States of Matter | O Level Chemistry 5070 & IGCSE Chemistry 0620 | Detailed Free Notes
1.1 Solids, Liquids, and Gases
- Definition of Matter
- Matter consists of substances and materials making up the physical universe.
- Exists in three fundamental states: solid, liquid, and gas.
- Properties of Solids
- Fixed shape and volume.
- Particles are closely packed in a regular structure.
- Only vibrate around fixed positions.
- Strong intermolecular forces.
- Example: Ice, metals, wood.
- Properties of Liquids
- Fixed volume but takes the shape of its container.
- Particles are close together but move freely.
- Moderate intermolecular forces.
- Example: Water, oil, mercury.
- Properties of Gases
- No fixed shape or volume; expand to fill the container.
- Particles are far apart and move randomly at high speeds.
- Weak intermolecular forces.
- Example: Oxygen, nitrogen, steam.
- Compressibility
- Solids are incompressible.
- Liquids are slightly compressible.
- Gases are highly compressible due to large intermolecular spaces.
- Expansion and Contraction
- Solids, liquids, and gases expand when heated and contract when cooled.
- Example: Expansion joints in railway tracks prevent buckling in hot weather.
1.2 The Kinetic Particle Theory
- Basic Principles
- All matter is made of tiny particles in constant motion.
- The amount of motion depends on temperature.
- Stronger forces of attraction hold particles together in solids compared to gases.
- Particle Arrangement in Different States
- Solids: Tightly packed, vibrating in place.
- Liquids: Close together but can move around each other.
- Gases: Far apart, moving randomly and rapidly.
- Effect of Temperature on Particle Motion
- Higher temperatures increase kinetic energy and motion.
- Cooling slows down particle movement.
- Example: Heating ice causes it to melt into water, then evaporate into steam.
- Diffusion
- The spreading of particles from high to low concentration.
- Occurs faster in gases than in liquids.
- Example: Perfume spreading in a room.
1.3 Changes of State
- Melting (Solid → Liquid)
- Particles absorb heat and move apart.
- Melting point: The temperature at which a solid turns into a liquid.
- Example: Ice melting into water at 0°C.
- Boiling (Liquid → Gas)
- Particles gain energy to overcome attraction and form a gas.
- Boiling point: The temperature at which a liquid turns into a gas.
- Example: Water boils at 100°C at atmospheric pressure.
- Condensation (Gas → Liquid)
- Particles lose energy and come closer together to form a liquid.
- Example: Water vapor condenses into droplets on a cold surface.
- Freezing (Liquid → Solid)
- Particles lose energy and form a solid structure.
- Freezing point: The temperature at which a liquid solidifies.
- Example: Water freezes at 0°C.
- Sublimation (Solid → Gas)
- A solid changes directly into a gas without becoming a liquid.
- Example: Dry ice (solid CO2) sublimates at room temperature.
1.4 Effects of Temperature and Pressure on Gases
- Effect of Temperature on Gas Volume
- As temperature increases, gas molecules move faster and spread out, increasing volume.
- Example: A balloon expands in hot weather.
- Effect of Pressure on Gas Volume
- Increasing pressure forces particles closer together, reducing volume.
- Boyle’s Law: P1V1 = P2V2 (Pressure-Volume relationship at constant temperature).
- Example: Compressing air in a syringe.
1.5 Diffusion
- Definition
- The random movement of particles from a high to low concentration.
- Occurs faster in gases due to larger intermolecular spaces.
- Examples of Diffusion
- Ammonia gas and hydrogen chloride gas react to form a white ring of ammonium chloride.
- The smell of cooking spreads through a room.
- Food coloring spreading in water.
- Factors Affecting Diffusion
- Temperature: Higher temperature increases particle movement.
- Molecular Mass: Lighter particles diffuse faster.
Key Diagrams to Include
- Particle Arrangement in Solids, Liquids, and Gases
- Labelled diagrams showing particle spacing and movement.
- Heating and Cooling Curves
- Graphs showing temperature changes during melting and boiling.
- Diffusion Experiment
- Diagram of ammonia and hydrogen chloride diffusion forming ammonium chloride.
- Effect of Temperature and Pressure on Gases
- Illustration of gas expansion and compression in a balloon or syringe.
Conclusion
- The kinetic particle theory explains how matter behaves in different states.
- Understanding changes of state is crucial in explaining everyday phenomena.
- Temperature and pressure significantly impact gases and diffusion rates.
- Diffusion is essential in natural processes, such as breathing and transport of substances in cells.
