) The Redox Reaction With Reactive Metals To Produce A Salt And H2(G) (B) The Neutralisation Reaction With Alkalis To Produce A Salt And H2o(L ) (C) The Acid–base Reaction With Carbonates To Produce A Salt And H2o(L) And Co2(G) (D) Esterification With Alcohols With Concentrated H2so4 As Catalyst (E) Reduction By Lialh4 To Form A Primary Alcohol
- 14.177Carboxylic Acids And Derivatives: Esters: Recall The Reaction (Reagents And Conditions) By Which Esters Can Be Produced: (A) The Condensation Reaction Between An Alcohol And A Carboxylic Acid With Concentrated H₂so₄ As Catalyst
- 14.178Carboxylic Acids And Derivatives: Esters: Describe The Hydrolysis Of Esters By Dilute Acid And By Dilute Alkali And Heatv
- 14.179Nitrogen Compounds: Primary Amines: Recall The Reactions By Which Amines Can Be Produced: (A) Reaction Of A Halogenoalkane With Nh₃ In Ethanol Heated Under Pressure Classification Of Amines Will Not Be Tested At As Level.
- 14.180Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Nitriles Can Be Produced: (A) Reaction Of A Halogenoalkane With Kcn In Ethanol And Heat
- 14.181Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Hydroxynitriles Can Be Produced: (A) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat
- 14.182Nitrogen Compounds: Nitriles And Hydroxynitriles: Describe The Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification To Produce A Carboxylic Acid
- 14.183Polymerisation: Addition Polymerisation: Describe Addition Polymerisation As Exemplified By Poly(Ethene) And Poly(Chloroethene), Pvc
- 14.184Polymerisation: Addition Polymerisation: Deduce The Repeat Unit Of An Addition Polymer Obtained From A Given Monomer
- 14.185Polymerisation: Addition Polymerisation: Identify The Monomer(S) Present In A Given Section Of An Addition Polymer Molecule
- 14.186Polymerisation: Addition Polymerisation: Recognise The Difficulty Of The Disposal Of Poly(Alkene)s, I.e. Non-biodegradability And Harmful Combustion Products
- 14.187Organic Synthesis: Organic Synthesis: For An Organic Molecule Containing Several Functional Groups: (A) Identify Organic Functional Groups Using The Reactions In The Syllabus (B) Predict Properties And Reactions
- 14.188Organic Synthesis: Organic Synthesis: Devise Multi-step Synthetic Routes For Preparing Organic Molecules Using The Reactions In The Syllabus
- 14.189Organic Synthesis: Organic Synthesis: Analyse A Given Synthetic Route In Terms Of Type Of Reaction And Reagents Used For Each Step Of It, And Possible By-products Analysis
- 14.190Analytical Techniques: Infrared Spectroscopy: Analyse An Infrared Spectrum Of A Simple Molecule To Identify Functional Groups (See The Data Section For The Functional Groups Required)
- 14.191Analytical Techniques: Mass Spectrometry: Analyse Mass Spectra In Terms Of M/e Values And Isotopic Abundances (Knowledge Of The Working Of The Mass Spectrometer Is Not Required)
- 14.192Analytical Techniques: Mass Spectrometry: Calculate The Relative Atomic Mass Of An Element Given The Relative Abundances Of Its Isotopes, Or Its Mass Spectrum
- 14.193Analytical Techniques: Mass Spectrometry: Deduce The Molecular Mass Of An Organic Molecule From The Molecular Ion Peak In A Mass Spectrum
- 14.194Analytical Techniques: Mass Spectrometry: Suggest The Identity Of Molecules Formed By Simple Fragmentation In A Given Mass Spectrum
- 14.195Analytical Techniques: Mass Spectrometry: Deduce The Number Of Carbon Atoms, N, In A Compound Using The [m + 1]+ Peak And The Formula N = 100 × Abundance Of [m + 1]+ Ion 1.1 × Abundance Of M+ Ion
- 14.196Analytical Techniques: Mass Spectrometry: Deduce The Presence Of Bromine And Chlorine Atoms In A Compound Using The [m + 2]+ Peak
- Practice Questions/ Practice ExamsPractice Questions/ Exams Based Both On Actual Exam Pattern And On Topical Content To Boost Preparation And Improve Performance198
- 15.1Practice Questions: Atomic Structure: Particles In The Atom And Atomic Radius: Understand That Atoms Are Mostly Empty Space Surrounding A Very Small, Dense Nucleus That Contains Protons And Neutrons; Electrons Are Found In Shells In The Empty Space Around The Nucleus
- 15.2Practice Questions: Atomic Structure: Particles In The Atom And Atomic Radius: Identify And Describe Protons, Neutrons And Electrons In Terms Of Their Relative Charges And Relative Masses
- 15.3Practice Questions: Atomic Structure: Particles In The Atom And Atomic Radius: Understand The Terms Atomic And Proton Number; Mass And Nucleon Number
- 15.4Practice Questions: Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Distribution Of Mass And Charge Within An Atom
- 15.5Practice Questions: Atomic Structure: Particles In The Atom And Atomic Radius: Describe The Behaviour Of Beams Of Protons, Neutrons And Electrons Moving At The Same Velocity In An Electric Field
- 15.6Practice Questions: Atomic Structure: Particles In The Atom And Atomic Radius: Determine The Numbers Of Protons, Neutrons And Electrons Present In Both Atoms And Ions Given Atomic Or Proton Number, Mass Or Nucleon Number And Charge
- 15.7Practice Questions: Atomic Structure: Particles In The Atom And Atomic Radius: State And Explain Qualitatively The Variations In Atomic Radius And Ionic Radius Across A Period And Down A Group
- 15.8Practice Questions: Atomic Structure: Isotopes: Define The Term Isotope In Terms Of Numbers Of Protons And Neutrons
- 15.9Practice Questions: Atomic Structure: Isotopes: Understand The Notation X Ya For Isotopes, Where X Is The Mass Or Nucleon Number And Y Is The Atomic Or Proton Number
- 15.10Practice Questions: Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have The Same Chemical Properties
- 15.11Practice Questions: Atomic Structure: Isotopes: State That And Explain Why Isotopes Of The Same Element Have Different Physical Properties, Limited To Mass And Density
- 15.12Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand The Terms: • Shells, Sub-shells And Orbitals • Principal Quantum Number (N) • Ground State, Limited To Electronic Configuration
- 15.13Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Number Of Orbitals Making Up S, P And D Sub-shells, And The Number Of Electrons That Can Fill S, P And D Sub-shells
- 15.14Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Order Of Increasing Energy Of The Sub-shells Within The First Three Shells And The 4s And 4p Sub-shells
- 15.15Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe The Electronic Configurations To Include The Number Of Electrons In Each Shell, Sub-shell And Orbital
- 15.16Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Explain The Electronic Configurations In Terms Of Energy Of The Electrons And Inter-electron Repulsion
- 15.17Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Determine The Electronic Configuration Of Atoms And Ions Given The Atomic Or Proton Number And Charge, Using Either Of The Following Conventions: E.g. For Fe: 1s2 2s2 2p6 3s2 3p6 3d6 4s2 (Full Electronic Configuration) Or [ar] 3d6 4s2 (Shorthand Electronic Configuration)
- 15.18Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Understand And Use The Electrons In Boxes Notation E.g. For Fe: [ar]
- 15.19Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe And Sketch The Shapes Of S And P Orbitals
- 15.20Practice Questions: Atomic Structure: Electrons, Energy Levels And Atomic Orbitals: Describe A Free Radical As A Species With One Or More Unpaired Electrons
- 15.21Practice Questions: Atomic Structure: Ionisation Energy: Define And Use The Term First Ionisation Energy, Ie
- 15.22Practice Questions: Atomic Structure: Ionisation Energy: Construct Equations To Represent First, Second And Subsequent Ionisation Energies
- 15.23Practice Questions: Atomic Structure: Ionisation Energy: Identify And Explain The Trends In Ionisation Energies Across A Period And Down A Group Of The Periodic Table
- 15.24Practice Questions: Atomic Structure: Ionisation Energy: Identify And Explain The Variation In Successive Ionisation Energies Of An Element
- 15.25Practice Questions: Atomic Structure: Ionisation Energy: Understand That Ionisation Energies Are Due To The Attraction Between The Nucleus And The Outer Electron
- 15.26Practice Questions: Atomic Structure: Ionisation Energy: Explain The Factors Influencing The Ionisation Energies Of Elements In Terms Of Nuclear Charge, Atomic/ionic Radius, Shielding By Inner Shells And Sub-shells And Spin-pair Repulsion
- 15.27Practice Questions: Atomic Structure: Ionisation Energy: Deduce The Electronic Configurations Of Elements Using Successive Ionisation Energy Data
- 15.28Practice Questions: Atomic Structure: Ionisation Energy: Deduce The Position Of An Element In The Periodic Table Using Successive Ionisation Energy Data
- 15.29Practice Questions: Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define The Unified Atomic Mass Unit As One Twelfth Of The Mass Of A Carbon-12 Atom
- 15.30Practice Questions: Atoms, Molecules And Stoichiometry: Relative Masses Of Atoms And Molecules: Define Relative Atomic Mass, Ar , Relative Isotopic Mass, Relative Molecular Mass, Mr , And Relative Formula Mass In Terms Of The Unified Atomic Mass Unit
- 15.31Practice Questions: Atoms, Molecules And Stoichiometry: The Mole And The Avogadro Constant: Define And Use The Term Mole In Terms Of The Avogadro Constant
- 15.32Practice Questions: Atoms, Molecules And Stoichiometry: Formulas: Write Formulas Of Ionic Compounds From Ionic Charges And Oxidation Numbers (Shown By A Roman Numeral), Including: (A) The Prediction Of Ionic Charge From The Position Of An Element In The Periodic Table (B) Recall Of The Names And Formulas For The Following Ions: No3 – , Co3 2–, So4 2–, Oh– , Nh4 + , Zn2+, Ag+ , Hco3 – , Po4 3–
- 15.33Practice Questions: Atoms, Molecules And Stoichiometry: Formulas: (A) Write And Construct Equations (Which Should Be Balanced), Including Ionic Equations (Which Should Not Include Spectator Ions) (B) Use Appropriate State Symbols In Equations
- 15.34Practice Questions: Atoms, Molecules And Stoichiometry: Formulas: Define And Use The Terms Empirical And Molecular Formula
- 15.35Practice Questions: Atoms, Molecules And Stoichiometry: Formulas: Understand And Use The Terms Anhydrous, Hydrated And Water Of Crystallisation
- 15.36Practice Questions: Atoms, Molecules And Stoichiometry: Formulas: Calculate Empirical And Molecular Formulas, Using Given Data
- 15.37Practice Questions: Atoms, Molecules And Stoichiometry: Reacting Masses And Volumes (Of Solutions And Gases): Perform Calculations Including Use Of The Mole Concept, Involving: (A) Reacting Masses (From Formulas And Equations) Including Percentage Yield Calculations (B) Volumes Of Gases (E.g. In The Burning Of Hydrocarbons) (C) Volumes And Concentrations Of Solutions (D) Limiting Reagent And Excess Reagent (When Performing Calculations, Candidates’ Answers Should Reflect The Number Of Significant Figures Given Or Asked For In The Question. When Rounding Up Or Down, Candidates Should Ensure That Significant Figures Are Neither Lost Unnecessarily Nor Used Beyond What Is Justified (See Also Mathematical Requirements Section).) (E) Deduce Stoichiometric Relationships From Calculations Such As Those In 2.4.1(A)–(D)
- 15.38Practice Questions: Chemical Bonding: Electronegativity And Bonding: Define Electronegativity As The Power Of An Atom To Attract Electrons To Itself
- 15.39Practice Questions: Chemical Bonding: Electronegativity And Bonding: Explain The Factors Influencing The Electronegativities Of The Elements In Terms Of Nuclear Charge, Atomic Radius And Shielding By Inner Shells And Sub-shells
- 15.40Practice Questions: Chemical Bonding: Electronegativity And Bonding: State And Explain The Trends In Electronegativity Across A Period And Down A Group Of The Periodic Table
- 15.41Practice Questions: Chemical Bonding: Electronegativity And Bonding: Use The Differences In Pauling Electronegativity Values To Predict The Formation Of Ionic And Covalent Bonds (The Presence Of Covalent Character In Some Ionic Compounds Will Not Be Assessed) (Pauling Electronegativity Values Will Be Given Where Necessary)
- 15.42Practice Questions: Chemical Bonding: Ionic Bonding: Define Ionic Bonding As The Electrostatic Attraction Between Oppositely Charged Ions (Positively Charged Cations And Negatively Charged Anions)
- 15.43Practice Questions: Chemical Bonding: Ionic Bonding: Describe Ionic Bonding Including The Examples Of Sodium Chloride, Magnesium Oxide And Calcium Fluoride
- 15.44Practice Questions: Chemical Bonding: Metallic Bonding: Define Metallic Bonding As The Electrostatic Attraction Between Positive Metal Ions And Delocalised Electrons
- 15.45Practice Questions: Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: Define Covalent Bonding As Electrostatic Attraction Between The Nuclei Of Two Atoms And A Shared Pair Of Electrons (A) Describe Covalent Bonding In Molecules Including: • Hydrogen, H2 • Oxygen, O2 • Nitrogen, N2 • Chlorine, Cl 2 • Hydrogen Chloride, Hcl • Carbon Dioxide, Co2 • Ammonia, Nh3 • Methane, Ch4 • Ethane, C2h6 • Ethene, C2h4 (B) Understand That Elements In Period 3 Can Expand Their Octet Including In The Compounds Sulfur Dioxide, So2, Phosphorus Pentachloride, Pcl 5 , And Sulfur Hexafluoride, Sf6 (C) Describe Coordinate (Dative Covalent) Bonding, Including In The Reaction Between Ammonia And Hydrogen Chloride Gases To Form The Ammonium Ion, Nh4 + , And In The Al 2cl 6 Molecule
- 15.46Practice Questions: Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: (A) Describe Covalent Bonds In Terms Of Orbital Overlap Giving Σ And Π Bonds: • Σ Bonds Are Formed By Direct Overlap Of Orbitals Between The Bonding Atoms • Π Bonds Are Formed By The Sideways Overlap Of Adjacent P Orbitals Above And Below The Σ Bond (B) Describe How The Σ And Π Bonds Form In Molecules Including H₂, C₂h₆, C₂h₄, Hcn And N₂ (C) Use The Concept Of Hybridisation To Describe Sp, Sp² And Sp³ Orbitals
- 15.47Practice Questions: Chemical Bonding: Covalent Bonding And Coordinate (Dative Covalent) Bonding: A) Define The Terms: • Bond Energy As The Energy Required To Break One Mole Of A Particular Covalent Bond In The Gaseous State • Bond Length As The Internuclear Distance Of Two Covalently Bonded Atoms (B) Use Bond Energy Values And The Concept Of Bond Length To Compare The Reactivity Of Covalent Molecules
- 15.48Practice Questions: Chemical Bonding: Shapes Of Molecules: State And Explain The Shapes Of, And Bond Angles In, Molecules By Using Vsepr Theory, Including As Simple Examples: • Bf3 (Trigonal Planar, 120°) • Co2 (Linear, 180°) • Ch4 (Tetrahedral, 109.5°) • Nh3 (Pyramidal, 107°) • H2o (Non-linear, 104.5°) • Sf6 (Octahedral, 90°) • Pf5 (Trigonal Bipyramidal, 120° And 90°)
- 15.49Practice Questions: Chemical Bonding: Shapes Of Molecules: Predict The Shapes Of, And Bond Angles In, Molecules And Ions Analogous To Those Specified In 3.5.1
- 15.50Practice Questions: Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Hydrogen Bonding, Limited To Molecules Containing N–h And O–h Groups, Including Ammonia And Water As Simple Examples (B) Use The Concept Of Hydrogen Bonding To Explain The Anomalous Properties Of H₂o (Ice And Water): • Its Relatively High Melting And Boiling Points • Its Relatively High Surface Tension • The Density Of The Solid Ice Compared With The Liquid Water
- 15.51Practice Questions: Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: Use The Concept Of Electronegativity To Explain Bond Polarity And Dipole Moments Of Molecules
- 15.52Practice Questions: Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: (A) Describe Van Der Waals’ Forces As The Intermolecular Forces Between Molecular Entities Other Than Those Due To Bond Formation, And Use The Term Van Der Waals’ Forces As A Generic Term To Describe All Intermolecular Forces (B) Describe The Types Of Van Der Waals’ Forces: • Instantaneous Dipole–induced Dipole (Id-id) Forces, Also Called London Dispersion Forces • Permanent Dipole–permanent Dipole (Pd-pd) Forces, Including Hydrogen Bonding (C) Describe Hydrogen Bonding And Understand That Hydrogen Bonding Is A Special Case Of Permanent Dipole–permanent Dipole Forces Between Molecules Where Hydrogen Is Bonded To A Highly Electronegative Atom
- 15.53Practice Questions: Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: State That, In General, Ionic, Covalent And Metallic Bonding Are Stronger Than Intermolecular Forces
- 15.54Practice Questions: Chemical Bonding: Dot-and-cross Diagrams: Use Dot-and-cross Diagrams To Illustrate Ionic, Covalent And Coordinate Bonding Including The Representation Of Any Compounds Stated In 3.4 And 3.5 (Dot-and-cross Diagrams May Include Species With Atoms Which Have An Expanded Octet Or Species With An Odd Number Of Electrons)
- 15.55Practice Questions: States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Explain The Origin Of Pressure In A Gas In Terms Of Collisions Between Gas Molecules And The Wall Of The Container
- 15.56Practice Questions: States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: Understand That Ideal Gases Have Zero Particle Volume And No Intermolecular Forces Of Attraction
- 15.57Practice Questions: States Of Matter: The Gaseous State: Ideal And Real Gases And Pv = Nrt: State And Use The Ideal Gas Equation Pv = Nrt In Calculations, Including In The Determination Of Mr
- 15.58Practice Questions: States Of Matter: Bonding And Structure: Describe, In Simple Terms, The Lattice Structure Of A Crystalline Solid Which Is: (A) Giant Ionic, Including Sodium Chloride And Magnesium Oxide (B) Simple Molecular, Including Iodine, Buckminsterfullerene C60 And Ice (C) Giant Molecular, Including Silicon(Iv) Oxide, Graphite And Diamond (D) Giant Metallic, Including Copper
- 15.59Practice Questions: States Of Matter: Bonding And Structure: Describe, Interpret And Predict The Effect Of Different Types Of Structure And Bonding On The Physical Properties Of Substances, Including Melting Point, Boiling Point, Electrical Conductivity And Solubility
- 15.60Practice Questions: States Of Matter: Bonding And Structure: Deduce The Type Of Structure And Bonding Present In A Substance From Given Information
- 15.61Practice Questions: Chemical Energetics: Enthalpy Change, Δh: Understand That Chemical Reactions Are Accompanied By Enthalpy Changes And These Changes Can Be Exothermic (δh Is Negative) Or Endothermic (δh Is Positive)
- 15.62Practice Questions: Chemical Energetics: Enthalpy Change, Δh: Construct And Interpret A Reaction Pathway Diagram, In Terms Of The Enthalpy Change Of The Reaction And Of The Activation Energy
- 15.63Practice Questions: Chemical Energetics: Enthalpy Change, Δh: Define And Use The Terms: (A) Standard Conditions (This Syllabus Assumes That These Are 298k And 101kpa) Shown By ⦵ . (B) Enthalpy Change With Particular Reference To: Reaction, Δhr , Formation, Δhf , Combustion, Δhc , Neutralisation, Δhneut
- 15.64Practice Questions: Chemical Energetics: Enthalpy Change, Δh: Understand That Energy Transfers Occur During Chemical Reactions Because Of The Breaking And Making Of Chemical Bonds
- 15.65Practice Questions: Chemical Energetics: Enthalpy Change, Δh: Use Bond Energies (δh Positive, I.e. Bond Breaking) To Calculate Enthalpy Change Of Reaction, Δhr
- 15.66Practice Questions: Chemical Energetics: Enthalpy Change, Δh: Understand That Some Bond Energies Are Exact And Some Bond Energies Are Averages
- 15.67Practice Questions: Chemical Energetics: Enthalpy Change, Δh: Calculate Enthalpy Changes From Appropriate Experimental Results, Including The Use Of The Relationships Q = Mcδt And Δh = –mcδt/ N
- 15.68Practice Questions: Chemical Energetics: Hess’s Law: Apply Hess’s Law To Construct Simple Energy Cycles
- 15.69Practice Questions: Chemical Energetics: Hess’s Law: Carry Out Calculations Using Cycles And Relevant Energy Terms, Including: (A) Determining Enthalpy Changes That Cannot Be Found By Direct Experiment (B) Use Of Bond Energy Data
- 15.70Practice Questions: Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Calculate Oxidation Numbers Of Elements In Compounds And Ions
- 15.71Practice Questions: Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use Changes In Oxidation Numbers To Help Balance Chemical Equations
- 15.72Practice Questions:Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Redox, Oxidation, Reduction And Disproportionation In Terms Of Electron Transfer And Changes In Oxidation Number
- 15.73Practice Questions: Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Explain And Use The Terms Oxidising Agent And Reducing Agent
- 15.74Practice Questions: Electrochemistry: Redox Processes: Electron Transfer And Changes In Oxidation Number (Oxidation State): Use A Roman Numeral To Indicate The Magnitude Of The Oxidation Number Of An Element
- 15.75Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: (A) Understand What Is Meant By A Reversible Reaction (B) Understand What Is Meant By Dynamic Equilibrium In Terms Of The Rate Of Forward And Reverse Reactions Being Equal And The Concentration Of Reactants And Products Remaining Constant (C) Understand The Need For A Closed System In Order To Establish Dynamic Equilibrium
- 15.76Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Define Le Chatelier’s Principle As: If A Change Is Made To A System At Dynamic Equilibrium, The Position Of Equilibrium Moves To Minimise This Change
- 15.77Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use Le Chatelier’s Principle To Deduce Qualitatively (From Appropriate Information) The Effects Of Changes In Temperature, Concentration, Pressure Or Presence Of A Catalyst On A System At Equilibrium
- 15.78Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Concentrations, Kc
- 15.79Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Terms Mole Fraction And Partial Pressure
- 15.80Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Deduce Expressions For Equilibrium Constants In Terms Of Partial Pressures, Kp (Use Of The Relationship Between Kp And Kc Is Not Required)
- 15.81Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Use The Kc And Kp Expressions To Carry Out Calculations (Such Calculations Will Not Require The Solving Of Quadratic Equations)
- 15.82Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Calculate The Quantities Present At Equilibrium, Given Appropriate Data
- 15.83Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: State Whether Changes In Temperature, Concentration Or Pressure Or The Presence Of A Catalyst Affect The Value Of The Equilibrium Constant For A Reaction
- 15.84Practice Questions: Equilibria: Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium: Describe And Explain The Conditions Used In The Haber Process And The Contact Process, As Examples Of The Importance Of An Understanding Of Dynamic Equilibrium In The Chemical Industry And The Application Of Le Chatelier’s Principle
- 15.85Practice Questions: Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Acids, Limited To Hydrochloric Acid, Hcl, Sulfuric Acid, H2so4, Nitric Acid, Hno3, Ethanoic Acid, Ch3cooh
- 15.86Practice Questions: Brønsted–lowry Theory Of Acids And Bases: State The Names And Formulas Of The Common Alkalis, Limited To Sodium Hydroxide, Naoh, Potassium Hydroxide, Koh, Ammonia, Nh3
- 15.87Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Describe The Brønsted–lowry Theory Of Acids And Bases
- 15.88Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Describe Strong Acids And Strong Bases As Fully Dissociated In Aqueous Solution And Weak Acids And Weak Bases As Partially Dissociated In Aqueous Solution
- 15.89Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Appreciate That Water Has Ph Of 7, Acid Solutions Ph Of Below 7 And Alkaline Solutions Ph Of Above 7
- 15.90Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Explain Qualitatively The Differences In Behaviour Between Strong And Weak Acids Including The Reaction With A Reactive Metal And Difference In Ph Values By Use Of A Ph Meter, Universal Indicator Or Conductivity
- 15.91Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Understand That Neutralisation Reactions Occur When H+ (Aq) And Oh– (Aq) Form H2o(L)
- 15.92Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Understand That Salts Are Formed In Neutralisation Reactions
- 15.93Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Sketch The Ph Titration Curves Of Titrations Using Combinations Of Strong And Weak Acids With Strong And Weak Alkalis
- 15.94Practice Questions: Brønsted–lowry Theory Of Acids And Bases: Select Suitable Indicators For Acid-alkali Titrations, Given Appropriate Data (Pka Values Will Not Be Used)
- 15.95Practice Questions: Reaction Kinetics: Rate Of Reaction: Explain And Use The Term Rate Of Reaction, Frequency Of Collisions, Effective Collisions And Non-effective Collisions
- 15.96Practice Questions: Reaction Kinetics: Rate Of Reaction: Explain Qualitatively, In Terms Of Frequency Of Effective Collisions, The Effect Of Concentration And Pressure Changes On The Rate Of A Reaction
- 15.97Practice Questions: Reaction Kinetics: Rate Of Reaction: Use Experimental Data To Calculate The Rate Of A Reaction
- 15.98Practice Questions: Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Define Activation Energy, Ea, As The Minimum Energy Required For A Collision To Be Effective
- 15.99Practice Questions: Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Sketch And Use The Boltzmann Distribution To Explain The Significance Of Activation Energy
- 15.100Practice Questions: Reaction Kinetics: Effect Of Temperature On Reaction Rates And The Concept Of Activation Energy: Explain Qualitatively, In Terms Both Of The Boltzmann Distribution And Of Frequency Of Effective Collisions, The Effect Of Temperature Change On The Rate Of A Reaction
- 15.101Practice Questions: Reaction Kinetics: Homogeneous And Heterogeneous Catalysts: Explain And Use The Terms Catalyst And Catalysis: (A) Explain That, In The Presence Of A Catalyst, A Reaction Has A Different Mechanism, I.e. One Of Lower Activation Energy (B) Explain This Catalytic Effect In Terms Of The Boltzmann Distribution (C) Construct And Interpret A Reaction Pathway Diagram, For A Reaction In The Presence And Absence Of An Effective Catalyst
- 15.102Practice Questions: The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Describe Qualitatively (And Indicate The Periodicity In) The Variations In Atomic Radius, Ionic Radius, Melting Point And Electrical Conductivity Of The Elements
- 15.103Practice Questions: The Periodic Table: Chemical Periodicity: Periodicity Of Physical Properties Of The Elements In Period 3: Explain The Variation In Melting Point And Electrical Conductivity In Terms Of The Structure And Bonding Of The Elements
- 15.104Practice Questions: The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen (To Give Na2o, Mgo, Al 2o3, P4o10, So2), Chlorine (To Give Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5) And Water (Na And Mg Only)
- 15.105Practice Questions: The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: State And Explain The Variation In The Oxidation Number Of The Oxides (Na2o, Mgo, Al 2o3, P4o10, So2 And So3 Only) And Chlorides (Nacl, Mgcl 2, Alcl 3, Sicl 4, Pcl 5 Only) In Terms Of Their Outer Shell (Valence Shell) Electrons
- 15.106Practice Questions: The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, And Write Equations For, The Reactions, If Any, Of The Oxides Na2o, Mgo, Al 2o3, Sio2, P4o10, So2 And So3 With Water Including The Likely Phs Of The Solutions Obtained
- 15.107Practice Questions: The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Acid/base Behaviour Of The Oxides Na2o, Mgo, Al 2o3, P4o10, So2 And So3 And The Hydroxides Naoh, Mg(Oh)2 And Al(Oh)3 Including, Where Relevant, Amphoteric Behaviour In Reactions With Acids And Bases (Sodium Hydroxide Only)
- 15.108Practice Questions: The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Describe, Explain, And Write Equations For, The Reactions Of The Chlorides Nacl, Mgcl 2, Al Cl 3, Sicl 4, Pcl 5 With Water Including The Likely Phs Of The Solutions Obtained
- 15.109Practice Questions: The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Explain The Variations And Trends In 9.2.2, 9.2.3, 9.2.4 And 9.2.5 In Terms Of Bonding And Electronegativity
- 15.110Practice Questions: The Periodic Table: Periodicity Of Chemical Properties Of The Elements In Period 3: Suggest The Types Of Chemical Bonding Present In The Chlorides And Oxides From Observations Of Their Chemical And Physical Properties
- 15.111Practice Questions: Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Reactions Of The Elements With Oxygen, Water And Dilute Hydrochloric And Sulfuric Acids
- 15.112Practice Questions: Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Write Equations For, The Thermal Decomposition Of The Nitrates And Carbonates, To Include The Trend In Thermal Stabilities
- 15.113Practice Questions: Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: Describe, And Make Predictions From, The Trends In Physical And Chemical Properties Of The Elements Involved In The Reactions In 10.1.1 And The Compounds Involved In 10.1.2, 10.1.3 And 10.1.5
- 15.114Practice Questions: Group 2: Similarities And Trends In The Properties Of The Group 2 Metals, Magnesium To Barium, And Their Compounds: State The Variation In The Solubilities Of The Hydroxides And Sulfates
- 15.115Practice Questions: Group 17: Physical Properties Of The Group 17 Elements: Describe The Colours And The Trend In Volatility Of Chlorine, Bromine And Iodine
- 15.116Practice Questions: Group 17: Physical Properties Of The Group 17 Elements: Describe And Explain The Trend In The Bond Strength Of The Halogen Molecules
- 15.117Practice Questions: Group 17: Physical Properties Of The Group 17 Elements: Interpret The Volatility Of The Elements In Terms Of Instantaneous Dipole–induced Dipole Forces
- 15.118Practice Questions: Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Reactivity Of The Elements As Oxidising Agents
- 15.119Practice Questions: Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Reactions Of The Elements With Hydrogen And Explain Their Relative Reactivity In These Reactions
- 15.120Practice Questions: Group 17: The Chemical Properties Of The Halogen Elements And The Hydrogen Halides: Describe The Relative Thermal Stabilities Of The Hydrogen Halides And Explain These In Terms Of Bond Strengths
- 15.121Practice Questions: Group 17: Some Reactions Of The Halide Ions: Describe The Relative Reactivity Of Halide Ions As Reducing Agents
- 15.122Practice Questions: Group 17: Some Reactions Of The Halide Ions: Describe And Explain The Reactions Of Halide Ions With: (A) Aqueous Silver Ions Followed By Aqueous Ammonia (The Formation And Formula Of The [ag(Nh3) 2] + Complex Is Not Required) (B) Concentrated Sulfuric Acid, To Include Balanced Chemical Equations
- 15.123Practice Questions: Group 17: The Reactions Of Chlorine: Describe And Interpret, In Terms Of Changes In Oxidation Number, The Reaction Of Chlorine With Cold And With Hot Aqueous Sodium Hydroxide And Recognise These As Disproportionation Reactions
- 15.124Practice Questions: Group 17: The Reactions Of Chlorine: Explain, Including By Use Of An Equation, The Use Of Chlorine In Water Purification To Include The Production Of The Active Species Hocl And Clo– Which Kill Bacteria
- 15.125Practice Questions: Nitrogen And Sulfur: Nitrogen And Sulfur: Explain The Lack Of Reactivity Of Nitrogen, With Reference To Triple Bond Strength And Lack Of Polarity
- 15.126Practice Questions: Nitrogen And Sulfur: Nitrogen And Sulfur: Describe And Explain: (A) The Basicity Of Ammonia, Using The Brønsted–lowry Theory (B) The Structure Of The Ammonium Ion And Its Formation By An Acid–base Reaction (C) The Displacement Of Ammonia From Ammonium Salts By An Acid–base Reaction
- 15.127Practice Questions: Nitrogen And Sulfur: Nitrogen And Sulfur: State And Explain The Natural And Man-made Occurrences Of Oxides Of Nitrogen And Their Catalytic Removal From The Exhaust Gases Of Internal Combustion Engines
- 15.128Practice Questions: Nitrogen And Sulfur: Nitrogen And Sulfur: Understand That Atmospheric Oxides Of Nitrogen (No And No2) Can React With Unburned Hydrocarbons To Form Peroxyacetyl Nitrate, Pan, Which Is A Component Of Photochemical Smog
- 15.129Practice Questions: Nitrogen And Sulfur: Nitrogen And Sulfur: Describe The Role Of No And No2 In The Formation Of Acid Rain Both Directly And In Their Catalytic Role In The Oxidation Of Atmospheric Sulfur Dioxide
- 15.130Practice Questions: An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Define The Term Hydrocarbon As A Compound Made Up Of C And H Atoms Only
- 15.131Practice Questions: An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That Alkanes Are Simple Hydrocarbons With No Functional Group
- 15.132Practice Questions: An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand That The Compounds In The Table On Pages 29 And 30 Contain A Functional Group Which Dictates Their Physical And Chemical Properties
- 15.133Practice Questions: An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Interpret And Use The General, Structural, Displayed And Skeletal Formulas Of The Classes Of Compound Stated In The Table On Pages 29 And 30
- 15.134Practice Questions: An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Understand And Use Systematic Nomenclature Of Simple Aliphatic Organic Molecules With Functional Groups Detailed In The Table On Pages 29 And 30, Up To Six Carbon Atoms (Six Plus Six For Esters, Straight Chains Only For Esters And Nitriles)
- 15.135Practice Questions: An Introduction To As Level Organic Chemistry: Formulas, Functional Groups And The Naming Of Organic Compounds: Deduce The Molecular And/or Empirical Formula Of A Compound, Given Its Structural, Displayed Or Skeletal Formula
- 15.136Practice Questions: An Introduction To As Level Organic Chemistry: Characteristic Organic Reactions: Interpret And Use The Following Terminology Associated With Types Of Organic Compounds And Reactions: (A) Homologous Series (B) Saturated And Unsaturated (C) Homolytic And Heterolytic Fission (D) Free Radical, Initiation, Propagation, Termination (E) Nucleophile, Electrophile, Nucleophilic, Electrophilic (F) Addition, Substitution, Elimination, Hydrolysis, Condensation (G) Oxidation And Reduction (In Equations For Organic Redox Reactions, The Symbol [o] Can Be Used To Represent One Atom Of Oxygen From An Oxidising Agent And The Symbol [h] To Represent One Atom Of Hydrogen From A Reducing Agent)
- 15.137Practice Questions: An Introduction To As Level Organic Chemistry: Characteristic Organic Reactions: Understand And Use The Following Terminology Associated With Types Of Organic Mechanisms: (A) Free-radical Substitution (B) Electrophilic Addition (C) Nucleophilic Substitution (D) Nucleophilic Addition (In Organic Reaction Mechanisms, The Use Of Curly Arrows To Represent Movement Of Electron Pairs Is Expected; The Arrow Should Begin At A Bond Or A Lone Pair Of Electrons)
- 15.138Practice Questions: An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe Organic Molecules As Either Straight-chained, Branched Or Cyclic
- 15.139Practice Questions: An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe And Explain The Shape Of, And Bond Angles In, Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 15.140Practice Questions: An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Describe The Arrangement Of Σ And Π Bonds In Molecules Containing Sp, Sp2 And Sp3 Hybridised Atoms
- 15.141Practice Questions: An Introduction To As Level Organic Chemistry: Shapes Of Organic Molecules; Σ And Π Bonds: Understand And Use The Term Planar When Describing The Arrangement Of Atoms In Organic Molecules, For Example Ethene
- 15.142Practice Questions: An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Structural Isomerism And Its Division Into Chain, Positional And Functional Group Isomerism
- 15.143Practice Questions: An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Stereoisomerism And Its Division Into Geometrical (Cis/trans) And Optical Isomerism (Use Of E/z Nomenclature Is Acceptable But Is Not Required)
- 15.144Practice Questions: An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Describe Geometrical (Cis/trans) Isomerism In Alkenes, And Explain Its Origin In Terms Of Restricted Rotation Due To The Presence Of Π Bonds
- 15.145Practice Questions: An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Explain What Is Meant By A Chiral Centre And That Such A Centre Gives Rise To Two Optical Isomers (Enantiomers) (Candidates Should Appreciate That Compounds Can Contain More Than One Chiral Centre, But Knowledge Of Meso Compounds, Or Nomenclature Such As Diastereoisomers Is Not Required.)
- 15.146Practice Questions: An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Identify Chiral Centres And Geometrical (Cis/trans) Isomerism In A Molecule Of Given Structural Formula Including Cyclic Compounds
- 15.147Practice Questions: An Introduction To As Level Organic Chemistry: Isomerism: Structural Isomerism And Stereoisomerism: Deduce The Possible Isomers For An Organic Molecule Of Known Molecular Formula
- 15.148Practice Questions: Hydrocarbons: Alkanes: Recall The Reactions (Reagents And Conditions) By Which Alkanes Can Be Produced: (A) Addition Of Hydrogen To An Alkene In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (B) Cracking Of A Longer Chain Alkane, Heat With Al 2o3
- 15.149Practice Questions: Hydrocarbons: Alkanes: Describe: (A) The Complete And Incomplete Combustion Of Alkanes (B) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane
- 15.150Practice Questions: Hydrocarbons: Alkanes: Describe The Mechanism Of Free-radical Substitution With Reference To The Initiation, Propagation And Termination Steps
- 15.151Practice Questions: Hydrocarbons: Alkanes: Suggest How Cracking Can Be Used To Obtain More Useful Alkanes And Alkenes Of Lower Mr From Heavier Crude Oil Fractions
- 15.152Practice Questions: Hydrocarbons: Alkanes: Understand The General Unreactivity Of Alkanes, Including Towards Polar Reagents In Terms Of The Strength Of The C–h Bonds And Their Relative Lack Of Polarity
- 15.153Practice Questions: Hydrocarbons: Alkanes: Recognise The Environmental Consequences Of Carbon Monoxide, Oxides Of Nitrogen And Unburnt Hydrocarbons Arising From The Combustion Of Alkanes In The Internal Combustion Engine And Of Their Catalytic Removal
- 15.154Practice Questions: Hydrocarbons: Alkenes: Recall The Reactions (Including Reagents And Conditions) By Which Alkenes Can Be Produced: (A) Elimination Of Hx From A Halogenoalkane By Ethanolic Naoh And Heat (B) Dehydration Of An Alcohol, By Using A Heated Catalyst (E.g. Al 2o3) Or A Concentrated Acid (E.g. Concentrated H2so4) (C) Cracking Of A Longer Chain Alkane
- 15.155Practice Questions: Hydrocarbons: Alkenes: Describe The Following Reactions Of Alkenes: (A) The Electrophilic Addition Of (I) Hydrogen In A Hydrogenation Reaction, H2(G) And Pt/ni Catalyst And Heat (Ii) Steam, H2o(G) And H3po4 Catalyst (Iii) A Hydrogen Halide, Hx(G), At Room Temperature (Iv) A Halogen, X2 (B) The Oxidation By Cold Dilute Acidified Kmno4 To Form The Diol (C) The Oxidation By Hot Concentrated Acidified Kmno4 Leading To The Rupture Of The Carbon–carbon Double Bond And The Identities Of The Subsequent Products To Determine The Position Of Alkene Linkages In Larger Molecules (D) Addition Polymerisation Exemplified By The Reactions Of Ethene And Propene
- 15.156Practice Questions: Hydrocarbons: Alkenes: Describe The Use Of Aqueous Bromine To Show The Presence Of A C=c Bond
- 15.157Practice Question: Hydrocarbons: Alkenes: Describe The Mechanism Of Electrophilic Addition In Alkenes, Using Bromine/ethene And Hydrogen Bromide/propene As Examplesions:
- 15.158Practice Questions: Hydrocarbons: Alkenes: Describe And Explain The Inductive Effects Of Alkyl Groups On The Stability Of Primary, Secondary And Tertiary Cations Formed During Electrophilic Addition (This Should Be Used To Explain Markovnikov Addition)
- 15.159Practice Questions: Halogen Compounds: Halogenoalkanes: Recall The Reactions (Reagents And Conditions) By Which Halogenoalkanes Can Be Produced: (A) The Free-radical Substitution Of Alkanes By Cl 2 Or Br2 In The Presence Of Ultraviolet Light, As Exemplified By The Reactions Of Ethane (B) Electrophilic Addition Of An Alkene With A Halogen, X2, Or Hydrogen Halide, Hx(G), At Room Temperature (C) Substitution Of An Alcohol, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2
- 15.160Practice Questions: Halogen Compounds: Halogenoalkanes: Classify Halogenoalkanes Into Primary, Secondary And Tertiary
- 15.161Practice Questions: Halogen Compounds: Halogenoalkanes: Describe The Following Nucleophilic Substitution Reactions: (A) The Reaction With Naoh(Aq) And Heat To Produce An Alcohol (B) The Reaction With Kcn In Ethanol And Heat To Produce A Nitrile (C) The Reaction With Nh3 In Ethanol Heated Under Pressure To Produce An Amine (D) The Reaction With Aqueous Silver Nitrate In Ethanol As A Method Of Identifying The Halogen Present As Exemplified By Bromoethane
- 15.162Practice Questions: Halogen Compounds: Halogenoalkanes: Describe The Elimination Reaction With Naoh In Ethanol And Heat To Produce An Alkene As Exemplified By Bromoethane
- 15.163Practice Questions: Halogen Compounds: Halogenoalkanes: Describe The Sn1 And Sn2 Mechanisms Of Nucleophilic Substitution In Halogenoalkanes Including The Inductive Effects Of Alkyl Groups
- 15.164Practice Questions: Halogen Compounds: Halogenoalkanes: Recall That Primary Halogenoalkanes Tend To React Via The Sn2 Mechanism; Tertiary Halogenoalkanes Via The Sn1 Mechanism; And Secondary Halogenoalkanes By A Mixture Of The Two, Depending On Structure
- 15.165Practice Questions: Halogen Compounds: Halogenoalkanes: Describe And Explain The Different Reactivities Of Halogenoalkanes (With Particular Reference To The Relative Strengths Of The C–x Bonds As Exemplified By The Reactions Of Halogenoalkanes With Aqueous Silver Nitrates)
- 15.166Practice Questions: Hydroxy Compounds: Alcohols: Recall The Reactions (Reagents And Conditions) By Which Alcohols Can Be Produced: (A) Electrophilic Addition Of Steam To An Alkene, H2o(G) And H3po4 Catalyst (B) Reaction Of Alkenes With Cold Dilute Acidified Potassium Manganate(Vii) To Form A Diol (C) Substitution Of A Halogenoalkane Using Naoh(Aq) And Heat (D) Reduction Of An Aldehyde Or Ketone Using Nabh4 Or Lialh4 (E) Reduction Of A Carboxylic Acid Using Lialh4 (F) Hydrolysis Of An Ester Using Dilute Acid Or Dilute Alkali And Heat
- 15.167Practice Questions: Hydroxy Compounds: Alcohols: Describe: (A) The Reaction With Oxygen (Combustion) (B) Substitution To Form Halogenoalkanes, E.g. By Reaction With Hx(G); Or With Kcl And Concentrated H2so4 Or Concentrated H3po4; Or With Pcl 3 And Heat; Or With Pcl 5; Or With Socl 2 (C) The Reaction With Na(S) (D) Oxidation With Acidified K2cr2o7 Or Acidified Kmno4 To: (I) Carbonyl Compounds By Distillation (Ii) Carboxylic Acids By Refluxing (Primary Alcohols Give Aldehydes Which Can Be Further Oxidised To Carboxylic Acids, Secondary Alcohols Give Ketones, Tertiary Alcohols Cannot Be Oxidised) (E) Dehydration To An Alkene, By Using A Heated Catalyst, E.g. Al 2o3 Or A Concentrated Acid (F) Formation Of Esters By Reaction With Carboxylic Acids And Concentrated H2so4 As Catalyst As Exemplified By Ethanol
- 15.168Practice Questions: Hydroxy Compounds: Alcohols: (A) Classify Alcohols As Primary, Secondary And Tertiary Alcohols, To Include Examples With More Than One Alcohol Group (B) State Characteristic Distinguishing Reactions, E.g. Mild Oxidation With Acidified K2cr2o7 , Colour Change From Orange To Green
- 15.169Practice Questions: Hydroxy Compounds: Alcohols: Deduce The Presence Of A Ch3ch(Oh)– Group In An Alcohol, Ch3ch(Oh)–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 15.170Practice Questions: Hydroxy Compounds: Alcohols: Explain The Acidity Of Alcohols Compared With Water
- 15.171Practice Questions: Carbonyl Compounds: Aldehydes And Ketones: Recall The Reactions (Reagents And Conditions) By Which Aldehydes And Ketones Can Be Produced: (A) The Oxidation Of Primary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Aldehydes (B) The Oxidation Of Secondary Alcohols Using Acidified K2cr2o7 Or Acidified Kmno4 And Distillation To Produce Ketones
- 15.172Practice Questions: Carbonyl Compounds: Aldehydes And Ketones: Describe: (A) The Reduction Of Aldehydes And Ketones Using Nabh4 Or Lialh4 To Produce Alcohols (B) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat To Produce Hydroxynitriles As Exemplified By Ethanal And Propanone
- 15.173Practice Questions: Carbonyl Compounds: Aldehydes And Ketones: Describe The Mechanism Of The Nucleophilic Addition Reactions Of Hydrogen Cyanide With Aldehydes And Ketones In 17.1.2(B)
- 15.174Practice Questions: Carbonyl Compounds: Aldehydes And Ketones: Describe The Use Of 2,4-dinitrophenylhydrazine (2,4-dnph Reagent) To Detect The Presence Of Carbonyl Compounds
- 15.175Practice Questions: Carbonyl Compounds: Aldehydes And Ketones: Deduce The Nature (Aldehyde Or Ketone) Of An Unknown Carbonyl Compound From The Results Of Simple Tests (Fehling’s And Tollens’ Reagents; Ease Of Oxidation)
- 15.176Practice Questions: Carbonyl Compounds: Aldehydes And Ketones: Deduce The Presence Of A Ch3co– Group In An Aldehyde Or Ketone, Ch3co–r, From Its Reaction With Alkaline I2(Aq) To Form A Yellow Precipitate Of Tri-iodomethane And An Ion, Rco2 –
- 15.177Practice Questions: Carboxylic Acids And Derivatives: Carboxylic Acids: Recall The Reactions By Which Carboxylic Acids Can Be Produced: (A) Oxidation Of Primary Alcohols And Aldehydes With Acidified K2cr2o7 Or Acidified Kmno4 And Refluxing (B) Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification (C) Hydrolysis Of Esters With Dilute Acid Or Dilute Alkali And Heat Followed By Acidification
- 15.178Practice Questions: Carboxylic Acids And Derivatives: Carboxylic Acids: Describe: (A) The Redox Reaction With Reactive Metals To Produce A Salt And H2(G) (B) The Neutralisation Reaction With Alkalis To Produce A Salt And H2o(L ) (C) The Acid–base Reaction With Carbonates To Produce A Salt And H2o(L) And Co2(G) (D) Esterification With Alcohols With Concentrated H2so4 As Catalyst (E) Reduction By Lialh4 To Form A Primary Alcohol
- 15.179Practice Questions: Carboxylic Acids And Derivatives: Esters: Recall The Reaction (Reagents And Conditions) By Which Esters Can Be Produced: (A) The Condensation Reaction Between An Alcohol And A Carboxylic Acid With Concentrated H₂so₄ As Catalyst
- 15.180Practice Questions: Carboxylic Acids And Derivatives: Esters: Describe The Hydrolysis Of Esters By Dilute Acid And By Dilute Alkali And Heat
- 15.181Practice Questions: Nitrogen Compounds: Primary Amines: Recall The Reactions By Which Amines Can Be Produced: (A) Reaction Of A Halogenoalkane With Nh₃ In Ethanol Heated Under Pressure Classification Of Amines Will Not Be Tested At As Level.
- 15.182Practice Questions: Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Nitriles Can Be Produced: (A) Reaction Of A Halogenoalkane With Kcn In Ethanol And Heat
- 15.183Practice Questions: Nitrogen Compounds: Nitriles And Hydroxynitriles: Recall The Reactions By Which Hydroxynitriles Can Be Produced: (A) The Reaction Of Aldehydes And Ketones With Hcn, Kcn As Catalyst, And Heat
- 15.184Practice Questions: Nitrogen Compounds: Nitriles And Hydroxynitriles: Describe The Hydrolysis Of Nitriles With Dilute Acid Or Dilute Alkali Followed By Acidification To Produce A Carboxylic Acid
- 15.185Practice Questions: Polymerisation: Addition Polymerisation: Describe Addition Polymerisation As Exemplified By Poly(Ethene) And Poly(Chloroethene), Pvc
- 15.186Practice Questions: Polymerisation: Addition Polymerisation: Deduce The Repeat Unit Of An Addition Polymer Obtained From A Given Monomer
- 15.187Practice Questions: Polymerisation: Addition Polymerisation: Identify The Monomer(S) Present In A Given Section Of An Addition Polymer Molecule
- 15.188Practice Questions: Polymerisation: Addition Polymerisation: Recognise The Difficulty Of The Disposal Of Poly(Alkene)s, I.e. Non-biodegradability And Harmful Combustion Products
- 15.189Practice Questions: Organic Synthesis: Organic Synthesis: For An Organic Molecule Containing Several Functional Groups: (A) Identify Organic Functional Groups Using The Reactions In The Syllabus (B) Predict Properties And Reactions
- 15.190Practice Questions: Organic Synthesis: Organic Synthesis: Devise Multi-step Synthetic Routes For Preparing Organic Molecules Using The Reactions In The Syllabus
- 15.191Practice Questions: Organic Synthesis: Organic Synthesis: Analyse A Given Synthetic Route In Terms Of Type Of Reaction And Reagents Used For Each Step Of It, And Possible By-products Analysis
- 15.192Practice Questions: Analytical Techniques: Infrared Spectroscopy: Analyse An Infrared Spectrum Of A Simple Molecule To Identify Functional Groups (See The Data Section For The Functional Groups Required)
- 15.193Practice Questions: Analytical Techniques: Mass Spectrometry: Analyse Mass Spectra In Terms Of M/e Values And Isotopic Abundances (Knowledge Of The Working Of The Mass Spectrometer Is Not Required)
- 15.194Practice Questions: Analytical Techniques: Mass Spectrometry: Calculate The Relative Atomic Mass Of An Element Given The Relative Abundances Of Its Isotopes, Or Its Mass Spectrum
- 15.195Practice Questions: Analytical Techniques: Mass Spectrometry: Deduce The Molecular Mass Of An Organic Molecule From The Molecular Ion Peak In A Mass Spectrum
- 15.196Practice Questions: Analytical Techniques: Mass Spectrometry: Suggest The Identity Of Molecules Formed By Simple Fragmentation In A Given Mass Spectrum
- 15.197Practice Questions: Analytical Techniques: Mass Spectrometry: Deduce The Number Of Carbon Atoms, N, In A Compound Using The [m + 1]+ Peak And The Formula N = 100 × Abundance Of [m + 1]+ Ion 1.1 × Abundance Of M+ Ion
- 15.198Practice Questions: Analytical Techniques: Mass Spectrometry: Deduce The Presence Of Bromine And Chlorine Atoms In A Compound Using The [m + 2]+ Peak
- Mock Tests/ Mock ExamsMock Exams For Final Preparation0
- Class RecordingsClass Recordings From Previous Sessions/ Current Session For Content0
- Other MaterialOther Useful Material For Exams0
- Notes + Written Material For Contents of The Syllabus Version 2Notes for Chapters + Written Resources Regarding The Content Version 252
- 19.1Particles In The Atom And Atomic Radius
- 19.2Isotopes
- 19.3Electrons, Energy Levels and Atomic Orbitals
- 19.4Ionization Energy
- 19.5Relative Masses of Atoms And Molecules
- 19.6The Mole And The Avogadro Constant
- 19.7Formulas
- 19.8Reaching Masses And Volumes (of Solutions and Gases)
- 19.9Electronegativity and Bonding
- 19.10Ionic Bonding
- 19.11Metallic Bonding
- 19.12Covalent Bonding And Coordinate (Dative Covalent) Bonding
- 19.13Shapes of Molecules
- 19.14Intermolecular Forces, Electronegativity and Bond Properties
- 19.15Dot-and-Cross Diagrams
- 19.16The Gaseous State: Ideal and Real Gases and pV = nRT
- 19.17Bonding and Structure
- 19.18Enthalpy Change, ΔH
- 19.19Hess’s Law
- 19.20Redox Processes: Electron Transfer and Changes In Oxidation Number (Oxidation State)
- 19.21Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium
- 19.22Bronsted-Lowry Theory of Acids and Bases
- 19.23Rate of Reaction
- 19.24Effect of Temperature on Reaction Rates and The Concept of Activation Energy
- 19.25Homogeneous and Heterogeneous Catalysts
- 19.26Periodicity of Physical Properties of the Elements in Period 3
- 19.27Periodicity of Chemical Properties of the Elements in Period 3
- 19.28Chemical Periodicity of Other Elements
- 19.29Similarities and Trends In The Properties of the Group 2 Metals, Magnesium To Barium, And Their Compounds
- 19.30Physical Properties of the Group 17 Elements
- 19.31The Chemical Properties of The Halogen Elements and Their Hydrogen Halides
- 19.32Some Reactions of The Halide Ions
- 19.33The Reactions of Chlorine
- 19.34Nitrogen and Sulfur
- 19.35An Introduction to AS Level Organic Chemistry
- 19.36Formulas, Functional Groups and The Naming of Organic Compounds
- 19.37Characteristic Organic Reactions
- 19.38Shapes of Organic Molecules; σ and π Bonds
- 19.39Isomerism: Structural Isomerism and Stereoisomerism
- 19.40Alkanes
- 19.41Alkenes
- 19.42Halogenoalkanes
- 19.43Alcohols
- 19.44Aldehydes and Ketones
- 19.45Carboxylic Acids
- 19.46Esters
- 19.47Primary Amines
- 19.48Nitrites and Hydroxynitrites
- 19.49Addition Polymerisation
- 19.50Organic Synthesis
- 19.51Infrared Spectroscopy
- 19.52Mass Spectrometry
- Quizzes For Preparation Version 2Quizzes With Detailed Explained Answers And Common Mistakes Discussed In Detail Version 252
- 20.1Particles In The Atom And Atomic Radius
- 20.2Isotopes
- 20.3Electrons, Energy Levels and Atomic Orbitals
- 20.4Ionization Energy
- 20.5Relative Masses of Atoms And Molecules
- 20.6The Mole And The Avogadro Constant
- 20.7Formulas
- 20.8Reaching Masses And Volumes (of Solutions and Gases)
- 20.9Electronegativity and Bonding
- 20.10Ionic Bonding
- 20.11Metallic Bonding
- 20.12Covalent Bonding And Coordinate (Dative Covalent) Bonding
- 20.13Shapes of Molecules
- 20.14Intermolecular Forces, Electronegativity and Bond Properties
- 20.15Dot-and-Cross Diagrams
- 20.16The Gaseous State: Ideal and Real Gases and pV = nRT
- 20.17Bonding and Structure
- 20.18Enthalpy Change, ΔH
- 20.19Hess’s Law
- 20.20Redox Processes: Electron Transfer and Changes In Oxidation Number (Oxidation State)
- 20.21Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium
- 20.22Bronsted-Lowry Theory of Acids and Bases
- 20.23Rate of Reaction
- 20.24Effect of Temperature on Reaction Rates and The Concept of Activation Energy
- 20.25Homogeneous and Heterogeneous Catalysts
- 20.26Periodicity of Physical Properties of the Elements in Period 3
- 20.27Periodicity of Chemical Properties of the Elements in Period 3
- 20.28Chemical Periodicity of Other Elements
- 20.29Similarities and Trends In The Properties of the Group 2 Metals, Magnesium To Barium, And Their Compounds
- 20.30Physical Properties of the Group 17 Elements
- 20.31The Chemical Properties of The Halogen Elements and Their Hydrogen Halides
- 20.32Some Reactions of The Halide Ions
- 20.33The Reactions of Chlorine
- 20.34Nitrogen and Sulfur
- 20.35An Introduction to AS Level Organic Chemistry
- 20.36Formulas, Functional Groups and The Naming of Organic Compounds
- 20.37Characteristic Organic Reactions
- 20.38Shapes of Organic Molecules; σ and π Bonds
- 20.39Isomerism: Structural Isomerism and Stereoisomerism
- 20.40Alkanes
- 20.41Alkenes
- 20.42Halogenoalkanes
- 20.43Alcohols
- 20.44Aldehydes and Ketones
- 20.45Carboxylic Acids
- 20.46Esters
- 20.47Primary Amines
- 20.48Nitrites and Hydroxynitrites
- 20.49Addition Polymerisation
- 20.50Organic Synthesis
- 20.51Infrared Spectroscopy
- 20.52Mass Spectrometry
- Cheat Sheets Version 2Short, Quick Revision Cheat Sheets Version 251
- 21.1Particles In The Atom And Atomic Radius
- 21.2Isotopes
- 21.3Electrons, Energy Levels and Atomic Orbitals
- 21.4Ionization Energy
- 21.5Relative Masses of Atoms And Molecules
- 21.6The Mole And The Avogadro Constant
- 21.7Formulas
- 21.8Reaching Masses And Volumes (of Solutions and Gases)
- 21.9Electronegativity and Bonding
- 21.10Ionic Bonding
- 21.11Metallic Bonding
- 21.12Covalent Bonding And Coordinate (Dative Covalent) Bonding
- 21.13Shapes of Molecules
- 21.14Intermolecular Forces, Electronegativity and Bond Properties
- 21.15Dot-and-Cross Diagrams
- 21.16The Gaseous State: Ideal and Real Gases and pV = nRT
- 21.17Bonding and Structure
- 21.18Enthalpy Change, ΔH
- 21.19Hess’s Law
- 21.20Redox Processes: Electron Transfer and Changes In Oxidation Number (Oxidation State)
- 21.21Chemical Equilibria: Reversible Reactions, Dynamic Equilibrium
- 21.22Bronsted-Lowry Theory of Acids and Bases
- 21.23Rate of Reaction
- 21.24Effect of Temperature on Reaction Rates and The Concept of Activation Energy
- 21.25Homogeneous and Heterogeneous Catalysts
- 21.26Periodicity of Chemical Properties of the Elements in Period 3
- 21.27Chemical Periodicity of Other Elements
- 21.28Similarities and Trends In The Properties of the Group 2 Metals, Magnesium To Barium, And Their Compounds
- 21.29Physical Properties of the Group 17 Elements
- 21.30The Chemical Properties of The Halogen Elements and Their Hydrogen Halides
- 21.31Some Reactions of The Halide Ions
- 21.32The Reactions of Chlorine
- 21.33Nitrogen and Sulfur
- 21.34An Introduction to AS Level Organic Chemistry
- 21.35Formulas, Functional Groups and The Naming of Organic Compounds
- 21.36Characteristic Organic Reactions
- 21.37Shapes of Organic Molecules; σ and π Bonds
- 21.38Isomerism: Structural Isomerism and Stereoisomerism
- 21.39Alkanes
- 21.40Alkenes
- 21.41Halogenoalkanes
- 21.42Alcohols
- 21.43Aldehydes and Ketones
- 21.44Carboxylic Acids
- 21.45Esters
- 21.46Primary Amines
- 21.47Nitrites and Hydroxynitrites
- 21.48Addition Polymerisation
- 21.49Organic Synthesis
- 21.50Infrared Spectroscopy
- 21.51Mass Spectrometry
Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: Use The Concept Of Electronegativity To Explain Bond Polarity And Dipole Moments Of Molecules
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Chemical Bonding: Intermolecular Forces, Electronegativity And Bond Properties: State That, In General, Ionic, Covalent And Metallic Bonding Are Stronger Than Intermolecular Forces
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